In the photoelectric effect, incident light ejects electrons from a material when each absorbed photon supplies sufficient energy to overcome its work function . Conservation of energy gives the maximum emitted kinetic energy,At fixed frequency above threshold, increasing light intensity primarily increases the electron emission rate; it does not increase in the single-photon regime. Emission occurs without the long accumulation delay predicted for weak classical illumination.
Classical electromagnetism distributes incident energy continuously. By itself, that picture suggests that sufficiently intense or sufficiently long illumination could eject electrons at any frequency, and that emitted electron energies should increase with light intensity. It does not account for the observed threshold frequency and the linear dependence of on frequency with slope . Quantized photon absorption accounts for all three features.
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