Past exam of the physics 1 paper of the University of Oxford / 2017 resit / 9 / b / Solution

For equal masses $m$, the reduced mass is $m/2$. The kinetic energy of their centre of mass cannot be removed by an isolated collision, since total momentum is fixed. Therefore the maximum energy available for conversion to internal forms is the initial relative kinetic energy,It is attained by a perfectly inelastic collision in which the final relative velocity is zero. This concerns the convertible initial kinetic energy, not an arbitrary pre-existing internal energy reservoir.