Let λ=mU0a2/ℏ2≪1 and ka≪1. Inside a region of size a, the Schrödinger equation estimates the curvature as a2ψ′′=O(λ+(ka)2)ψ. Matching to the incoming and reflected waves constrains the slope as well. To leading order the interior wave has nearly constant value C, while its small accumulated derivative change encodes the potential's integrated strength.
This is not a Born assumption that C is close to one. At very low k the wave can be strongly reflected even by a weak potential, and C can be small. The matching solution in the next part gives C∼k/(k+imγ/ℏ2). It implies a fractional variation across the range of order ka+m∣γ∣a/ℏ2, which is small under the two specified conditions. ThusThe approximation requires a finite short-range potential with a controlled width and integral; it does not describe arbitrary long-range tails.
ψ(x)=C[1+O(ka,λ)]within the potential range.
Replace the slowly varying interior wave by C and eik∣x−x′∣ by one when both arguments lie within the range. The integral equation givesHenceThe integrated strength has dimensions of energy times length. For U=−αδ(x), γ=−α and this is exactly the result in part c. For a regular weak potential the approximation sums the important ratio mγ/(kℏ2) without requiring it to be small, which is why it remains useful beyond the naive first Born expansion at small momentum.
C=1−kℏ2imγC,γ=∫−∞∞U(x)dx.
C=t≃1+imγ/(kℏ2)1,r≃C−1.
Write ν=mγ/ℏ2, so t(k)≃k/(k+iν). Its nontrivial pole isFor negative γ this is on the positive imaginary k axis, the physical bound-state sheet. For positive γ it lies on the negative imaginary axis and is a virtual-state pole reached by analytic continuation through the continuum cut. These different sheets can have the same negative numerical energy; specifying only E∗ would conceal the distinction. As a function of E, the momentum square root also introduces the continuum threshold branch point at zero. If γ=0, numerator and denominator cancel at this order and no pole is predicted by this leading approximation.
k∗=−iν=−ℏ2imγ,E∗=−2ℏ2mγ2.
For a nonzero everywhere attractive weak potential, γ<0, the pole has k=iκ with κ=m∣γ∣/ℏ2>0. The exterior waves decay as e−κ∣x∣, giving one shallow bound state to leading weak-coupling order:Its size κ−1 is much larger than the potential range because κa=O(λ)≪1. For an everywhere repulsive potential there is no negative-energy normalizable bound state: the kinetic and potential quadratic forms are both nonnegative. Its lower-half-plane pole is a virtual state, not a stable bound state. More complicated sign-changing potentials with a vanishing integral require higher-order analysis and are not covered by this simple leading result.
Eb≃−2ℏ2m(∫U(x)dx)2.
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