Heat-engine calorimetry 2026-10-14
Heat-engine calorimetry measures heat transfers so that observed work can be compared with the correct energy input. Measuring motion alone cannot supply the denominator of thermal efficiency.
The institutional Laboratory 16: Stirling Engine describes a modern teaching arrangement: an ethanol lamp drives a Stirling engine coupled to an electrical output device, which supplies a resistor immersed in water in a calorimeter. The prescribed readouts include fuel mass consumed, the pressure-volume loop, electrical readings, and water temperature. The sequence separates fuel input, gas-cycle work, electrical output, and Joule heating of the water. Warming of the water is the final useful output; it is not the engine's rejected . The handout distinguishes warm-up from steady operation and asks students to compare the final warming with direct heating by the lamp. It gives a procedure, not a table of measured efficiencies. Its pp. 1–3 therefore establish an apparatus and measurement design without supplying a new experimental result.
For a proposed calibration, use a known input of electrical work to determine the effective heat capacity of the water, vessel and immersed parts; stir to make the measured temperature representative. A matched run with no input estimates exchange with the room. For constant and no phase transition, the resulting model iswhere is the signed net heat lost to the room during the measurement. Here is supplied electrical work when the resistor lies inside the calibration boundary; for a separate external heat input it is the received heat. These are proposed controls, not controls reported in that handout. Slow cooling, changing material properties and imperfectly matched room exchange limit this inference; the approach to thermal equilibrium and heat capacity matter as much as the thermometer reading.
To measure the actual engine-input , one must instrument its hot-side transfer separately, or close a calibrated energy balance around a specified heater boundary. A heater's electrical work includes changes in its stored internal energy and heat transfer that bypasses the engine. At periodic operation a cold-side flowing-water measurement can instead estimate , if mass flow rate and specific heat capacity at constant pressure are known, with negligible storage and other heat exchange in that measurement boundary. It measures only the rejection captured by that stream. Include all remaining transfers before using the residual to infer . This measurement discipline makes a comparison with Carnot's theorem meaningful.