In neutron detection by proton recoil, a neutron strikes a hydrogen atomic nucleus, namely a proton, and the moving proton produces detectable ionization. Paraffin wax provides many hydrogen targets. There are two distinct questions: how much kinetic energy can a collision transfer, and how often does it occur? Elastic collision kinematics answers the first. It does not determine a collision cross-section or a detector's efficiency.
For the following derivations the target is initially at rest in the laboratory but is free to recoil. Its mass is finite. In particular a proton must not be treated as an immovable target. All massive particles are nonrelativistic particles, their translational kinetic energies are , and the collision changes no internal state. Target binding and thermal motion are neglected relative to the incident kinetic energy. These assumptions suit an introductory description of fast-neutron elastic collisions; they do not cover every neutron capture or other nuclear reaction.
Let a projectile have mass , incident speed , and incident kinetic energy . The stationary target has mass . In a head-on elastic collision, the signed outgoing projectile velocity and target velocity obey momentum conservation and conservation of energy:
Factor the second equation and eliminate . The nontrivial collision branch has , hence
This is the maximum over scattering angles, not the energy of every recoil. To see the bound without assuming a head-on event, set the recoil momentum magnitude to and its laboratory angle to the incident direction to . Conservation of energy with outgoing projectile momentum gives
Thus for a nonzero recoil, and the endpoint occurs at .
For an original numerical example, stipulate and , with the proton mass. Approximate hydrogen, helium and nitrogen target masses by , and respectively. Their maximum fractions and recoil energies are
These stipulated values illustrate the approximation ; they are not measurements from 1932. With , the incident ratio gives , consistent with the nonrelativistic limit used here. A million electronvolts is an energy unit, whereas a mass expressed in requires the factor when inserted into an energy equation.
The hydrogen endpoint permits essentially complete transfer because the projectile and target masses match. For a very heavy target, , the fraction approaches , which is small: the target can take substantial momentum with little kinetic energy. The exact inequality follows from , which implies .
Figure 1.
Recoil energy transfer and the two-target constraint on an unseen projectile's mass
. Details.
A single recoil endpoint leaves a tradeoff between incident speed and projectile mass. Two targets can remove the unknown incident speed. Assume both runs sample the same maximum projectile speed and that single elastic collisions reach the endpoint. For initially stationary target masses , let their maximum recoil speeds be . The maximum elastic recoil energy fraction calculation gives
If energies rather than speeds are inferred, use . The energy ratio itself is not the speed ratio.
For the stipulated example, hydrogen and nitrogen give
The inferred mass then determines . Changing the assumed mass to improve one recoil endpoint changes the prediction for the other: this is the constraining power of the comparison.
James Chadwick's June paper instead used approximate endpoints and , obtaining ; it allowed roughly ten percent uncertainty in . This was a rough mass comparison.[ref]
The inverse calculation has useful built-in checks. A positive finite mass requires . As approaches , distinguishing large projectile masses becomes difficult. Differentiation gives
Uncertain recoil endpoints therefore produce an uncertain inferred mass; the collision model cannot turn imprecise range measurements into exact spectroscopy. If different target runs select different incident energy groups, the common- cancellation also fails.
For comparison, Compton scattering of a photon of energy from a stationary free target of mass has the exact relativistic endpoint
This follows by combining momentum conservation with the target's relativistic energy, maximizing transfer when the photon reverses direction. Unlike the massive-projectile calculation, this equation does not approximate the incident photon as a nonrelativistic particle.
As a separate, explicitly hypothetical test, take and target rest energies and . To reproduce the stipulated hydrogen recoil endpoint , the photon would need . The same photon would give the heavier target at most , whereas the stipulated massive projectile gave . This is the structure of a two-target discrimination, not a transcription of a 1932 measurement. Actual radiation can contain more than one energy group or both photons and neutrons; a useful model must account for the observed endpoints and their origin together.

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