 Solution

A dielectric responds to an electric field mainly by displacing or orienting bound charges, rather than by sustaining a steady conduction current. The polarization density $\mathbf{P}$ is electric dipole moment per unit volume. It creates bound chargeSeparating these charges from free charge motivatesFor an isotropic linear dielectric, $\mathbf{P}={ϵ}_0{\chi }_e\mathbf{E}$, soThe electric susceptibility ${\chi }_e$ describes material polarization and is not the magnetic susceptibility. More generally it is a tensor and can depend on frequency, field strength and temperature.

Electronic polarization displaces an Electron cloud relative to its nucleus; ionic polarization displaces positive and negative ions; orientational polarization partially aligns permanent molecular dipoles against thermal disorder. For independent permanent moments of magnitude $p$, weak-field orientational response gives ${\chi }_e\simeq n{p}^2/(3{ϵ}_0{k}_{B}T)$ when local-field corrections and interactions are negligible. This explains a common inverse-temperature contribution without asserting that every dielectric follows that law.

At a static interface, $\mathbf{n}\cdot ({\mathbf{D}}_2-{\mathbf{D}}_1)={\sigma }_f$ and the tangential electric field is continuous. Bound surface charge is already included through $\mathbf{P}$. For a homogeneous filled capacitor, $C=ϵA/d$, and a reversible linear dielectric stores energy density $u=\mathbf{E}\cdot \mathbf{D}/2$. At fixed voltage, insertion raises the stored field energy but the voltage source also supplies energy; force arguments must include that source. At fixed charge the capacitor energy instead decreases on insertion.

At frequencies too high for a polarization mechanism to follow the field, its contribution weakens. A complex permittivity represents dissipative dielectric loss as well as phase lag; the sign of its imaginary part depends on the time convention. Strong fields can cause nonlinear response or dielectric breakdown, beyond the reversible linear model.