Initially, one slip system carries most of the deformation. Easy dislocation glide gives the nearly flat stage-I response, although lattice rotation and gradual dislocation interactions can already change the required tensile stress. In tension the loading direction expressed in the rotating crystal approaches the primary slip direction. Its path has the form until it reaches the symmetry boundary , at .
At that orientation, and have equal Schmid factors, . Conjugate slip therefore becomes competitive. Intersections between the two dislocation families generate obstacles, junctions and forest hardening, giving the sharp stage-II rise in flow stress. This is the ideal single-slip-to-conjugate-slip construction; real activation stresses can be shifted by latent hardening and imperfections.
Figure 1.
Ideal single-slip rotation and the onset of conjugate slip
. Original geometric construction. The stress trace before conjugate slip retains a constant critical resolved shear stress; the later hardening curve is schematic. Details.
Applying Schmid's law at first yield,
This infers the critical resolved shear stress for the initially active system, assuming the supplied tensile stress is the relevant uniaxial stress at yield and the twelve FCC systems have comparable initial slip resistance.
An FCC crystal slips on . For each slip system, Schmid's law gives , with . Enumerating the twelve systems for gives the maximum at
Here and are perpendicular, while , and . Hence . Reversing both directed slip conventions describes the same physical system.
(Bi) and are Bi-rich and Sn-rich terminal solid solutions, not intermetallic compounds. At the eutectic composition, cooling through gives
The two solids grow together as a fine eutectic microstructure, commonly lamellar or rod-like. Below about , the tin-rich component has an equilibrium tendency to transform from metallic tetragonal white tin to diamond-cubic grey tin, with a substantial volume increase. This is tin pest, which can disrupt the microstructure mechanically. The dashed transition does not transform the Bi-rich phase into tin. Actual transformation can be slow and depend strongly on impurities and nucleation; crossing the line does not guarantee immediate disintegration.
At a common test temperature and otherwise comparable microstructure, chemical order generally raises the yield strength. An ordinary FCC dislocation displaced by can interchange Au and Cu sublattices, creating an antiphase boundary behind it. This additional energy resists slip; paired dislocations can restore the order after the second member passes. The disordered phase does not pay the same ordering penalty. Comparing specimens actually tested at their different phase-stability temperatures also includes temperature-dependent mobility and recovery, so the ordering argument alone does not predict a unique measured strength ratio.
Successive planes normal to are chemically ordered Au and Cu layers. The supplied four-site cell is a convenient doubled description of the primitive tetragonal lattice: valid primitive translations are
They give a square basal cell of side , containing an Au basis atom at the origin and Cu at fractional . That last vector exchanges chemical species and is not a Bravais translation. Thus a face-centred-looking atomic arrangement does not make the chemically ordered material an FCC Bravais lattice. This is the L10 crystal structure; the following indices retain the larger cell specified in the question.
Figure 1.
Ordered copper-gold structure viewed along the second basal axis
. Original two-by-two projection of the supplied four-site cell. Colour gives chemical species; labels distinguish the fractional coordinate along the viewing direction. Details.
For a disordered face-centered cubic lattice, equal average scattering factors on the four sites give reflections only when are all even or all odd. Bragg's law also requires . With Fe K wavelength , the upper bound is . The allowed sums are , giving
The next allowed family, , has squared-index sum and cannot satisfy the diffraction condition for this wavelength. This list assumes the full geometrically accessible angular range, rather than an instrument-specific cutoff.
The local slow direction follows the radial rods. Between crossed polarizers, the angular factor is , so radial directions parallel to either polarizer are dark. The pattern is a Maltese cross in polarized-light microscopy, with four bright sectors separated by dark arms parallel to the polarizer directions. Its colours depend on the local optical path difference; tapering rods or changing fill fraction can make this vary with radius. The cross belongs to the local radial-axis pattern and does not imply a conoscopic interference figure.
Figure 1.
Form birefringence, wedge compensation and a radial extinction cross
. Original idealized optical model. The radial image shows normalized monochromatic intensity, not a simulated photograph or measured colour chart. Details.
At distance from its tip, the wedge thickness is . Its optical path difference is therefore
The perpendicular slow directions make the two retardances subtract. A white-light black compensation fringe is the zero-order cancellation, so the film retardance has magnitude approximately , with its slow direction along the rods. This interpretation assumes the observed fringe is the white-light compensation fringe; a single monochromatic dark fringe alone would have an integer-order ambiguity. Without the wedge, the wavelength dependence of selectively transmits visible wavelengths and gives the film its interference colour.
An optically isotropic film changes the phase of both transverse polarization components equally, so crossed polarizers still extinguish the transmitted light. The etched rod-and-gap composite has form birefringence: its effective permittivity depends on the direction of the electric field, even when the constituent material is intrinsically isotropic. In a simple subwavelength lamellar model,
The precise effective-medium formula changes with rod geometry, but the anisotropy remains. Resolving incident light along the two principal directions produces a phase retardation. An ideal lossless specimen between crossed polarizers transmits
where is the intensity after the first polarizer. Extinction occurs when a principal direction follows either polarizer; transmission is strongest near .
Features only a few tens of nanometres wide lie below the ordinary visible-light diffraction limit, approximately . The microscope cannot resolve individual rods, and unpolarized illumination does not directly reveal the orientation-dependent optical response. Scanning electron microscopy and atomic force microscopy can resolve the surface pattern. Transmission electron microscopy is another possible choice if a suitably thin specimen can be prepared.
Taking Cu K wavelength , Bragg's law gives . For cubic , and the nearest Zn–S separation is . For ideal wurtzite structure, and the nearest separation is . Therefore
Both have tetrahedral nearest-neighbour coordination number four, but different further-neighbour stacking and lattice relaxation can shift their equilibrium bond lengths. The hexagonal value assumes ideal and ; a real distorted wurtzite structure can have unequal axial and inclined bonds. One measured spacing alone does not determine every bond length without that structural assumption.

Pinned article: Introduction to the OurBigBook Project

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