Expanding with the angular momentum commutators gives
For , commuting past a ladder operator gives
Thus the raised or lowered vector, if nonzero, is an eigenvector with the shifted eigenvalue; an angular momentum ladder endpoint can instead be annihilated. Also , so for every nonzero ladder result.
For orbital angular momentum, gives an azimuthal factor . Single-valuedness under requires integer . Positivity of ladder norms gives
for normalized states. A fixed finite therefore has upper and lower endpoints. Writing the upper endpoint as , its vanishing raising norm gives ; the lower endpoint is . Consequently
with . This integer conclusion is for orbital angular momentum; spin representations can also have half-integer labels.
For the specified Gaussian-radial state, use a Cartesian p-orbital decomposition: write . Its angular factor is
Only occurs. The squared angular coefficients are before common normalization, so each allowed has probability one third. Therefore the simultaneous outcome is
The common normalized radial factor cancels from this ratio. The standard symmetric sequence used above resolves the duplicated central positive entry in the printed list.
The orbital angular momentum of a particle is the operator , with in the position representation. Its angular momentum commutation relations are
Thus one may specify and one component, conventionally , simultaneously. One generally cannot assign sharp values to all three components, because they do not commute. The common angular eigenfunctions are the spherical harmonics:
For a scalar orbital wavefunction, single-valuedness in the azimuthal angle gives integer , and regularity on the sphere and termination of the ladder give integer . Half-integer angular momenta describe intrinsic spin rather than scalar orbital motion.
The ladder operators obey . Their normalized action is
The coefficient vanishes at the top or bottom of the multiplet. Its squared magnitude follows from , and positivity of the resulting norm constrains the allowed values.
For a central potential, the Hamiltonian commutes with and every component of . Stationary states can be separated as , and rotational symmetry makes the energy independent of , giving a quantum degeneracy at fixed radial label and . Additional degeneracy between distinct values requires additional structure, as in the Coulomb potential. The parity of is . These results organize atomic orbitals and their selection rules. They describe quantized rotation and symmetry, without assigning the electron a classical orbit or a simultaneously definite three-component angular momentum vector.
For the quantum harmonic oscillator, using , direct multiplication gives
The commutators are
Thus each ladder operation shifts energy by one quantum. The ladder operator norms and , with conventional phases, give
Let . In position space , so becomes . Normalizing and then applying gives
Their overlap vanishes because is odd on the full real line; the Gaussian second moment verifies .
Figure 1.
Oscillator ground and first states
. Original normalized oscillator wavefunctions show even ground-state parity, odd first-excited parity and one interior node in the excited state. Details.
Invert the given ladder operators:
Because the Energy eigenstate are orthonormal, : each operator changes the state to one orthogonal to . Hence
The result also follows from the definite parity of every oscillator energy eigenfunction, but here it follows directly from the specified operators.
Expanding the total angular momentum and replacing transverse components by ladder operators gives
The particle exchange operator obeys and , with the reverse relation for index . These statements also apply to the ladder operators. Exchanging the indices preserves and ; it interchanges the last two terms in . Operators on different tensor factors commute. Hence
The full particle exchange includes the spin coordinates as well as the spatial coordinates.
In the ordered orthonormal basis , the spin one-half angular momentum operators are , with Pauli matrices
The ladder operators are
Explicit multiplication gives and . Their commutator is therefore
The angular momentum commutation relations are
where is the Levi-Civita symbol. The angular momentum eigenstates have
with angular momentum quantum number and magnetic quantum number . There are such states in one irreducible spin representation, so the eigenspace has dimension within that multiplet. The use of avoids confusing the magnetic quantum number with the particle mass in the earlier questions.
For completeness, the ladder operators satisfy and
The upper and lower ends are ; integer steps between them require to be a nonnegative integer. This explains both the spectrum and the multiplet dimension. Pure orbital angular momentum permits only integer , whereas general spin allows half-integers. If a larger Hilbert space contains several copies of the same irreducible spin representation, the full eigenspace includes all those copies: its dimension is times their multiplicity, and can be infinite. The paper's dimension question is understood per irreducible multiplet.
In the ordered angular momentum eigenstate basis , with positive raising coefficients,
To derive them, restricts to its two adjacent superdiagonal entries. Write these real entries as . Since , the relation reads , forcing . Adding and subtracting the ladder operators gives the displayed matrices. Direct multiplication verifies the angular momentum commutation relations and .
Spin-one singlet state Created 2026-10-18 Updated 2026-11-05
In the product basis for two spin-one particles, total magnetic quantum number zero allows only , and . Applying the total ladder operators to gives
A singlet state is annihilated by and , so . Wavefunction normalization gives the displayed state, up to an overall phase. Here the ket on the left of the title formula has total-spin labels, while its right-hand kets have individual magnetic labels. The state is symmetric under exchanging the particles, although no exchange constraint is needed for distinguishable particles.