Spherical-particle frequency scaling. For a dielectric sphere of radius , the quasistatic electric polarizability is
The electric dipole radiation formula and give
Thus Rayleigh scattering scales as , or , when the polarizability varies slowly with frequency. Material resonances and absorption can change this simple scaling. For the incident polarization, the dipole is along : intensity is proportional to , where is the angle from . There is no radiation on the dipole axis and a maximum in the plane. In a direction the scattered electric field is along , hence linearly polarized wherever nonzero.[ref]
Figure 1.
A z-directed electric dipole radiates most strongly perpendicular to its axis and has axial zeros
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Needle model used in parts (a)–(d). Let its axis be . A very slender, high-permittivity needle has dominant longitudinal response, so use the rank-one needle polarizability . Its transverse response is neglected at leading order. For observation along , define , and
For a unit incident Jones vector , the common far-field relation is , and . Here is irradiance at distance ; multiplying by gives power per solid angle. No absolute value of is given or needed for the requested relative intensities.
Diffuse random cloud, with the incident polarization of (a). The single-particle amplitudes through and analysers are proportional to and . The isotropic orientation fourth moment gives the needle-scattering analyzer moments
For example, ; symmetry and give . Since the particles scatter mutually incoherently, intensities add. For illuminated particles,
The cross correlation vanishes by reflection symmetry. The degree of linear polarization is : random anisotropic scatterers produce partially depolarized light, even though every individual needle produces a single linear polarization.
Figure 2.
Independent isotropically oriented needles give the analyser ratio one to three, while coherent mean amplitudes have no x component
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Continuous homogeneous dielectric. One must sum amplitudes coherently and include their spatial phases, rather than retain the preceding sum of intensities. Random orientations give , so the averaged response is isotropic and its induced polarization is along . Its coherent radiation toward , when allowed by the sample geometry, is therefore purely polarized, with . The independent-needle prefactor is no longer a quantitative dense-medium model; local-field and collective effects determine the effective permittivity.
There is also coherent continuum phase matching: a uniform bulk driven by a plane wave has no arbitrary outgoing plane-wave component. In an ideal infinite homogeneous medium there is no diffuse side scattering at all; propagation, refraction and reflection are determined by the medium and its interfaces. A finite sample's coherent side signal depends on its shape and boundaries. Thus the old diffuse ratio is replaced by a coherent isotropic-medium response, not by a universal nonzero side-scattering intensity.
Using the needle definitions in the question-level solution, . The scattered field is parallel to , and
The light is linearly polarized along the needle's projection into the observation plane. Its Jones vector in the basis is whenever the intensity is nonzero. A needle perpendicular to the incident electric field, or pointing directly at the observer, has zero leading-order signal.
Now , so
Whenever nonzero, the scattered light has the same linear polarization along as in (a). Although the incident field points toward the observer, the tilted anisotropic needle can induce a dipole component perpendicular to that direction. An isotropic sphere would instead have an axial radiation zero for this incident polarization.
Choose one circular convention as with time dependence . Reversing the handedness convention changes the sign of but not the result here. The scattered complex amplitude is
The scalar factor contributes a common phase to both output components. Consequently the scattered wave is linearly polarized along , rather than circular or elliptical, with
The dominant longitudinal needle response has rank one, so both incident circular components emerge in the same real output direction.
Unpolarized incident light has equal, mutually incoherent - and -polarized intensities. Both components scatter into the same direction , so their coherency matrices add to
This matrix has rank one when the signal is nonzero. The light is therefore fully linearly polarized along , with
A fixed highly anisotropic needle can act as a polarizing scatterer even for unpolarized input. The equality of total intensities with (c) does not mean the incident states were identical. These conclusions use the leading longitudinal-polarizability approximation; finite transverse response can change the polarization purity.

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