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A carbon dioxide laser, or CO2 laser, uses excited carbon dioxide molecules as its laser gain medium. Its characteristic emission lies in the infrared, with important lines near $10.6\mu \mathrm{m}$. The emitting transitions change the molecule's vibrational and rotational states. This connects laser action with molecular vibration and molecular rotation, rather than with a requirement to break the molecule into its constituent atoms.

Energy supplied to the gas creates an appropriate excited-state distribution. Stimulated emission amplifies light on a selected transition; an optical cavity returns it through the medium, and a partly transmitting output element extracts useful radiant power. The laser threshold depends on complete round-trip gain and loss. The presence of carbon dioxide alone does not establish population inversion or select a unique oscillating line.

A primary experimental landmark is C. K. N. Patel's 1964 report from Bell Telephone Laboratories. It identified continuous-wave laser action on several rotational lines of two vibrational bands, with the strongest reported vacuum wavelength $10.6324\mu \mathrm{m}$ and continuous output around $1\mathrm{mW}$. The same transitions were observed under pulsed-discharge excitation, and time-dependent output was studied. These are properties of that reported experiment, not universal power or wavelength limits for every CO2 laser.^[ref]

The molecular line structure explains why a quoted wavelength is only part of the specification. Several allowed transitions can supply gain, while the optical cavity favours its own normal modes. A device need not emit every line of a rovibrational spectrum, nor is its line selected merely by saying that the medium contains carbon dioxide. A spectral measurement can test which transitions actually oscillate.

An original calculation connects the reported wavelength with the size of an energy quantum. Using the Planck constant $h$ and the speed of light $c$,For a stipulated monochromatic $1\mathrm{mW}$ beam at that wavelength, the rate of emitted photons isThe individual photon energy is small even when the collective beam carries measurable power. This bookkeeping does not establish how efficiently the electrical input becomes output radiation; that comparison requires separate input and output measurements.

The film-activation apparatus in laser capture microdissection supplies a distinct application: a carbon dioxide laser pulse activates a thermoplastic film locally to collect selected tissue. Its use there depends on the material's response and the spatial delivery of energy, rather than the name of the laser alone.^[ref]

The resolved lines arise from simultaneous changes of vibration and rotation in hydrogen cyanide. A vibrational fundamental connects many populated lower rotational levels to different upper rotational levels, giving the fine structure of a rovibrational spectrum.

The prominent central Q branch, together with flanking P branch and R branch lines, identifies a perpendicular band. For linear HCN, this is the doubly degenerate bending fundamental, not either stretching fundamental. Bending creates a transition-dipole component perpendicular to the molecular axis; its vibrational angular momentum permits $\Delta J=0$ as well as $\Delta J=\pm 1$.

The two perpendicular bending coordinates share one vibrational frequency. Their degeneracy is different from the series of resolved rotational transitions superimposed on that fundamental. The stretches have their electric dipole transition moment along the molecular axis and would give the usual parallel-band P/R pattern without this strong central Q feature.

This is a rovibrational spectrum: the vibrational excitation is accompanied by quantized molecular rotation. The high-wavenumber R branch has $\Delta J=+1$, and the low-wavenumber P branch has $\Delta J=-1$. In the simplest common-$B$ approximation,Consecutive lines within either branch are therefore separated by roughly $2B$, while the gap between P(1) and R(0) is roughly $4B$. There is no Q branch: for this diatomic parallel $\Sigma \to \Sigma$ transition, the electric-dipole rotational selection rule allows $\Delta J=\pm 1$, and the $\Delta J=0$ line strength vanishes.

The intensity envelope comes from rotational populations, approximately $(2J+1)e^{-hcBJ(J+1)/(k_{B}T)}$, together with the rotational line strengths. The paired peaks arise from the two chlorine isotopologues, ${\mathrm{H}}^{35}Cl$ and ${\mathrm{H}}^{37}Cl$: their different reduced masses shift both rotational and vibrational spacings. The more abundant ${}^{35}\mathrm{Cl}$ gives the stronger member. The changing spacing away from the band centre reflects $B_1\ne B_0$ and, at higher $J$, centrifugal distortion; it is not evidence for additional vibrational fundamentals.