An applied electric field displaces bound charges or reorients permanent dipoles, producing electric polarization , the dipole moment per unit volume. It gives bound charges and . Definefor a linear isotropic dielectric. Then separates free charge from the bound-charge response. Electronic, ionic and orientational electric polarization respond on different timescales; real permittivity is frequency dependent, and its dissipative part describes dielectric loss.
A uniform dielectric filling a parallel-plate capacitor raises its capacitance to . At fixed charge this reduces field energy ; at fixed voltage the stored energy increases because the voltage source supplies charge and energy. Insulation and energy storage are useful applications, limited by loss and dielectric breakdown. Static interface conditions are continuous tangential and a jump in normal equal to free surface charge.
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