In the photoelectric effect, incident light ejects electrons from a material when each absorbed photon supplies sufficient energy to overcome its work function . Conservation of energy gives the maximum emitted kinetic energy,
At fixed frequency above threshold, increasing light intensity primarily increases the electron emission rate; it does not increase in the single-photon regime. Emission occurs without the long accumulation delay predicted for weak classical illumination.
Classical electromagnetism distributes incident energy continuously. By itself, that picture suggests that sufficiently intense or sufficiently long illumination could eject electrons at any frequency, and that emitted electron energies should increase with light intensity. It does not account for the observed threshold frequency and the linear dependence of on frequency with slope . Quantized photon absorption accounts for all three features.
The incident photon energy is
Subtracting the work function gives . This is much less than the electron rest energy, so nonrelativistic kinetic energy is adequate:
The magnitude of the retarding stopping potential satisfies , so
The collector must be negative relative to the emitting surface to retard the electrons; the quoted number is the magnitude. Contact-potential corrections are neglected.
The incident photon rate is . The stated quantum efficiency is , so the emitted electron rate is . If all emitted electrons are collected, the photocurrent magnitude is
The light power controls the number of events; the work function already determined the kinetic energy per emitted electron and should not be subtracted from the photon energy when counting incident photons. Incomplete collection would reduce the measured photocurrent below this value.
An electron accelerated from negligible initial kinetic energy through gains . The largest possible single photon energy in an X-ray tube is this entire kinetic energy, so the Duane-Hunt law gives
The massive anode can absorb the required recoil momentum with negligible recoil energy; most actual events produce lower-energy bremsstrahlung photons. The acceleration energy is valid without approximating the electron speed nonrelativistically.
Work in the initial rest frame of the free electron. If it absorbed a photon of positive energy , conservation of momentum would give the final electron momentum magnitude , while conservation of energy would give . But the final electron must obey the relativistic energy–momentum relation,
Combining these statements gives
which contradicts . Thus
The initial rest frame always exists for an electron, so this excludes the process in every inertial frame. Compton scattering is allowed because an outgoing photon carries additional energy and momentum. Absorption by an electron bound in matter is also possible because the rest of the system can share recoil.

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