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For a finite irreducible Markov chain with at least two states satisfying detailed balance, its Dirichlet form of a Markov chain obeysExpand $f-\pi (f)$ in an orthonormal eigenbasis. The denominator is ${\sum }_{j\ge 2}{a}_j^2$, and the numerator is ${\sum }_{j\ge 2}(1-{\lambda }_j)a_j^2$. Their ratio is at least $1-{\lambda }_2$ and equality holds for the second eigenfunction. Thus the optimal Poincare inequality for a reversible Markov chain constant is $1/\gamma$, for the ordinary rather than absolute spectral gap.

A Poisson Metropolis chain samples a Poisson distribution by proposing an upward or downward unit step with equal probability and reflecting a downward proposal at zero into a self-proposal. Its upward and downward transition probabilities are the displayed $u_n,d_n$, with $d_0=0$, and the diagonal entry is $1-u_n-d_n$. For ${\pi }_n=e^{-\lambda }{\lambda }^n/n!$, adjacent stationary fluxes equal $\frac{1}{2}\min ({\pi }_n,{\pi }_{n+1})$. Hence detailed balance holds. Positive adjacent probabilities imply an irreducible Markov chain; $P(0,0)\ge 1/2$ implies aperiodicity. The normalized invariant Poisson distribution implies positive recurrence, so the countable-state Markov chain convergence theorem applies. The boundary proposal probability is essential: forcing every proposal at zero to go upward would require a different acceptance ratio.

An irreducible Markov chain is positive recurrent when its mean return times are finite. For a nonexplosive Markov chain on a countable state space, this is equivalent to the existence of a stationary distribution on its irreducible class. For continuous time, a return cycle includes departure and return, rather than counting immediate residence as a return.

An invariant distribution of a continuous-time Markov chain whose coordinates are independent Poisson distributions. This property needs verification from the reaction propensity functions; it does not follow merely from having an equilibrium for the deterministic reaction-rate equations.

For example, consider the cyclic chemical reaction network with stoichiometric vectors $(1,0)$, $(0,1)$ and $(-1,-1)$ and respective reaction propensity functions $\lambda$, $\beta n$, $\gamma nm$, where all three constants are positive. Put $a=\lambda /\beta$ and $b=\beta /\gamma$. For $\pi (n,m)=e^{-a-b}{a}^n{b}^m/(n!m!)$, the three incoming terms in the chemical master equation are respectively $\beta n\pi (n,m)$, $\gamma nm\pi (n,m)$ and $\lambda \pi (n,m)$. They exactly cancel the outgoing terms. Boundary terms vanish by the zero negative-index convention, and normalization follows from the two Poisson distributions. Establishing a limiting probability distribution additionally requires nonexplosion, an irreducible Markov chain and positive recurrence.

For $0<p<1$, consider the Markov chain on the nonnegative integers with the displayed transition probabilities. From zero it starts a new upward run; from each positive state it either increments or resets. Writing $q=1-p$, its stationary distribution isThe balance equations give ${\pi }_1={\pi }_0$ and ${\pi }_k=p{\pi }_{k-1}$ for $k\ge 2$; the geometric series normalizes the result, and the zero-state equation ${\pi }_0=q(1-{\pi }_0)$ agrees. It is an irreducible Markov chain and is positive recurrent. Equivalently, its first return time to zero is one plus a geometric random variable with success probability $q$, so its mean recurrence time is $1+1/q$. Return paths of lengths two and three also make it aperiodic.

For a finite irreducible Markov chain satisfying detailed balance with $\pi$, its transition matrix is a self-adjoint operator for $⟨f,g{⟩}_{\pi }={\sum }_x\pi (x)f(x)g(x)$. For a real orthonormal eigenbasis $(f_j)$ with eigenvalues $({\lambda }_j)$,Indeed, apply the spectral decomposition of $P^t$ to the function $1_{\{y\}}/\pi (y)$, whose coefficient against $f_j$ is $f_j(y)$. For $t=0$, every eigenvalue multiplier is interpreted as one.

A stationary distribution is a probability distribution $\pi$ preserved by a Markov chain's evolution. For a Discrete-time Markov chain in the row convention,Thus $\pi$ is a normalized nonnegative left eigenvector of the transition matrix for eigenvalue one. Starting with $X_0$ distributed as $\pi$ makes every $X_n$ have that same probability distribution. For a time-homogeneous Markov chain, the path probabilities are also unchanged by shifting all observation times together: the process has strict stationarity. This does not mean its individual paths are constant. See Hao Wu's MIT lecture 2, stationary distributions.

For the sunny/rainy transition matrix, write $\pi =(a,1-a)$. The sunny component of $\pi P=\pi$ gives $a=0.8a+0.4(1-a)$, so $0.6a=0.4$ andMoreover,These equal stationary flows verify detailed balance and show that the Markov chain is reversible. The diagonal detailed balance equations hold automatically. Only $1/3$ of the stationary days are rainy, but $0.6$ of the days following a rainy day are rainy: stationarity permits dependence.

A finite Markov chain that is an irreducible Markov chain has a unique stationary distribution. If it is also an aperiodic Markov chain, ${\mu }_0{P}^n\to \pi$ for every initial probability distribution. The sunny/rainy example satisfies both conditions: both directions are possible and each state has a positive holding probability of a Markov chain. See Hao Wu's MIT lecture 4, convergence theorem. For an infinite state space, the additional positive recurrence hypothesis in the countable-state Markov chain convergence theorem matters.

Existence of a stationary distribution alone does not give this convergence. Consider the deterministic two-cycleHere $\pi C=\pi$, but starting in the first state gives alternating probability distributions $(1,0),(0,1),(1,0),\dots$. Its period of a state in a Markov chain is two. The running fraction of visits to either state nevertheless tends to $1/2$, illustrating the Markov chain ergodic theorem. Starting with $\pi$ instead keeps the one-time probability distributions stationary even though every path alternates.

On states $0,\dots ,m$, take an interior step of $+1$ or $-1$ with probability $p$ each and hold with probability $1-2p$. At an endpoint take the inward step with probability $2p$ and hold with probability $1-2p$. For $m\ge 1$ and $0<p\le 1/2$, the chain is irreducible and its stationary distribution has endpoint weights $1/(2m)$ and interior weights $1/m$.

Detailed balance proves this: the doubled inward endpoint transition requires its stationary mass to be half that of an adjacent interior point, and all interior points have equal mass. The total unnormalized weight is $1+2(m-1)+1=2m$. For $m=1$ there are just two equal endpoint masses.

When $p<1/2$, positive self-loops make the chain aperiodic, so its transition probabilities converge to this law. At $p=1/2$ every move changes parity and two-step returns are possible, giving period two and no such convergence from a fixed starting state. At $p=0$ every state is absorbing and uniqueness of the stationary law is lost.

Consider an irreducible Markov chain on the nonnegative integers with up-step probabilities $u_k>0$ and down-step probabilities $d_k>0$ for $k\ge 1$, reflected at zero. The displayed weights satisfy detailed balance. Every stationary distribution is proportional to them: the stationary equation at zero sets the edge flow ${\pi }_0{u}_0-{\pi }_1{d}_1$ to zero, and the remaining stationary equations make the flow constant along all edges. Hence positive recurrence is equivalent to ${\sum }_k{w}_k<\infty$, and then ${\pi }_k=w_k/{\sum }_j{w}_j$. This also allows holding probabilities of a Markov chain.

Take $d$ independent copies of the simple random walk on the integer line, each stepping left or right with equal probability at every integer time. Their product Markov chain moves all coordinates at once; each of its $2^d$ diagonal increments has probability $2^{-d}$. At odd times a return to the origin is impossible. At time $2n$, independence gives the displayed return probability, whose asymptotic equivalence follows from Stirling's approximation. The recurrence criterion by return probabilities and the p-series therefore imply recurrence for $d=1,2$ and a transient Markov chain for $d\ge 3$.

For $d>1$ the chain from the origin visits only the sublattice whose coordinates all have the same parity. This is one communicating class; restricting to it gives an irreducible Markov chain. The period of a state in a Markov chain is two here. The conclusion applies to that class, without incorrectly claiming Markov chain irreducibility on all of ${\mathbb{Z}}^d$. This walk moves diagonally; the usual axis-step simple random walk has different transition probabilities, even though the same dimensional recurrence threshold holds.

An irreducible Markov chain is transient when its states are transient states. Starting at any one state, there is a positive probability of never returning, and the number of visits to any fixed state is finite almost surely.

Refill the stock to a fixed positive size $N$ immediately whenever a step empties it. The resulting Markov chain has state space $\{1,\dots ,N\}$ and transitions $P(i,j)=1/i$ for $j<i$ and $P(i,N)=1/i$. It is irreducible and aperiodic, since every state reaches $N$, $N$ reaches every state, and $P(N,N)>0$. Its unique stationary distribution is ${\pi }_N=1/H_N$ and ${\pi }_k=1/((k+1)H_N)$ for $k<N$. Normalization is the harmonic number identity. For $k<N$, stationarity follows from ${\sum }_{j=k+1}^{N-1}1/(j(j+1))+1/N=1/(k+1)$; the same telescoping sum starting at $1$ gives stationarity at $N$. The finite-state convergence theorem therefore makes this stationary distribution the limiting distribution from every initial state.

An irreducible Markov chain on a finite or countably infinite state space has at most one stationary distribution. On a countably infinite state space it exists exactly when the chain is positive recurrent. In that case, for every state $i$,where $T_i^{+}$ is the first return time. The expression determines every component uniquely. The formula follows by dividing the one visit to $i$ in each return cycle by the mean recurrence time; the strong law of large numbers for successive cycles makes this occupation fraction precise.

Every irreducible finite Markov chain is positive recurrent and has exactly one stationary distribution. On an infinite state space, an irreducible null recurrent Markov chain or transient Markov chain has none. For example, the simple symmetric random walk on the integers is null recurrent. Aperiodicity affects convergence of the one-time laws, but is unnecessary for existence or uniqueness of a stationary distribution.