Term symbol Updated 2025-07-16
This notation is so confusing! People often don't manage to explain the intuition behind it, why this is an useful notation. When you see Indian university entry exam level memorization classes about this, it makes you want to cry.
The key reason why term symbols matter are Hund's rules, which allow us to predict with some accuracy which electron configurations of those states has more energy than the other.
web.chem.ucsb.edu/~devries/chem218/Term%20symbols.pdf puts it well: electron configuration notation is not specific enough, as each such notation e.g. 1s2 2s2 2p2 contains several options of spins and z angular momentum. And those affect energy.
This is why those symbols are often used when talking about energy differences: they specify more precisely which levels you are talking about.
Basically, each term symbol appears to represent a group of possible electron configurations with a given quantum angular momentum.
We first fix the energy level by saying at which orbital each electron can be (hyperfine structure is ignored). It doesn't even have to be the ground state: we can make some electrons excited at will.
The best thing to learn this is likely to draw out all the possible configurations explicitly, and then understand what is the term symbol for each possible configuration, see e.g. term symbols for carbon ground state.
It also confusing how uppercase letters S, P and D are used, when they do not refer to orbitals s, p and d, but rather to states which have the same angular momentum as individual electrons in those states.
It is also very confusing how extremelly close it looks to spectroscopic notation!
The form of the term symbol is:
Atomic Term Symbols by TMP Chem (2015)
Source. Atomic Term Symbols by T. Daniel Crawford (2016)
Source. Bibliography:
- chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/Supplemental_Modules_(Physical_and_Theoretical_Chemistry)/Spectroscopy/Electronic_Spectroscopy/Spin-orbit_Coupling/Atomic_Term_Symbols
- chem.libretexts.org/Courses/Pacific_Union_College/Quantum_Chemistry/08%3A_Multielectron_Atoms/8.08%3A_Term_Symbols_Gives_a_Detailed_Description_of_an_Electron_Configuration The PDF origin: web.chem.ucsb.edu/~devries/chem218/Term%20symbols.pdf
- chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Inorganic_Coordination_Chemistry_(Landskron)/08%3A_Coordination_Chemistry_III_-_Electronic_Spectra/8.01%3A_Quantum_Numbers_of_Multielectron_Atoms
- physics.stackexchange.com/questions/8567/how-do-electron-configuration-microstates-map-to-term-symbols How do electron configuration microstates map to term symbols?
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Old town sign of Fugging, Upper Austria
. Source. Welcome to Austria!
C. elegans cell lineage Updated 2025-07-16
Exactly 131 commit apoptosis in the hermaphrodite.
www.wormatlas.org/celllineages.html contains the full lineage as some huge and impossible to view images. This image was taken directly from The embryonic cell lineage of the nematode Caenorhabditis elegans where it is split across many pages, it is a thing of beauty on the PDF.
www.wormatlas.org/celllistsulston.htm contains a non-hierarchical table with the cells and their names.
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In this section we classify some functions by the type of inputs and outputs they take and produce.
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High level simulation only, no way to get from DNA to worm! :-) Includes:
- nervous system
- muscle system
OpenWorm Sibernetic demo by Mike Vella (2013)
Source. Sibernetic adds a fluid dynamics solver for brain-in-the-loop simulation of C. elegans. s-orbital Updated 2025-07-16
x86 Paging Tutorial Basic TLB operation Updated 2025-07-16
After a translation between linear and physical address happens, it is stored on the TLB. For example, a 4 entry TLB starts in the following state:
valid linear physical
----- ------ --------
> 0 00000 00000
0 00000 00000
0 00000 00000
0 00000 00000The
> indicates the current entry to be replaced.And after a page linear address and after a second translation of
00003 is translated to a physical address 00005, the TLB becomes: valid linear physical
----- ------ --------
1 00003 00005
> 0 00000 00000
0 00000 00000
0 00000 0000000007 to 00009 it becomes: valid linear physical
----- ------ --------
1 00003 00005
1 00007 00009
> 0 00000 00000
0 00000 00000 CIA 2010 covert communication websites Non Reuters ranges Updated 2025-07-16
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Invalid Bitcoin script Updated 2025-07-16
They appear to be included, with rationale that you can already include syntactically valid crap in an unprovable way: github.com/bitcoin/bitcoin/issues/320 Better then have syntactically invalid crap that is provable.
The outputs of this transaction seem to be the first syntactically incorrect scripts of the blockchain: blockchain.info/tx/ebc9fa1196a59e192352d76c0f6e73167046b9d37b8302b6bb6968dfd279b767?format=json, found by parsing everything locally. The transaction was made in 2013 for 0.1 BTC, which then became unspendable.
x86 Paging Tutorial Hardware implementation Updated 2025-07-16
Paging is implemented by the CPU hardware itself.
Paging could be implemented in software, but that would be too slow, because every single RAM memory access uses it!
Operating systems must setup and control paging by communicating to the CPU hardware. This is done mostly via:
- the CR3 register, which tells the CPU where the page table is in RAM memory
- writing the correct paging data structures to the RAM pointed to the CR3 register.Using RAM data structures is a common technique when lots of data must be transmitted to the CPU as it would cost too much to have such a large CPU register.The format of the configuration data structures is fixed by the hardware, but it is up to the OS to set up and manage those data structures on RAM correctly, and to tell the hardware where to find them (via
cr3).Then some heavy caching is done to ensure that the RAM access will be fast, in particular using the TLB.Another notable example of RAM data structure used by the CPU is the IDT which sets up interrupt handlers. - CR3 cannot be modified in ring 3. The OS runs in ring 0. See also:
- the page table structures are made invisible to the process using paging itself!
Processes can however make requests to the OS that cause the page tables to be modified, notably:
- stack size changes
brkandmmapcalls, see also: stackoverflow.com/questions/6988487/what-does-brk-system-call-do/31082353#31082353
The kernel then decides if the request will be granted or not in a controlled manner.
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