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For a stationary film of uniform thickness, thermal conduction gives $T_{zz}=0$, so $T=T_0+cz$. The cooling boundary condition determines $c$:Consequently the surface temperature isThis is the quasistatic temperature of a conductively cooled film, with a weak-cooling expansion when $\alpha h/\kappa \ll 1$.

Let the thickness and longitudinal scales be $h_{\ast },L$, with $ϵ=h_{\ast }/L\ll 1$. Incompressibility gives transverse speed of order $ϵU$, and film evolution has the kinematic time scale $L/U$. For the temperature variation scale $\Theta$, longitudinal diffusion divided by transverse diffusion is $h_{\ast }^2/L^2={ϵ}^2$. Each advective term, and the time derivative on that evolution scale, divided by transverse diffusion isThus ${ϵ}^2\ll 1$ and $Pe\ll 1$ make the leading thermal profile locally linear and quasistatic. Retaining the weak-cooling condition gives the same surface-temperature approximation with the local $h(x,t)$. For any independently imposed faster time variation one would also require its thermal relaxation ratio $h_{\ast }^2/(\kappa t_{\mathrm{evol}})$ to be small.

Define the positive surface-tension gradient coefficientThe weak-cooling approximation gives ${\gamma }_s\simeq {\gamma }_0+Bh$, so the Marangoni stress is ${\gamma }_{s,x}=B{h}_x$. The Young–Laplace equation gives the leading liquid pressure $p=p_a-{\gamma }_0{h}_{xx}$, with constant ambient pressure. In lubrication theory, $p_z=0$ and $\mu u_{zz}=p_x$. The no-slip boundary condition at the wall and the tangential surface condition $\mu u_z(h)={\gamma }_{s,x}$ giveHence the volume flux isConservation of mass gives the thermocapillary thin-film equationThe replacement of surface tension by ${\gamma }_0$ in the capillary term needs $B{h}_{\ast }/{\gamma }_0\ll 1$. For comparable capillary and thermocapillary fluxes,so the fractional tension change is only $O({ϵ}^2)$. Both the tension correction to $\gamma h_{xxx}$ and the differentiated-tension contribution ${\gamma }_x{h}_{xx}$ are then higher-order. Weak cooling alone would not justify that replacement if $|{\gamma }^{\prime }|\Delta T/{\gamma }_0$ were allowed to grow without bound.

The capillary term smooths the film: a crest has negative curvature and higher liquid pressure, causing flow away from it. The thermal term has the opposite effect. A thicker region has a colder surface and therefore higher surface tension; Marangoni stress pulls surface fluid toward that region, reinforcing the thickness disturbance. These mechanisms give fourth-order damping and second-order growth respectively.

Use $H=h/\hat{h}$, $X=ϵx/\hat{h}$, and $\tau =t/\hat{t}$. The two dimensionless flux-divergence coefficients are $B{ϵ}^2\hat{t}/(2\mu )$ and ${\gamma }_0{ϵ}^4\hat{t}/(3\mu \hat{h})$. Setting both equal to one gives the balanced scales for a thermocapillary film:These choices yield $H_{\tau }+(H^2{H}_X{)}_X+(H^3{H}_{XXX}{)}_X=0$. The predicted $ϵ$ must be small for the assumed long-wave approximation.

Linearize about $H=1$ using a normal mode of amplitude $\delta$. The resulting equation is $s-k^2+k^4=0$, so the dispersion relation isModes with $0<|k|<1$ grow, while $|k|>1$ modes decay. Differentiating $s$ gives the most unstable wavenumbersThe physical fastest wavenumber is $ϵ/(\sqrt{2}\hat{h})$.

For a positive steady film with zero volume flux, $H^2{H}_X+H^3{H}_{XXX}=0$. Divide by $H^3$ and integrate once:Choosing the thickness scale so that $H=1$ when $H_{XX}=0$ sets $C=0$. Multiply $H_{XX}=-\ln H$ by $H_X$ and integrate to obtain the zero-flux thermocapillary film profiles relationThus the stated potential is $V(H)=H(\ln H-1)$ and the integration constant $E$ is the corresponding first integral.