Put . The matrix is real and symmetric, so orthogonality means . Multiplication gives the scalar conditions
If , then and ; if , then and or . In both cases . The eight parameter triples are therefore
These conditions are sufficient as well as necessary, since they make every entry of equal to the corresponding entry of the identity matrix.
A three-dimensional rotation matrix is an orthogonal matrix with determinant . Here . For the branch , the determinant condition gives ; for the branch , it gives . Hence
The first is the identity rotation; the remaining three are half-turns. Their fixed axes are respectively the axis, the direction and the direction . The identity is included under the usual rotation matrix convention.
A square homogeneous linear system has a nonzero solution exactly when its determinant vanishes. Expanding along the second row gives
Consequently
For an explicit check, the null space contains at and at .
The original PDF requires itself to be an orthogonal skew-symmetric matrix; it does not require to be diagonal. A real two-dimensional skew-symmetric matrix has the form . The orthogonal matrix condition gives , so choose . Then is forced:
Direct multiplication verifies , and . Choosing gives the same . Replacing by a matrix of eigenvectors to make diagonal would generally fail the printed antisymmetry requirement.
For the obtained above, the characteristic polynomial is
Thus the eigenvalues are and . For , gives ; for , it gives . Normalizing the eigenvectors yields
Both are unit vectors, their dot product is zero, and either overall sign is allowed for each eigenvector.

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