Define the instantaneous spin magnetization . Global reversal sends to without changing the zero-field energy. Pairing every microstate with its reversed partner proves at every positive temperature, even when almost all probability lies on the two fully aligned patterns. A vanishing mean does not imply weak alignment: the limiting probability distribution is half at and half at .
The Ising ring magnetization fluctuations measure this distinction through variance. In the class, both patterns have . Among the patterns, eight have and four have ; the two patterns also have . Consequently
It equals at , approaches for four independent fair Ising spins at , and approaches as . Unlike the energy variance, the spin magnetization variance remains large in the low-temperature symmetric mixture.
Figure 1.
Exact bond correlation, magnetization variance and heat capacity of the four-spin Ising ring
. Original exact finite-ring calculations at and , plotted against ; increasing means cooling at fixed . The marked point has , Ising ring bond correlation and spin magnetization variance . These smooth curves are model predictions. Details.
The same thermal fluctuation controls the field response. Allow to vary before setting it to zero; differentiating the Boltzmann distribution inserts , giving
This is a spin-normalized magnetic susceptibility with respect to the energy-valued parameter ; conversion to physical magnetization and magnetic field requires the magnetic moment and sample volume factors.
For finite , is a finite positive sum of exponential functions. Its free energy is a real analytic function for , so the smooth heat capacity peak here is not a critical phase transition. Spontaneous magnetization concerns the order of limits: first a thermodynamic limit, then removal of a symmetry-breaking field. The four-spin Ising ring alone establishes neither that limit nor any two-dimensional Ising model result.[ref]