Assume a real, time-independent potential with the same zero asymptote on both sides, so is the same incident and transmitted wave number. For unit incoming amplitudes,
Multiplying the two Schrödinger equations crosswise and subtracting shows that the Wronskian is constant. Its two asymptotic values are and , hence .
For a real potential the probability current is conserved, giving . Therefore
The reflection amplitudes can have different phases. Reality or self-adjointness is essential for the reflection-probability conclusion: a complex absorbing potential need not have equal left and right reflectances. Equal asymptotic speeds are also used in identifying transmission with the squared amplitude.
Away from , the free equation is . The outgoing boundary condition selects , continuous at its source. Integrating the differential equation across the source gives the derivative jump
The jump for the proposed form is , so . Thus
For far to either side, the -dependent phase is absorbed into the outgoing amplitude. The outgoing prescription is equivalently the boundary value of the resolvent with ; changing that prescription would give a different Green function.
Write and use the outgoing inverse of . Adding the homogeneous incoming wave yields
For the attractive delta potential, let . The equation reduces to and . Separating the two half-lines gives
Both sides have the same group velocity, so
The same amplitudes satisfy continuity and the exact delta-potential derivative jump , providing an independent local check on the sign.
Let and . Inside a region of size , the Schrödinger equation estimates the curvature as . Matching to the incoming and reflected waves constrains the slope as well. To leading order the interior wave has nearly constant value , while its small accumulated derivative change encodes the potential's integrated strength.
This is not a Born assumption that is close to one. At very low the wave can be strongly reflected even by a weak potential, and can be small. The matching solution in the next part gives . It implies a fractional variation across the range of order , which is small under the two specified conditions. Thus
The approximation requires a finite short-range potential with a controlled width and integral; it does not describe arbitrary long-range tails.
Replace the slowly varying interior wave by and by one when both arguments lie within the range. The integral equation gives
Hence
The integrated strength has dimensions of energy times length. For , and this is exactly the result in part c. For a regular weak potential the approximation sums the important ratio without requiring it to be small, which is why it remains useful beyond the naive first Born expansion at small momentum.
Write , so . Its nontrivial pole is
For negative this is on the positive imaginary axis, the physical bound-state sheet. For positive it lies on the negative imaginary axis and is a virtual-state pole reached by analytic continuation through the continuum cut. These different sheets can have the same negative numerical energy; specifying only would conceal the distinction. As a function of , the momentum square root also introduces the continuum threshold branch point at zero. If , numerator and denominator cancel at this order and no pole is predicted by this leading approximation.
For a nonzero everywhere attractive weak potential, , the pole has with . The exterior waves decay as , giving one shallow bound state to leading weak-coupling order:
Its size is much larger than the potential range because . For an everywhere repulsive potential there is no negative-energy normalizable bound state: the kinetic and potential quadratic forms are both nonnegative. Its lower-half-plane pole is a virtual state, not a stable bound state. More complicated sign-changing potentials with a vanishing integral require higher-order analysis and are not covered by this simple leading result.

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