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For vacuum incidence at fixed angle ${\theta }_i$ into a transparent isotropic medium, Snell's law gives $n({\lambda }_0)=\sin {\theta }_i/\sin {\theta }_t({\lambda }_0)$. Thus $dn/d{\lambda }_0=-n\cot {\theta }_{t}d{\theta }_t/d{\lambda }_0$, andAngles must be differentiated in radians. This determines the local group velocity from a first derivative of measured refraction angles; pulse broadening needs further information about group velocity dispersion and absorption.

Intermodal dispersion is the temporal separation of components in different propagating normal modes because their group velocities differ. A pulse exciting several modes can therefore broaden even when its individual modal components have negligible bandwidth. It is distinct from group velocity dispersion within a single mode.

A dispersion relation specifies the allowed angular frequency $\omega (k)$ of a wavevector $k$. A single harmonic wave $A\cos (kx-\omega t)$ has constant-phase surfaces moving at the phase velocity,For two nearby components, use the identityThe slowly varying envelope moves at $\Delta \omega /\Delta k$. Taking a narrowband limit gives the group velocity,More generally, expand $\omega (k)$ around the central wavevector of a wavepacket. The linear term translates its envelope at $v_g$; the quadratic and higher terms produce group velocity dispersion and packet distortion. This interpretation needs a sufficiently narrow spectrum and weak enough absorption and distortion for an identifiable envelope to persist.

For light in a transparent material, $k=n(\omega )\omega /c$, soThe derivative is evaluated at the wavepacket's central frequency and ${\lambda }_0$ is the vacuum wavelength. In a nondispersive medium with constant $n$, the two velocities coincide and a packet can propagate without dispersion. In normal optical dispersion $dn/d{\lambda }_0<0$, the displayed model gives $v_g<v_p$.

The two velocities can differ even without material dispersion: a waveguide mode with ${\omega }^2={\omega }_c^2+c^2{k}^2$ has $v_p=\omega /k>c$ and $v_g=c^{2}k/\omega <c$, with $v_p{v}_g=c^2$. The phase velocity is not a signal speed. Near strongly absorbing resonances an anomalous derivative can also make the group velocity exceed $c$ or become negative; reshaping then prevents its simple identification with information transport. Relativistic causality constrains the signal front, not the speed of an arbitrary moving phase or distorted intensity maximum.

Different transverse normal modes have different cutoff frequencies and group velocities. A pulse exciting several of them reaches the output in delayed modal components, causing intermodal dispersion, pulse distortion and overlap of successive signals. Their interference also makes the transverse wave intensity pattern depend on propagation distance; irregularities can transfer energy between modes.

Mitigations are to operate between the first and second cutoff frequencies of a membrane waveguide, excite only the desired mode shape with a suitable source, and use smooth uniform boundaries or gradual transitions to reduce mode conversion. Reducing the signal bandwidth keeps its spectrum inside the single-mode interval and reduces group velocity dispersion within the selected mode. Single-mode operation removes intermodal dispersion but does not remove the dispersion derived in part (b).

Use a complex envelope $A(t)$ normalized so that $|A(t){|}^2=P(t)$; its units are ${\mathrm{W}}^{1/2}$. The optical carrier convention is $e^{-i{\omega }_{0}t}$: the physical electric field is proportional to the real part of $A(t)e^{-i{\omega }_{0}t}$ for a fixed transverse mode. With angular frequency offset $\Omega =\omega -{\omega }_0$, fix the Fourier transform conventionWrite $\tilde{A}=B{e}^{i\varphi }$ with real $B\ge 0$. A dispersive element adds spectral phaseConstant phase rotates the envelope; the linear term delays it by ${\varphi }_1$. The group delay is $d\varphi /d\Omega$. The quadratic coefficient ${\varphi }_2$ is group delay dispersion, abbreviated GDD, with units of time squared. Positive GDD makes higher frequencies arrive later with this convention. It is accumulated dispersion of a component; material group velocity dispersion is its corresponding coefficient per unit length.

To undo a quadratic stretcher spectral phase, the compressor must supply opposite GDD. Include the amplifier and all intervening optics in the sum:Setting this sum to zero does not cancel third-order dispersion, ${\varphi }_3$, or still higher orders. Residual spectral phase can produce asymmetry and satellite pulses even when the quadratic term vanishes. A diffraction grating system can make path length depend on frequency; matching the complete spectral phase over the occupied spectrum is more demanding than merely choosing opposite quadratic coefficients.

There is a useful proof of what phase correction can accomplish. By Parseval's identity,For a smooth decaying spectrum, the Fourier transform of $tA$ is $-id\tilde{A}/d\Omega$. Consequently the power-weighted mean arrival time and variance obeyAt fixed spectral amplitude, constant group delay minimizes this root mean square duration. Such a pulse is a transform-limited pulse, up to a time shift and constant phase. The nonnegative second term measures temporal broadening from unequal arrival times; the first term remains even after perfect phase correction.