Past exam of the physics of atmospheres and oceans course of the University of Oxford / 2021 / 1 / c

At the interface the pressure is continuous. Immediately below it the temperature is $T_s$ and mean molar mass is $M_d(1+ax)$; immediately above it the dry hydrogen has temperature $T_1$. The ideal gas law therefore givesAn infinitesimal interchange is unstable to convection when the lower fluid is less dense than the upper fluid. HenceEquality gives neutral interfacial buoyancy; reversing the inequality gives a stable density jump. This is an interfacial criterion, not a claim that the whole dry upper atmosphere is stable. Its vertical temperature profile has not been specified. Also, $\mathrm{RH}(p_1)=p_1/P<1$, so infinitesimal displacement at the interface initially involves no condensation or release of latent heat.

There are two competing effects. Increasing $T_s$ directly reduces the lower density, favouring convection. Increasing the mole fraction of heavy water vapor increases its mean molar mass, opposing convection. With $x\ll 1$, the criterion is approximately $T_s>T_1$. With $x\to 1$, it tends to $T_s>ϵT_1\simeq 9T_1$: substantial surface heating need not overcome the compositional stabilization in hydrogen.

For a specified $P_d,\Delta p,T_1$, solve $T_s/T_1-1-ax(T_s)=0$ on the admissible branch to locate the transitions. Its derivative is $1/T_1-a{x}^{\prime }(T_s)$, so there is no universal monotone trend: rapid growth of the saturation pressure can suppress an instability that was present at lower $T_s$. Without numerical parameter values, neither the number of crossings nor a unique interval of unstable temperatures can be asserted.