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Birefringence is the existence of different optical propagation constants for different eigenpolarizations in an anisotropic material. It provides the propagation-mode separation needed for adiabatic optical following in a twisted nematic.

Two different refractive indices can produce two displaced images, as in the calcite double-image experiment, or a phase retardation between overlapping components, as in a waveplate. Spatial separation concerns where energy flux travels; phase retardation concerns the relative wave phase. A specimen need not show two visibly separated images to have birefringence.

The extraordinary wave's Poynting vector can differ in direction from its wavevector. The latter specifies wave phase propagation, while the former specifies energy flux. This angular separation is walk-off.^[ref]

In the lossless, nondispersive model above, take the gradient of $\omega =c\sqrt{k_x^2/n_e^2+k_z^2/n_o^2}$ to obtain the group velocity, parallel to the Poynting vector. If its angle to the optic axis is $\varphi$, this gives $\tan \varphi =(n_o^2/n_e^2)\tan \theta$. Consequently the extraordinary wave generally carries energy away from its wavevector direction. An internal wavevector normal to a slab face therefore does not guarantee a normal energy path. Birefringent walk-off vanishes at $\theta =0$ and $\theta =\pi /2$; the latter direction still has unequal refractive indices. This is a useful waveplate geometry: overlapping components can acquire phase retardation without spatial splitting. A thin specimen, insufficient imaging resolution, or excitation of only one linear polarization can also hide a double image, for different reasons.

For the overlapping monochromatic wave components, let $d$ be the thickness and ${\lambda }_0$ the vacuum wavelength. Define $\Delta n=n_s-n_f>0$ using the slow and fast refractive indices. With complex amplitude convention $e^{i(kz-\omega t)}$, the accumulated slow-minus-fast phase difference isThis is the optical path difference $\Delta nd$ expressed as a wave phase. It is a signed accumulation convention; with the opposite time convention the sign reverses. The outgoing polarization of an electromagnetic wave depends on $\delta$ modulo $2\pi$. Here the positive slow-minus-fast $\Delta n$ differs from the signed principal-index $n_e-n_o$ used in the parent birefringence entry when $n_e<n_o$.

For an original worked example, stipulate $\Delta n=0.0100$ at ${\lambda }_0=600\mathrm{nm}$ and a uniform thickness $d=15.0\mu \mathrm{m}$. These are design assumptions, not measured material data. The optical path difference is $150\mathrm{nm}$, soIt is a quarter-wave plate. At the same wavelength and refractive indices, doubling $d$ to $30.0\mu \mathrm{m}$ gives $\delta =\pi$, a half-wave plate. A $1.0\mu \mathrm{m}$ thickness increase changes $\delta$ by $\pi /30$, or $6^{\circ }$; retaining the same birefringence at $500\mathrm{nm}$ would instead give $\delta =3\pi /5$ for the $15.0\mu \mathrm{m}$ plate. Real refractive indices also vary with wavelength, so this last calculation explicitly neglects optical dispersion.

For these equal transmitted wave amplitudes, orthogonal projection onto a polarizer crossed with the initial $45^{\circ }$ linear polarization gives a simple independent readout. After removing a common wave phase, the component complex amplitudes are proportional to $(1,e^{i\delta })/\sqrt{2}$; orthogonal projection onto $(1,-1)/\sqrt{2}$ gives $(1-e^{i\delta })/2$. Squaring its modulus yields $I_{\perp }/I_{\mathrm{in}}={\sin }^2(\delta /2)$: zero at $d=0$, one half at $15\mu \mathrm{m}$, and one at $30\mu \mathrm{m}$. This assumes ideal polarizers, negligible specular reflection and wave absorption, overlapping components and stable relative wave phase. It measures a periodic function of phase retardation, so one brightness measurement cannot determine the thickness uniquely.

A quarter-wave plate gives a quarter-cycle phase retardation. Equal transmitted wave amplitudes initially in linear polarization at $45^{\circ }$ become circular polarization; unequal wave amplitudes generally give elliptical polarization. Reversing the sign reverses the traversal of the same circle.

A waveplate uses birefringence to change polarization of an electromagnetic wave through phase retardation. Its fast axis has the smaller refractive index, hence the larger phase velocity; its slow axis has the larger index. Consider normal incidence with the optic axis in the plate face, so both components follow the same straight path. A linear polarization at $45^{\circ }$ to these axes excites equal wave amplitudes.

A complementary experiment uses two sheet polarizers with a cellophane sheet between them. First cross the polarizers and remove the sheet: the field is dark. Insert and rotate the sheet about the beam: light returns at intermediate orientations, but extinction recurs at two perpendicular orientations. The sheet has changed the polarization of an electromagnetic wave, without requiring a resolved double image. With white light, different wavelengths can produce different transmitted colors.^[ref]. Brightness alone does not establish circular polarization: an ideal rotating linear polarizer also gives orientation-independent light intensity for unpolarized light.