Take a nonrelativistic particle of constant mass with energy , and choose the same zero of potential energy on both sides of a rectangular potential barrier:The equality of the exterior potential energies matters: it gives the same exterior wavenumber and makes . Here is the reduced Planck constant. This model has a finite jump in potential energy, no delta potential, and no absorbing term.
For , the Time-independent Schrödinger equation gives the spatial wavefunctionThe full stationary state is . We set the incident probability amplitude to one and impose no incoming wave from the right; this scattering wavefunction is not a normalizable wavefunction. The tunnelling decay constant describes exponential decay, rather than an oscillatory wavenumber in the barrier. Both exponential functions are needed on the finite interval: the growing term is not excluded by a condition at infinity.
The wavefunction and its derivative are continuous at each face, giving four linear matching conditions:Their solution supplies the transmission amplitudeA short derivation is to use the two right-face equations to express and in terms of , then substitute into the left-face equations. Taking the squared modulus gives the rectangular barrier transmission probability.
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