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A good atomic qubit needs two reproducible, orthogonal internal states whose populations and relative quantum phase survive for many gate times. Both should be long lived, with weak spontaneous emission and little decoherence from fluctuating fields or atomic motion. Their transition must nevertheless permit fast, selective, coherent control with little leakage to other states. Reliable initialization and state-selective quantum measurement are also required; optical pumping and fluorescence readout can supply these functions.
For rubidium-87, use the two ground state hyperfine levels in the electronic configuration. The electronic angular momentum is , and addition of angular momentum to the given nuclear spin gives . A suitable Rubidium-87 clock qubit is
These are coupled electron-nucleus angular momentum eigenstates, rather than two bare nuclear-spin projections. Their hyperfine structure supplies a resolvable splitting . Both belong to the electronic ground state, avoiding a short optical excited-state lifetime. Since the weak-field Zeeman shift is proportional to , both have zero linear shift at : their rubidium-87 clock transition suppresses first-order magnetic-field dephasing near zero field. A quadratic Zeeman shift of a clock transition and differential optical shifts remain. A small stable bias field can define the quantization axis and help resolve unwanted transitions, at the cost of some residual magnetic sensitivity.[ref]
Drive the magnetic dipole transition with a resonant microwave field of suitable polarization, here , or use two phase-coherent optical fields for a far-detuned stimulated Raman transition with their frequency difference resonant with . The optical excited state is then only virtually populated, reducing spontaneous emission. In the rotating frame and rotating-wave approximation, define the drive phase by the effective Hamiltonian
Here are the Pauli matrices on the chosen qubit, and is the Rabi angular frequency. Pulse duration controls the rotation gate angle, while phase selects the axis in the equatorial plane of the Bloch sphere. A pulse exchanges the populations; a pulse makes an equal quantum superposition from either basis state. Controlled Rabi detuning, a differential energy shift, or compositions of these pulses give rotations. For example, realizes any one-qubit unitary operator up to a global phase. Thus the atomic encoding admits arbitrary single-qubit quantum gates.
Let and be normalized qubit states. By linearity, the SWAP gate gives
The output remains a product state. Single-qubit unitary operators also preserve product states, so an induction over any quantum circuit made from these operations shows that it cannot create quantum entanglement from a product state. Equivalently, moves every exchange through the local operations, leaving only local gates and a permutation of wires. This is the product-state obstruction to SWAP universality.
Consequently SWAP gates and arbitrary single-qubit gates do not form a universal quantum gate set. For example, they cannot map to the Bell state , whereas a Hadamard gate followed by a CNOT gate does so.
Use the ordered computational basis , with qubit 1 written first. The half-time gate requires a branch convention. Even stationary Hamiltonian evolution with does not uniquely specify : different accumulated eigenstate phases can agree at and differ at . In particular, both and below square to SWAP gate and leave unchanged. Adopt the conventional continuous isotropic exchange interaction branch, with a relative singlet phase increasing from to during the full pulse. This is the exchange square-root branch convention.
The symmetric and antisymmetric eigenstates
have SWAP gate eigenvalues . Let and be their antisymmetric and symmetric orthogonal projectors. The adopted exchange evolution is
For effective spin-one-half qubits, , an isotropic exchange interaction plus an energy offset that fixes the common phase. At half time choose on the symmetric sector and on the antisymmetric sector, the conventional principal square-root value of . Hence the square root of the SWAP gate is
Thus , , and , where and . The identities and verify , and the projector form proves unitarity. The endpoint truth table alone would allow other matrix square roots; the stated exchange branch supplies the additional physical assumption.
For the network, fix the Pauli Z gate, Hadamard gate and S gate conventions
The letter distinguishes this local S gate from the two-qubit exchange gate . In particular ; replacing by changes the network. Subscripts specify the acted-on qubit: , and . Operators act rightmost first, so the printed quantum circuit is
First multiply the central two exchange pulses. Since , their off-diagonal terms cancel:
This reduces the entire network to . Its action on all four computational basis states, retaining every relative quantum phase, is
Equivalently,
It flips the second qubit when the first is zero and contributes when the first is one. That conditional phase cannot be discarded as a global phase.
To obtain the standard CNOT gate controlled by qubit 1, append an gate to qubit 2 and to qubit 1. They commute, and
For control zero, undoes the original flip. For control one, it supplies the desired flip and cancels the phase because . This phase-corrected exchange network for a CNOT gate realizes the standard gate exactly with the declared conventions.
Finally, has equal Schmidt coefficients and is maximally entangled: a half exchange creates quantum entanglement although a full SWAP gate does not. More constructively, the network above produces a CNOT gate from two half exchanges and local gates. Since CNOT gates and arbitrary single-qubit unitary operators form a universal quantum gate set, the square root of the SWAP gate and arbitrary single-qubit gates are universal. The alternative inverse exchange branch remains entangling and universal, but its phases and local correction must be recomputed consistently.

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