Boltzmann constant by Ciro Santilli 40 Updated 2025-07-16
This is not a truly "fundamental" constant of nature like say the speed of light or the Planck constant.
Rather, it is just a definition of our Kelvin temperature scale, linking average microscopic energy to our macroscopic temperature scale.
The way to think about that link is, at 1 Kelvin, each particle has average energy:
per degree of freedom.
This is why the units of the Boltzmann constant are Joules per Kelvin.
For an ideal monatomic gas, say helium, there are 3 degrees of freedom. so each helium atom has average energy:
If we have 2 atoms at 1 K, they will have average energy , and so on.
Another conclusion is that this defines temperature as being proportional to the total energy. E.g. if we had 1 helium atom at 2 K then we would have about energy, 3 K and so on.
This energy is of course just an average: some particles have more, and others less, following the Maxwell-Boltzmann distribution.
Reversible reaction by Ciro Santilli 40 Updated 2025-07-16
I think these are the ones where , i.e. enthalpy and entropy push the reaction in different directions. And so we can use temperature to move the Chemical equilibrium back and forward.
Video 1.
Demonstration of a Reversible Reaction by Rugby School Chemistry (2020)
Source. Hydrated copper(ii) sulfate.
Entropy by Ciro Santilli 40 Updated 2025-07-16
OK, can someone please just stop the philosophy and give numerical predictions of how entropy helps you predict the future?
The original notion of entropy, and the first one you should study, is the Clausius entropy.
Video 1.
The Unexpected Side of Entropy by Daan Frenkel
. Source. 2021.
Video 2.
The Biggest Ideas in the Universe | 20. Entropy and Information by Sean Carroll (2020)
Source. In usual Sean Carroll fashion, it glosses over the subject. This one might be worth watching. It mentions 4 possible definitions of entropy: Boltzmann, Gibbs, Shannon (information theory) and John von Neumann (quantum mechanics).
Subtle is the Lord by Abraham Pais (1982) chapter 4 "Entropy and Probability" mentions well how Boltzmann first thought that the second law was an actual base physical law of the universe while he was calculating numerical stuff for it, including as late as 1872.
But then he saw an argument by Johann Joseph Loschmidt that given the time reversibility of classical mechanics, and because they were thinking of atoms as classical balls as in the kinetic theory of gases, then there always exist a valid physical state where entropy decreases, by just reversing the direction of time and all particle speeds.
So from this he understood that the second law can only be probabilistic, and not a fundamental law of physics, which he published clearly in 1877.
Considering e.g. Newton's laws of motion, you take a system that is a function of time , e.g. the position of many point particles, and then you reverse the speeds of all particles, then is a solution to that.
The more familiar transitions we are familiar with like liquid water into solid water happen at constant temperature.
However, other types of phase transitions we are less familiar in our daily lives happen across a continuum of such "state variables", notably:
Temperature by Ciro Santilli 40 Updated 2025-07-16
For scales from absolute 0 like Kelvin, is proportional to the total kinetic energy of the material.
The Boltzmann constant tells us how much energy that is, i.e. gives the slope.
Vacuum engineering by Ciro Santilli 40 Updated 2025-07-16
Video 1.
Air-tight vs. Vacuum-tight by AlphaPhoenix (2020)
Source. Shows how to debug a leak in an ultra-high vacuum system. Like every other area of engineering, you basically bisect the machine! :-) By Brian Haidet, a PhD at University of California, Santa Barbara.

Pinned article: Introduction to the OurBigBook Project

Welcome to the OurBigBook Project! Our goal is to create the perfect publishing platform for STEM subjects, and get university-level students to write the best free STEM tutorials ever.
Everyone is welcome to create an account and play with the site: ourbigbook.com/go/register. We belive that students themselves can write amazing tutorials, but teachers are welcome too. You can write about anything you want, it doesn't have to be STEM or even educational. Silly test content is very welcome and you won't be penalized in any way. Just keep it legal!
We have two killer features:
  1. topics: topics group articles by different users with the same title, e.g. here is the topic for the "Fundamental Theorem of Calculus" ourbigbook.com/go/topic/fundamental-theorem-of-calculus
    Articles of different users are sorted by upvote within each article page. This feature is a bit like:
    • a Wikipedia where each user can have their own version of each article
    • a Q&A website like Stack Overflow, where multiple people can give their views on a given topic, and the best ones are sorted by upvote. Except you don't need to wait for someone to ask first, and any topic goes, no matter how narrow or broad
    This feature makes it possible for readers to find better explanations of any topic created by other writers. And it allows writers to create an explanation in a place that readers might actually find it.
    Figure 1.
    Screenshot of the "Derivative" topic page
    . View it live at: ourbigbook.com/go/topic/derivative
  2. local editing: you can store all your personal knowledge base content locally in a plaintext markup format that can be edited locally and published either:
    This way you can be sure that even if OurBigBook.com were to go down one day (which we have no plans to do as it is quite cheap to host!), your content will still be perfectly readable as a static site.
    Figure 2.
    You can publish local OurBigBook lightweight markup files to either https://OurBigBook.com or as a static website
    .
    Figure 3.
    Visual Studio Code extension installation
    .
    Figure 4.
    Visual Studio Code extension tree navigation
    .
    Figure 5.
    Web editor
    . You can also edit articles on the Web editor without installing anything locally.
    Video 3.
    Edit locally and publish demo
    . Source. This shows editing OurBigBook Markup and publishing it using the Visual Studio Code extension.
    Video 4.
    OurBigBook Visual Studio Code extension editing and navigation demo
    . Source.
  3. https://raw.githubusercontent.com/ourbigbook/ourbigbook-media/master/feature/x/hilbert-space-arrow.png
  4. Infinitely deep tables of contents:
    Figure 6.
    Dynamic article tree with infinitely deep table of contents
    .
    Descendant pages can also show up as toplevel e.g.: ourbigbook.com/cirosantilli/chordate-subclade
All our software is open source and hosted at: github.com/ourbigbook/ourbigbook
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