The small baryon-to-photon ratio suppresses nuclear equilibrium abundances through the factor . Cooling eventually makes the binding-energy exponential favourable, but the deuterium bottleneck delays substantial nuclear burning until well after cosmological weak freeze-out. In ordinary Big Bang nucleosynthesis, nearly every neutron surviving that delay ends up in helium-4. This makes the final primordial helium mass fraction chiefly a neutron budget rather than an unrestricted equilibrium abundance.
Let be the neutron-to-proton ratio at freeze-out, let be the delay until effective nuclear burning, and let be the neutron mean lifetime. The initial fraction of baryons which are neutrons is . Because neutron decay converts a neutron into a proton, total baryon number remains constant, while the neutron fraction becomes . Each helium nucleus uses two neutrons and four baryons. Hence neutron-limited helium synthesis gives
Equivalently, with . This accounts for the extra protons produced by neutron decay; multiplying alone by the survival factor would miss their contribution. The following responses refer to ordinary neutron-limited burning, without exotic particle injection or a change to the nuclear network.
Extra relativistic neutrino species increase the effective number of relativistic energy degrees of freedom. At fixed temperature the Hubble parameter rises as , while the standard conversion rate is unchanged. Consequently cosmological weak freeze-out moves to higher temperature, , and the neutron-to-proton ratio increases. The initial neutron fraction therefore increases as well.
The quicker expansion also reduces the cosmic time required to cool to the deuterium bottleneck temperature: during radiation domination, while the thermal count is roughly constant. Fewer neutrons decay before burning. Both factors in the neutron budget increase, giving a larger final helium-4 mass fraction. This is the primordial helium response to extra relativistic species, under the assumption that the additional species contribute mainly to expansion rather than independently changing the conversion rates.
A longer neutron half-life means a larger mean lifetime . Holding the initial neutron-to-proton ratio and the nuclear-burning delay fixed, the derivative of the neutron survival factor is positive:
Thus fewer neutrons disappear during the deuterium bottleneck, and the final helium-4 mass fraction increases.
There can be a second effect if the increased lifetime represents a uniform reduction of the relevant weak interaction strength. With fixed masses and other couplings, neutron decay and the conversion reactions both scale as . Thus , whereas . Weaker conversion then freezes out earlier and increases , reinforcing the survival effect. The survival argument alone already establishes the requested neutron half-life effect on primordial helium; linking lifetime to all conversion rates additionally requires this microscopic assumption.
A larger baryon-to-photon ratio favours bound nuclei at a fixed temperature through the equilibrium factor . In particular it helps deuterium survive photodissociation sooner: there are fewer energetic photons per baryon, and nuclear reaction rates per baryon also rise. A schematic deuterium bottleneck condition is , suppressing slowly varying powers of temperature. It gives
Thus higher permits burning at a higher temperature. During radiation domination that means earlier cosmic time, , leaving less time for free-neutron decay after freeze-out. More neutrons enter helium, so the final helium-4 mass fraction increases, ordinarily rather weakly. This is the baryon-density effect on primordial helium.
The equilibrium helium factor indicates the direction of the change but is not a prediction that the final helium abundance grows without bound as . Once almost all surviving neutrons are captured, the final primordial helium mass fraction is limited by their supply, as the shared neutron budget shows.

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