For equal phase mass densities, equal sensible heat capacities per unit volume, and negligible thermal diffusion, a porous melting front driven by hot Darcy flux has speed
Here is the newly melted volume fraction. Mass conservation preserves on both sides: the liquid gained by melting fills the newly available pores. The enthalpy increase per unit bulk volume is , so its rate of production is balanced by incoming heat flux .
For a thermodynamically stable system, the entropy is concave in energy, so
Consequently : energy increases with temperature, and the corresponding heat capacity is positive.
Two thermal derivatives of a regulated Gaussian determinant produce this integral. For , rescaling yields a divergent power and heat-capacity critical exponent . At four dimensions the singularity is logarithmic, with power exponent zero. Above four the leading heat capacity is a finite cutoff-dependent background; its leading bounded-power convention has exponent zero, although the background-subtracted singular Gaussian contribution retains the negative index . In a stable quartic theory the mean-field ordered free energy proportional to instead produces a heat-capacity jump. This is why a dangerously irrelevant coupling qualifies naive hyperscaling relation.
For and inverse Stefan number , a stagnant mushy-layer model has nearly constant effective heat capacity, giving with . With negligible liquid solutal diffusivity, roof value , positive liquid superheat , and edge , the mush profile is . Matching heat flux requires . The square on in the exponential is essential. The porosity records the leading composition balance; the linear thermal profile is asymptotic, not exact at finite .
In units , a Schwarzschild black hole has Hawking temperature , so its heat capacity is . It heats up as it loses mass, preventing stable canonical equilibrium with an unlimited thermal reservoir.