Work in natural units , at temperatures far below the -boson mass but of order or above the electron mass. The Fermi interaction then supplies a local four-fermion amplitude. The Fermi constant has dimension energy. In scattering of a thermal lepton from a nonrelativistic nucleon, the nucleon current matrix element has size , while the lepton current has size . Thus . The two-body relativistic scattering cross-section contains the kinematic factor ; when the final and initial lepton energies are comparable, their momentum ratio is of order one. Consequently . This estimates temperatures above the electron mass and mass-splitting thresholds; those scales only affect the dimensionless rate function near freeze-out.
The light leptons in the thermal bath have number density and speed of order unity. Their conversion rate per nucleon is thereforeFor example, and change the neutron-to-proton ratio. The bath density here is the lepton density, not the much smaller baryon density. Dimensionless weak couplings, phase-space integrals and the several reaction channels set a numerical coefficient. Electron masses and the neutron-proton splitting also become important for a precision rate near cosmological weak freeze-out.
During radiation domination, the effective number of relativistic energy degrees of freedom, denoted , gives the energy densityThe paper's is this ; it is not the conventionally normalized effective number of neutrino species. With the specified reduced Planck mass, the Friedmann equation reads , whenceWrite the weak interaction conversion rate as . The ratio scales as , so it falls during cooling: conversion eventually becomes too slow to maintain neutron-proton chemical equilibrium. Equating the conversion and expansion rates givesOn suppressing the numerical coefficient, the cosmological weak freeze-out temperature is consequentlyThe one-sixth power reflects a balance between a conversion rate proportional to and a Hubble parameter proportional to .
Before electron-positron annihilation in cosmology, photons contribute two helicity states; electrons and positrons contribute two spin states each. Each of the three light neutrino flavours contributes one active neutrino helicity and one antineutrino helicity. At a common temperature the effective number of relativistic energy degrees of freedom is thereforeUsing and in the scaling formula alone gives . Including the explicit expansion coefficient from (ii), but setting the unknown rate coefficient to one, gives . Thus the warranted conclusion is a freeze-out temperature of order , above the electron mass. The omitted weak-rate coefficient prevents a more precise prediction from this estimate.
Neutrino decoupling occurs before most electron-positron pairs annihilate. Afterwards neutrinos redshift freely, , while the photons receive the pair entropy. For the still-coupled photon-pair gas, cosmological entropy conservation gives . Its entropy degrees of freedom drop from to . Comparing this with the freely cooling neutrinos givesAfter annihilation, photon and neutrino temperatures differ. To write the total energy density as , the neutrino contribution must include that temperature ratio:This is the paper's post-annihilation . Merely deleting the electron term while keeping all species at the same temperature would be incorrect. For comparison the entropy count, normalized to , is . These results assume instantaneous neutrino decoupling and relativistic neutrinos; the two counts represent different thermal moments.
The nucleons are nonrelativistic, so the Maxwell-Boltzmann distribution givesBoth spin degeneracies are two. Taking the ratio and using the specified negligible chemical potentials yields the neutron-to-proton ratioThe mass prefactor differs from unity only at the per-mille level. The dependence on is much stronger: . Thus earlier, hotter weak freeze-out leaves more neutrons relative to protons. For illustration, gives ; gives . Free-neutron decay after freeze-out lowers the ratio further before most Big Bang nucleosynthesis takes place.
The small baryon-to-photon ratio suppresses nuclear equilibrium abundances through the factor . Cooling eventually makes the binding-energy exponential favourable, but the deuterium bottleneck delays substantial nuclear burning until well after cosmological weak freeze-out. In ordinary Big Bang nucleosynthesis, nearly every neutron surviving that delay ends up in helium-4. This makes the final primordial helium mass fraction chiefly a neutron budget rather than an unrestricted equilibrium abundance.
Let be the neutron-to-proton ratio at freeze-out, let be the delay until effective nuclear burning, and let be the neutron mean lifetime. The initial fraction of baryons which are neutrons is . Because neutron decay converts a neutron into a proton, total baryon number remains constant, while the neutron fraction becomes . Each helium nucleus uses two neutrons and four baryons. Hence neutron-limited helium synthesis givesEquivalently, with . This accounts for the extra protons produced by neutron decay; multiplying alone by the survival factor would miss their contribution. The following responses refer to ordinary neutron-limited burning, without exotic particle injection or a change to the nuclear network.
Extra relativistic neutrino species increase the effective number of relativistic energy degrees of freedom. At fixed temperature the Hubble parameter rises as , while the standard conversion rate is unchanged. Consequently cosmological weak freeze-out moves to higher temperature, , and the neutron-to-proton ratio increases. The initial neutron fraction therefore increases as well.
The quicker expansion also reduces the cosmic time required to cool to the deuterium bottleneck temperature: during radiation domination, while the thermal count is roughly constant. Fewer neutrons decay before burning. Both factors in the neutron budget increase, giving a larger final helium-4 mass fraction. This is the primordial helium response to extra relativistic species, under the assumption that the additional species contribute mainly to expansion rather than independently changing the conversion rates.
A longer neutron half-life means a larger mean lifetime . Holding the initial neutron-to-proton ratio and the nuclear-burning delay fixed, the derivative of the neutron survival factor is positive:Thus fewer neutrons disappear during the deuterium bottleneck, and the final helium-4 mass fraction increases.
There can be a second effect if the increased lifetime represents a uniform reduction of the relevant weak interaction strength. With fixed masses and other couplings, neutron decay and the conversion reactions both scale as . Thus , whereas . Weaker conversion then freezes out earlier and increases , reinforcing the survival effect. The survival argument alone already establishes the requested neutron half-life effect on primordial helium; linking lifetime to all conversion rates additionally requires this microscopic assumption.
A larger baryon-to-photon ratio favours bound nuclei at a fixed temperature through the equilibrium factor . In particular it helps deuterium survive photodissociation sooner: there are fewer energetic photons per baryon, and nuclear reaction rates per baryon also rise. A schematic deuterium bottleneck condition is , suppressing slowly varying powers of temperature. It givesThus higher permits burning at a higher temperature. During radiation domination that means earlier cosmic time, , leaving less time for free-neutron decay after freeze-out. More neutrons enter helium, so the final helium-4 mass fraction increases, ordinarily rather weakly. This is the baryon-density effect on primordial helium.
The equilibrium helium factor indicates the direction of the change but is not a prediction that the final helium abundance grows without bound as . Once almost all surviving neutrons are captured, the final primordial helium mass fraction is limited by their supply, as the shared neutron budget shows.
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