The Time-independent Schrödinger equation is the energy eigenvalue equation for a particle of mass . The Hamiltonian operator is the sum of the kinetic operator and the prescribed potential energy . Here is the reduced Planck constant. A corresponding stationary state is . The Born rule identifies as probability density for a state with wavefunction normalization ; integrating it over an interval gives a position probability. A plane wave scattering state is not a normalizable wavefunction on the whole line, but its probability currents give the reflection and transmission fractions of an incident wave packet.
There is a notation discrepancy in the sources: the original PDF prints an unbarred in the kinetic term, whereas the local TeX uses . The standard physical equation uses the reduced Planck constant , where is the Planck constant; that convention is used below. Reading the printed literally as the Planck constant would scale all lengths in this model by relative to the standard answers, but would leave the amplitude ratios unchanged.
For , both sides allow oscillatory wavefunctions. A classical particle always crosses the potential step and slows because its kinetic energy falls from to . In quantum mechanics there is generally both reflection and transmission even though the particle is above the step. Define the positive wavenumbersWith no wave incident from the right, writeA finite potential step with constant mass makes both the wavefunction and its first derivative continuous. The two boundary conditions at areSolving gives the reflected and transmitted wavefunctionsFor the specified Electron energies, , so the relative probability amplitudes areThe transmitted probability amplitude exceeding one is compatible with conservation of quantum probability, since the outgoing speed is smaller. In fact the probability current givesThese are the quantum reflection probability and transmission probability, which must be distinguished from the requested relative amplitudes.
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