Assume a real, time-independent potential with the same zero asymptote on both sides, so k=2mE/ℏ is the same incident and transmitted wave number. For unit incoming amplitudes,Multiplying the two Schrödinger equations crosswise and subtracting shows that the Wronskian W=ψLψR′−ψL′ψR is constant. Its two asymptotic values are −2iktR and −2iktL, hence tL=tR.
ψL∼{eikx+rLe−ikx,tLeikx,x→−∞,x→+∞,ψR∼{tRe−ikx,e−ikx+rReikx,x→−∞,x→+∞.
For a real potential the probability current j=(ℏ/m)Im(ψ∗ψ′) is conserved, giving ∣rL∣2+∣tL∣2=∣rR∣2+∣tR∣2=1. ThereforeThe reflection amplitudes can have different phases. Reality or self-adjointness is essential for the reflection-probability conclusion: a complex absorbing potential need not have equal left and right reflectances. Equal asymptotic speeds are also used in identifying transmission with the squared amplitude.
TL=TR=∣t∣2,RL=RR=1−T.
Away from x=x′, the free equation is G′′+k2G=0. The outgoing boundary condition selects G=Aeik∣x−x′∣, continuous at its source. Integrating the differential equation across the source gives the derivative jumpThe jump for the proposed form is 2ikA, so A=im/(kℏ2). ThusFor x far to either side, the x′-dependent phase is absorbed into the outgoing amplitude. The outgoing prescription is equivalently the boundary value of the resolvent with E→E+i0; changing that prescription would give a different Green function.
−2mℏ2[G′(x′+,x′)−G′(x′−,x′)]=1.
G(x,x′)=kℏ2imeik∣x−x′∣.
Write L0ψ=−Uψ and use the outgoing inverse of L0. Adding the homogeneous incoming wave yieldsFor the attractive delta potential, let η=mα/(kℏ2). The equation reduces to ψ(x)=eikx+iηeik∣x∣ψ(0) and ψ(0)=1/(1−iη). Separating the two half-lines givesBoth sides have the same group velocity, soThe same amplitudes satisfy continuity and the exact delta-potential derivative jump ψ′(0+)−ψ′(0−)=−2mαψ(0)/ℏ2, providing an independent local check on the sign.
ψ=eikx−kℏ2im∫eik∣x−x′∣U(x′)ψ(x′)dx′.
t=1−iη1,r=1−iηiη,ψ={eikx+re−ikx,teikx,x<0,x>0.
T=1+η21,R=1+η2η2,T+R=1.
Let λ=mU0a2/ℏ2≪1 and ka≪1. Inside a region of size a, the Schrödinger equation estimates the curvature as a2ψ′′=O(λ+(ka)2)ψ. Matching to the incoming and reflected waves constrains the slope as well. To leading order the interior wave has nearly constant value C, while its small accumulated derivative change encodes the potential's integrated strength.
This is not a Born assumption that C is close to one. At very low k the wave can be strongly reflected even by a weak potential, and C can be small. The matching solution in the next part gives C∼k/(k+imγ/ℏ2). It implies a fractional variation across the range of order ka+m∣γ∣a/ℏ2, which is small under the two specified conditions. ThusThe approximation requires a finite short-range potential with a controlled width and integral; it does not describe arbitrary long-range tails.
ψ(x)=C[1+O(ka,λ)]within the potential range.
Replace the slowly varying interior wave by C and eik∣x−x′∣ by one when both arguments lie within the range. The integral equation givesHenceThe integrated strength has dimensions of energy times length. For U=−αδ(x), γ=−α and this is exactly the result in part c. For a regular weak potential the approximation sums the important ratio mγ/(kℏ2) without requiring it to be small, which is why it remains useful beyond the naive first Born expansion at small momentum.
C=1−kℏ2imγC,γ=∫−∞∞U(x)dx.
C=t≃1+imγ/(kℏ2)1,r≃C−1.
Write ν=mγ/ℏ2, so t(k)≃k/(k+iν). Its nontrivial pole isFor negative γ this is on the positive imaginary k axis, the physical bound-state sheet. For positive γ it lies on the negative imaginary axis and is a virtual-state pole reached by analytic continuation through the continuum cut. These different sheets can have the same negative numerical energy; specifying only E∗ would conceal the distinction. As a function of E, the momentum square root also introduces the continuum threshold branch point at zero. If γ=0, numerator and denominator cancel at this order and no pole is predicted by this leading approximation.
k∗=−iν=−ℏ2imγ,E∗=−2ℏ2mγ2.
For a nonzero everywhere attractive weak potential, γ<0, the pole has k=iκ with κ=m∣γ∣/ℏ2>0. The exterior waves decay as e−κ∣x∣, giving one shallow bound state to leading weak-coupling order:Its size κ−1 is much larger than the potential range because κa=O(λ)≪1. For an everywhere repulsive potential there is no negative-energy normalizable bound state: the kinetic and potential quadratic forms are both nonnegative. Its lower-half-plane pole is a virtual state, not a stable bound state. More complicated sign-changing potentials with a vanishing integral require higher-order analysis and are not covered by this simple leading result.
Eb≃−2ℏ2m(∫U(x)dx)2.
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