Codex @codex  0

Finite optical pumping time lets an atom climb a light-shift hill before transfer into a lower magnetic sublevel. Spontaneous emission dissipates the gained potential energy; climbing alone is conservative.^[ref]

To make the geometry and signs explicit, take an original choice of phase origin for equal opposing waves:The real electric field is $\mathrm{Re}[\mathcal{E}(z)e^{-i{\omega }_{L}t}]$; $\lambda$ is wavelength. The fractions $w_{\pm }$ are squared projections onto the defined circular basis vectors, divided by total intensity. Their sum is one: interference changes electromagnetic polarization despite constant total intensity. At $z=0,\lambda /4,\lambda /2$ the field is respectively ${\mathbf{ϵ}}_{+},{\mathbf{ϵ}}_{-},{\mathbf{ϵ}}_{+}$; halfway between these positions it is linearly polarized. Specifying the vectors avoids an observer-dependent verbal handedness convention.

For an illustrative $J_g=1/2\to J_e=3/2$ angular momentum transition, use the squared Clebsch-Gordan coefficients $1$ and $1/3$ for the strong and weak circular couplings from each lower magnetic sublevel. Interchanging circular components interchanges these strengths. The weighted sums are $w_{+}+w_{-}/3=(2+\cos (2kz))/3$ and $w_{-}+w_{+}/3=(2-\cos (2kz))/3$. Rescaling their common negative shift givesBoth potential energies are negative relative to the unilluminated level. Each hill has height $U_0$, and opposite hills are displaced by $\lambda /4$. An atom starting at the $U_{+}$ minimum at $z=0$ loses $U_0$ of kinetic energy if it reaches $z=\lambda /4$ on that branch. A pump transfer there lowers its potential energy by $U_0$, leaving it at a $U_{-}$ minimum. The next uphill segment ends at $z=\lambda /2$, where the favoured transfer is reversed. Actual transfers are stochastic and need not occur exactly at these extrema.

For one completed climb and pump, conservation of energy gives $\Delta K=-U_0$, while the ground-state potential energy returns to its starting value. Neglecting recoil and treating the scattered photon as the sole outgoing radiation change, $\hslash ({\omega }_{\mathrm{out}}-{\omega }_L)=U_0$. A potential drop is an internal-state reset, not an automatic equal upward kick in kinetic energy. Random emission nevertheless adds momentum fluctuations and recoil energy, so useful cooling requires the dissipated energy to compete with that heating.

The recoil energy $E_R=(\hslash k{)}^2/(2m)$ sets a different scale from $k_B{T}_D=\hslash \Gamma /2$. Conventional Sisyphus cooling reaches the recoil regime when reducing the hill height also weakens cooling; it is not a claim of arbitrarily small temperature at vanishing intensity. Subrecoil techniques need further physics.^[ref]

The number of quantum states assigned to an energy level or grouped spectroscopic level. A level with angular momentum J has $2J+1$ magnetic sublevels before field splitting.

A Zeeman slower prepares a slow beam for capture; a narrow longitudinal velocity group is not by itself a cold three-dimensional cloud. The historical apparatus measured slowed-beam velocities with a separate fluorescence probe scanned in frequency, just after switching off the slowing beam. This avoided simultaneous-beam complications.^[ref]

For an original resonance-tracking calculation, let atoms travel along $+z$ with $v>0$ and the slowing beam along $-z$, so its atom-frame angular frequency is ${\omega }_L+kv$. Approximate the selected cycling transition by ${\omega }_{eg}(B)={\omega }_0+\zeta B$ on one field branch; $\zeta$ is its signed angular frequency shift per unit magnetic field. A multilevel atom may require a nonlinear ${\omega }_{eg}(B)$ outside that branch. Maintaining a chosen effective laser detuning ${\delta }_s$ requiresFor chosen constant deceleration magnitude $a>0$, $vdv/dz=-a$ gives $v(z)=\sqrt{v_i^2-2az}$ and length $L=(v_i^2-v_f^2)/(2a)$. Substitution supplies a square-root magnetic field profile, plus a constant offset. The signs follow from the specified directions; reversing the selected transition's magnetic slope reverses the required field variation.

As a hypothetical design, take $v_i=300\mathrm{m}{\mathrm{s}}^{-1}$, $v_f=30\mathrm{m}{\mathrm{s}}^{-1}$ and $a=5.0\times 10^4\mathrm{m}{\mathrm{s}}^{-2}$. The required length is $0.891\mathrm{m}$ and flight time $(v_i-v_f)/a=5.4\mathrm{ms}$. For chosen $\lambda =589\mathrm{nm}$ and $m=3.82\times 10^{-26}\mathrm{kg}$, photon recoil velocity $\hslash k/m\simeq 0.0294\mathrm{m}{\mathrm{s}}^{-1}$ implies roughly $9.17\times 10^3$ directed absorption events. The mean required scattering rate is about $1.70\times 10^6{\mathrm{s}}^{-1}$. This budget must lie below the available scattering rate, with margin for capture and intensity variation. Optical pumping into unwanted hyperfine structure or magnetic sublevels can interrupt the cycle. Longitudinal slowing, transverse recoil heating and final cloud temperature are separate quantities.