At fixed temperature, equilibrium blackbody radiation has fixed energy density , with radiation pressure . Doubling the volume therefore doubles its internal energy, so . The work done by the radiation isThe first law of thermodynamics, with positive work done by the radiation, givesThus is absorbed from the walls. The walls must replace the energy used to do work as well as supply the extra stored energy; using only would omit that work. This is a reversible isothermal expansion of a photon gas, not an adiabatic expansion.
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