The real spectral theorem states that a symmetric matrix has an orthonormal basis of real eigenvectors, and hence is a diagonalisable matrix. Here is a proof in this setting.
For , the quadratic form attains a maximum on the unit sphere, by compactness and the extreme value theorem. Choose a unit maximizer and put . For any , the Rayleigh quotient along has a maximum at , so
The last equality uses and . Thus is orthogonal to every , so .
The orthogonal complement is an invariant subspace, because for ,
The restriction of to is again symmetric with respect to the induced inner product. By mathematical induction on dimension, it has an orthonormal basis of eigenvectors; adjoining gives one for . If has those basis vectors as columns, then is a real diagonal matrix and .
Let be a skew-symmetric matrix. For every real vector , the real scalar equals its own transpose, but
Hence . If is a real eigenvector equation with , it follows that
so . If is a diagonalisable matrix over , it has a real basis of eigenvectors, all with eigenvalue zero. Thus vanishes on a basis and .
The field matters: a nonzero real skew-symmetric matrix can be a diagonalisable matrix over the complex numbers, for example with eigenvalues .

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