Write , where is the inverse temperature, is temperature and is the Boltzmann constant. In the canonical ensemble, each spin configuration has probability . The nearest-neighbor Boltzmann factors multiply, so the spin-chain transfer matrix, in the order , isMultiplying its entries around the ring and summing over every Ising spin yields the partition function:The trace implements the periodic boundary conditions; replacing it by an endpoint sum would describe a different partition function. The normalized eigenvectors and corresponding eigenvalues areThe negative eigenvalue is essential for the antiferromagnetic Ising model. Introduce their ratioThe exact finite- partition function and Helmholtz free energy areFor finite , , so for both even and odd . The last term retains the finite-ring effect of geometric frustration.
To insert an Ising spin into this trace, use the diagonal matrix . In the eigenbasis of , it exchanges and , and hence has vanishing diagonal entries. The one-point correlation function is thereforeThe same conclusion follows directly from spin inversion symmetry: reversing every Ising spin preserves the energy and the Boltzmann factor while reversing .
For the two-point correlation function, the two insertions divide the ring into paths of and bonds. ThusIn particular, the exact finite-ring antiferromagnetic Ising correlation isBecause the one-point correlation functions vanish, this is also the connected correlation function. It gives and , as required by and exchanging the two paths around the ring. At , distinct Ising spins are independent and for ; is understood separately if a power occurs in the displayed expression.
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