Past exam of the mathematics course of the University of Cambridge / 2008 / iii / Paper 50 / 1

A phase diagram locates stable pure thermodynamic phases and their phase coexistence boundaries in a space of control parameters. For a concrete three-dimensional example, take the temperature, crystal-field parameter, and magnetic field of the Blume–Capel model. Its spins take values $0,\pm 1$; changing the cost of the zero-spin state can turn a continuous ordering transition into a discontinuous one. A local scalar description near the resulting tricritical point is the Landau-Ginzburg theoryThe three local control coordinates are $(r,u,h)$, with $r$ varying linearly with the thermal scaling field. For $u>0$, $h=0$, the transition at $r=0$ is continuous. For $u<0$, zero-field coexistence is at $r=3u^2/(16v)$, and the magnetization jumps between zero and $\pm \sqrt{-3u/(4v)}$. The two loci meet at $r=u=h=0$, the tricritical point.

The full three-dimensional phase diagram has an ordered coexistence sheet at $h=0$, where the two opposite magnetizations exchange stability when $h$ changes sign. On its three-phase line it meets two nonzero-field tricritical wings. These wings are first-order phase transition surfaces between minima of the same sign but different magnitude, terminating at ordinary thermodynamic critical points. Their tricritical wing critical edges are found by $V^{\prime }=V^{\prime \prime }=V^{\prime \prime \prime }=0$:Indeed $V^{\prime \prime \prime }=6uM+20v{M}^3$ fixes $M_c^2$, and substituting into $V^{\prime \prime }=0$ and $V^{\prime }=0$ gives $r_c,h_c$; $V^{\prime \prime \prime \prime }=-12u>0$ ensures a stable critical quartic minimum. The two signs give the two wings. All transition surfaces and critical edges end together at the tricritical point. The following plot uses $v=1$; its wing surfaces come from the exact tricritical wing coexistence factorization, rather than schematic unconstrained surfaces.

The unheaded requests for critical exponents follow from the uniform equation of stateFor an ordinary thermodynamic critical point, $u>0$ is fixed and $r=At$, $A>0$. At $h=0$, $t<0$, the small ordered minimum obeys $M^2\sim -r/u$, so the order-parameter critical exponent is $\beta =1/2$. Above the transition $\chi =(\partial M/\partial h{)}_{h=0}=1/r$, giving the magnetic-susceptibility critical exponent $\gamma =1$. At $r=0$, $h\sim u{M}^3$, so the critical-isotherm exponent is $\delta =3$. At the tuned tricritical point, $u=0$, instead $M^4=-r/v$ below the transition and $h=v{M}^5$ on its critical isotherm, while the disordered susceptibility remains $1/r$. ThereforeBelow the transition the inverse susceptibility is $r+3u{M}^2+5v{M}^4$, giving $2|r|$ in the ordinary limit and $4|r|$ in the tricritical limit. Thus both sides give the same susceptibility power, with different amplitudes.

To derive the general Ginzburg criterion, tune away all lower even nonlinearities and let the leading stabilizer be $v_n{M}^{2n}/(2n)$, $n\ge 2$. The equation of state gives $M_0^2\asymp |r{|}^{1/(n-1)}$, and its curvature at the ordered saddle is $2(n-1)|r|$, so $\xi \asymp |r{|}^{-1/2}$. The fluctuations of the order parameter averaged over a correlation volume are estimated by its long-wavelength quadratic covariance:The integral has a fixed dimensionless upper limit after $q=p/\xi$; this is a coarse-volume fluctuation estimate, not the ultraviolet-dominated point variance. Consequently the multicritical Ginzburg ratio isThe Landau approximation is asymptotically controlled by this test only when the ratio tends to zero. This gives the upper critical dimensionThe same threshold follows by giving $M$ its Gaussian engineering dimension $(D-2)/2$: the coupling to $M^{2n}$ has scaling exponent $D-n(D-2)=2n-(n-1)D$, which becomes relevant below $D_c$.

For $D<D_c$, the fluctuation ratio diverges and the saddle calculation cannot predict the generic interacting critical exponents. At $D=D_c$ the test is marginal, not a proof of changed power exponents: the ratio has zero thermal power and marginal interactions can produce logarithmic corrections. Thus the PDF's inclusion of equality in a blanket claim about wrong power exponents needs this qualification. The Landau-Ginzburg theory as a fluctuating field theory remains useful; what loses validity is its fluctuation-free Landau approximation.

An order parameter distinguishes phases by an equilibrium expectation value. For an Ising model, the local field $M(x)$ is the coarse-grained magnetization, and the uniform value is $M=N^{-1}⟨{\sum }_r{\sigma }_r⟩$. The spin inversion symmetry maps $M$ to $-M$, so at zero field the Landau free energy contains even powers. Its disordered minimum is $M=0$; ordered pure thermodynamic phases have $M=\pm M_0$. Their sign is selected by taking the thermodynamic limit before sending $h$ to zero. A symmetric mixture can have zero average without being a single disordered phase. The term $-hM$ identifies $h$ as the field conjugate to an order parameter.

Use the connected correlation function $G(x)=⟨M(x)M(0)⟩-⟨M{⟩}^2$ in a selected pure thermodynamic phase. The exponential correlation length is defined by ${\xi }^{-1}=-{\lim }_{|x|\to \infty }|x{|}^{-1}\log |G(x)|$, when this limit exists in the chosen direction. Linearizing the Landau-Ginzburg theory around a stable uniform minimum $M_0$ givesHence the Landau scalar correlation length is $\boxed{\xi =\sqrt{K/V^{\prime \prime }(M_0)}}$. Away from criticality the massive Gaussian field correlation tail behaves as $|x{|}^{-(D-1)/2}{e}^{-|x|/\xi }$, up to its amplitude. At a continuous transition $V^{\prime \prime }$ tends to zero, so $\xi$ diverges and fields vary on scales much longer than the lattice spacing. This motivates a gradient expansion, but the simultaneous growth of correlated fluctuations is precisely why the Ginzburg criterion must be checked.

A first-order phase transition exchanges distinct global minima of the Landau free energy; the order parameter jumps and a thermal crossing generically has latent heat. A continuous phase transition has minima merging continuously and a diverging correlation length. A local loss of stability at a spinodal point is not the equilibrium coexistence condition.

For the sextic even Landau potential, write $y=M^2$. At a nonzero zero-field stationary point, $r+uy+v{y}^2=0$. To coexist with $M=0$, also require $ry/2+u{y}^2/4+v{y}^3/6=0$. Eliminate $r$ to obtain $y=-3u/(4v)$ and $r=3u^2/(16v)$, which requires $u<0$. On this locusproving that all three equal minima are globally stable. Their curvatures are $3u^2/(16v)$ at zero and $3u^2/(4v)$ at the nonzero minima, so the correlation length is finite when $u<0$ is fixed. For $u>0$, by contrast, the nonzero minimum approaches zero as $r\uparrow 0$, giving the ordinary continuous transition. At fixed $u>0$ and $r<0$, crossing $h=0$ exchanges the two ordered minima discontinuously even though the zero-field thermal transition at $r=0$ is continuous.

Universality classes identify systems with the same long-distance renormalization-group fixed point. Spatial dimension, order parameter symmetry and number of components, and the range of interactions help determine the equilibrium class. Microscopic lattice details and many local interactions become irrelevant operators under coarse-graining. Universal quantities include critical exponents, scaling functions after fixing metric normalizations, and suitable amplitude ratios. The critical temperature, bare couplings, absolute correlation-length and susceptibility amplitudes, analytic free-energy density backgrounds, and microscopic length scales are generally not universal. Dynamic universality can additionally depend on conservation laws, so it should not be inferred solely from a static scalar potential.

A critical exponent describes the leading singular power of an observable in a specified scaling limit. The order-parameter critical exponent describes the zero-field ordered branch; the magnetic-susceptibility critical exponent describes response to its conjugate field; and the critical-isotherm exponent describes response at the critical temperature. They are found in the Landau approximation by minimizing the potential and differentiating the resulting equation of state, as calculated in the question's root solution. For a leading $M^{2n}$ stabilizer the same calculation gives $M\asymp (-r{)}^{1/(2n-2)}$, $\chi \asymp r^{-1}$ and $M\asymp h^{1/(2n-1)}$. Thus $\beta =1/(2n-2)$, $\gamma =1$ and $\delta =2n-1$. Beyond the Landau approximation, the renormalization-group relevance exponents and anomalous dimension determine the singular powers; Question 2 derives their relations. The critical exponents refer to specified paths, and tuning to a higher multicritical point requires eliminating its lower relevant perturbations.

At a tricritical point, both $r$ and $u$ vanish, while $v>0$ stabilizes the Landau free energy. It separates ordinary continuous transitions for $u>0$ from first-order coexistence for $u<0$. The zero-field order-parameter jump shrinks to zero as $u\uparrow 0$, and the tricritical wings terminate there in the full $(r,u,h)$ diagram. For $r<0$, $u=0$, minimizing gives $M^4=-r/v$ andTwo thermal derivatives give the heat-capacity critical exponent $\alpha =1/2$, compared with the finite mean-field heat-capacity jump, $\alpha =0$, at an ordinary quartic transition. The remaining tricritical mean-field critical exponents are $(\beta ,\gamma ,\delta )=(1/4,1,5)$, and the mean-field correlation-length critical exponent is $\nu =1/2$. To observe tricritical scaling one must tune the quartic scaling field as well as the thermal field: a generic path with fixed $u>0$ instead has ordinary critical behavior. Its upper critical dimension is three, as the multicritical Ginzburg ratio shows.