Let be a bounded region with a piecewise smooth closed boundary, and let be a continuously differentiable vector field on an open neighbourhood of its closure. With the outward unit normal vector, the divergence theorem statesThe boundary surface integral is the total outward flux. All boundary components are included; on the boundary of a cavity, the outward unit normal vector points into the cavity.
The specific heat capacity is the energy needed per unit mass per unit increase in temperature. With constant, a small element of volume has mass and thermal energy , measured relative to the reference at which . Summing over givesChoosing a different reference temperature only adds a time-independent constant to this energy, so it does not affect the heat balance with volumetric heat generation.
For any fixed subregion , with no internal heat generation, conservation of energy says that the rate of stored thermal energy equals the incoming heat flux:The minus sign is needed because denotes outgoing heat flux. Substitute Fourier's law and apply the divergence theorem:Here differentiation under the integral uses a fixed region and sufficient regularity of . Since the identity holds for every , continuity of the integrands gives the local heat equationFor spatially varying thermal conductivity, the product rule gives ; the second term cannot generally be discarded.
Suppose and are two sufficiently regular steady state solutions with the same prescribed temperature on the boundary. Their difference satisfiesThe identical PDE source terms cancel. Apply the product rule and the divergence theorem to ; this is the weighted form of Green's first identity:Since , the nonnegative integrand must vanish, so . Hence is constant on each connected component of , and its zero Dirichlet boundary condition makes each constant zero. Therefore : the solution, if it exists, is unique. This proves Dirichlet uniqueness for variable-conductivity heat conduction; it does not require a constant thermal conductivity.
Integrate the steady state equation over and use the divergence theorem:The zero heat flux condition makes the boundary term vanish. But and throughout a region of positive volume, soa contradiction. Thus no steady-state solution exists. This is the insulated steady heat balance: positive internal heat generation continually increases the stored thermal energy when no heat can escape.
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