For weak potentials, Boltzmann electrons give δne=neeϕ/(kBT) against fixed ions. Poisson's equation becomes ∇2ϕ=ϕ/λD2 outside a test charge, giving a Yukawa potential with λD=ϵ0kBT/(nee2). For a small electron displacement x relative to fixed ions, charge separation produces restoring field E=neex/ϵ0, so mx¨=−nee2x/ϵ0. Hence ωp=nee2/(ϵ0me). The two formulas respectively encode thermal screening and electron inertia.
Choose ND=(4π/3)neλD3. The stipulated estimate then givesThus density cancels and conductivity grows as T3/2 at fixed ion charge. Physically faster electrons are less effectively deflected by Coulomb encounters. Numerical factors depend on the Debye-volume convention, and a realistic collision calculation introduces a Coulomb logarithm and evolving ionization; the cancellation is approximate rather than exact for every real plasma.
τ≃3Znee44πϵ02me(kBT)3/2,σ≃3Ze2me4πϵ02(kBT)3/2.
In the cold solid, phonon scattering makes τ∝T−1 and therefore conductivity falls as temperature rises, at roughly fixed carrier density. After melting and ionization, the character of scattering changes; a hot Coulomb plasma eventually follows an increasing T3/2 branch. A minimum in the crossover region is natural, but a weakly coupled plasma formula is not quantitatively justified throughout the warm dense regime.
Room temperature corresponds to about 0.026 eV, or 2.6×10−5 keV. Read the left-hand branch there and draw a horizontal line to the rising hot branch. The original graph gives a return temperature of order kBT′∼1–2 keV, with graph-reading uncertainty, not the temperature of minimum conductivity.
At full ionization ne=13ρ/(27mu)≃7.8×1029 m−3. Inserting the inferred temperature into ND=(4π/3)ne[ϵ0kBT′/(nee2)]3/2 gives a Debye-sphere occupancy of order 60–170. This is much greater than one and supports a collective weak-coupling description more than the conductivity-minimum region does. The approximate collision-time formula and omitted Coulomb logarithm do not warrant forcing the entire plotted conductivity curve to have its exact prefactor.
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