At a critical point, a local field operator has scaling dimension if under coarse-graining by . The coupling in has renormalization-group eigenvalue
A perturbation is a relevant operator when , an irrelevant operator when , and a marginal operator when ; nonlinear terms in its renormalization-group beta function decide the fate of a marginal coupling. Irrelevant microscopic interactions decay under coarse-graining, so many distinct systems approach the same fixed point and share one universality class.
Near criticality the singular free energy density is of order one per correlation volume:
The heat capacity contains two derivatives with respect to temperature, so
Consequently the hyperscaling relation is
For , , so the Schwarzschild black hole has negative heat capacity. A small energy gain from a reservoir lowers its temperature below the reservoir temperature and causes further absorption; a small energy loss raises its temperature and causes further emission. The equilibrium is therefore unstable in the canonical ensemble.
The horizon area is , while
Thus the First law of black-hole mechanics
holds with the Bekenstein-Hawking entropy .
For equilibrium with an infinite fixed-temperature reservoir, local stability requires positive heat capacity. Since , its sign is the sign of
Therefore the Canonical stability of a Schwarzschild--anti-de Sitter black hole occurs precisely for
The equality is the minimum-temperature, marginal case; smaller black holes have negative heat capacity and unstable thermal equilibrium.
Put , so . At zero field the stationary equation factors as
For , is the unique minimum. For , it is unstable and the two minima are
The order parameter therefore tends continuously to zero, and its order-parameter critical exponent is .
At either ordered minimum the singular free-energy density is
whereas it is zero for . Two temperature derivatives give a singular heat capacity proportional to below the transition and zero above it, so the heat-capacity critical exponent is .
The inverse magnetic susceptibility at a stable minimum is the curvature . Below ,
and hence and . Above , however, the curvature at vanishes for every . Indeed, at small field , so and the linear susceptibility is already infinite away from the critical point. Consequently the usual magnetic-susceptibility critical exponent is not defined for this exceptional free energy; assigning it a finite value would incorrectly assume a quadratic term.
At , the equation of state is , so and the critical-isotherm exponent is . Thus the transition is continuous, although its missing quadratic term makes the high-temperature linear response singular throughout that phase.
At a first-order transition the Gibbs free energy is continuous but a first derivative such as entropy or volume jumps; there is latent heat. At a second-order transition the first derivatives are continuous while a second derivative, such as heat capacity or susceptibility, is discontinuous or divergent, and there is no latent heat.
Specific heat capacity Created 2026-09-28 Updated 2026-09-29
Thermal diffusivity Created 2026-09-24 Updated 2026-09-24
Thermal diffusivity is , the ratio of thermal conductivity to volumetric heat capacity. It sets the diffusion length over time .
Thermal inertia 2026-10-06
For a homogeneous material, thermal inertia is , where is thermal conductivity, is density and is specific heat capacity. It measures the resistance of the surface temperature to periodic heating and controls the phase lag relevant to the Yarkovsky effect.
For a gas-supported alpha disk with , compare rates at fixed surface density of a disk, radius, and composition on the thermal timescale of an accretion disk. Assume that the vertical dynamical timescale of a disk is shorter than that thermal time, and that the viscous timescale is longer; the separation is controlled for and small disk aspect ratio. Vertical hydrostatic equilibrium gives , , so . Viscous heating satisfies and radiative cooling satisfies . At equilibrium a positive temperature perturbation changes the net heating by . With positive effective heat capacity, it grows rather than relaxes. This is a local thermal statement and uses the fixed-column, rather than fixed-volume-density, comparison.
When the singular free-energy density has , the same thermal and free-energy metric factors multiply the singular heat capacity above and below the critical point. Their ratio cancels these factors and depends only on the normalized scaling functions of the universality class. This statement concerns singular amplitudes, not regular heat-capacity backgrounds, and needs separate treatment at logarithmic resonances or zero amplitudes. Branch matching constants belong to the fixed-point scaling functions and cannot be chosen as independent nonuniversal parameters.