Original paper: Public original, physical PDF pages 142–149.
For hydrostatic volume strain from Young's modulus and Poisson's ratio in isotropic linear elasticity, the bulk modulus is . Hydrostatic compression therefore givesHere is the pressure increase, and the negative sign denotes contraction. Equivalently each normal strain is and the three strains add. This is the small-strain isotropic model; concrete's microstructure is represented only through the supplied elastic constants.
Put line charges and on the two axes. For , the surface potentials differ byThus the capacitance per unit length in vacuum isThe two logarithms belong to one potential difference, not two independent capacitances in parallel. A homogeneous dielectric replaces by its absolute permittivity; finite radii and proximity corrections are neglected.
With the standard liquid-water approximation , each portion has mass . The equal heat capacities give final temperature by energy conservation. For an insulated mixing process with no other changes,The reversible integrals evaluate entropy differences between equilibrium states; the actual heat transfer is irreversible. These are two portions of the same substance, so there is no additional ideal-mixture compositional entropy.
Let absorbed solar flux per unit surface area be . The single-layer greenhouse model emits infrared upward and downward. Top-of-atmosphere balance gives , hence . Surface balance is , soThe layer simultaneously satisfies . This ideal radiative model excludes convection, spectral windows and atmospheric temperature structure; it is not a quantitative prediction for the real atmosphere.
For the tangent-axis inertia of a spherical shell, subtract the missing solid core from a solid sphere:The parallel axis theorem shifts the axis a distance :It tends to for a solid sphere and for a thin spherical shell.
The image charge construction replaces conductor-induced charge by fictitious sources outside the physical domain. Match the conductor potentials and the far-field condition; uniqueness then fixes the potential in the physical region. For a grounded plane, reflect a charge and reverse its sign, giving attraction . For a grounded sphere of radius , a charge at distance has image at radial distance . These are examples with prescribed zero potential, not arbitrary isolated conductors.[ref]
Use horizontal and upward in the upper right-angle wedge. The sheets meet electrically, so take their common potential as zero and assume no externally imposed field. For a real charge at , the image charges in a right-angle conducting wedge are at and , and at . The first two contributions have cancelling horizontal components. With ,Thus the force magnitude at the original height is , directed down toward the intersection. The sphere is treated as a point charge, with size much smaller than its distances from the sheets.
Since gravity is already balanced in the uncharged equilibrium, the charged vertical equilibrium satisfies . For , . Differentiating the force givesThe electrostatic softening above a conducting wedge reduces the restoring force; the small-charge vertical equilibrium remains stable.
For the lateral stability of a spring-supported charge in a wedge, the off-axis images of are at and and at . Expansion near the bisector givesSo the electrostatic force is laterally destabilizing: moving toward either sheet strengthens its attraction. In the simplified model where the spring supplies only a vertical force, the overall equilibrium is a saddle and is unstable.
A literal three-dimensional spring suspension also has geometrical transverse stiffness. If its charged-equilibrium tension is and length is , a small sideways displacement gives spring force , and stability requires , with . TODO: neither the attachment length nor a lateral stiffness is specified, so an unconditional lateral-stability verdict for that full suspension is unavailable. The saddle verdict uses the intended vertical-force spring idealization.
Original image-charge field construction and the opposite signs of vertical softening and lateral electrostatic stiffness
. Details. For distributed inductance and capacitance , a small segment obeys and . Differentiation gives and . For a forward wave,A backward voltage wave has current . This sign matters at an impedance discontinuity.
The source figure is the stacked-strip parallel-plate transmission line geometry, despite its use of the word coplanar. Gauss's law gives . Opposite surface currents give magnetic field between the strips by Ampère's law; the magnetic flux per unit length is , hence . ThereforeNo numerical is given; the impedance is appropriately left in terms of that ratio. The line is taken to be nonmagnetic and lossless.
Increasing the gap by changes to and to , so while is unchanged. voltage and current continuity at the step giveConsequently the voltage and energy-flux transmission coefficients areHere amplitudes are peak voltage amplitudes, with mean power . The reciprocal gaps have : equal reflected energy but opposite voltage phase. A voltage transmission coefficient above one does not imply energy gain.
For a finite impedance section of a transmission line, put and . Multiple reflections inside the altered section interfere. Summing their geometric series, relative to the first boundary,Transmission is unity at and minimal at , with minima . Resonances are separated by ; the long-wavelength limit also transmits fully. Matching the far termination removes end echoes, not the two internal reflections.
Original calculated power transmission through a finite changed-impedance section between matched lines
. Details. For a moving loop, Faraday's law of induction is , where is the local wire velocity, , and the oriented boundary and surface follow the right-hand rule. For a fixed loop the motional term vanishes. Lenz's law is the minus sign: the induced response opposes the change of linked flux, not necessarily the applied field itself.
Let increase downhill and choose positive current to produce an uphill magnetic force. The normal component of the imposed field is , so the changing external flux is . With initially zero current and no resistance, conservation of flux linkage gives . The rod feels gravity vertically downward, a rail reaction normal to the slope, and magnetic force of magnitude horizontally uphill. Its downhill component is ; its normal component presses the rod into the rails, giving .
The inductive oscillation of a sliding rod on inclined rails follows fromThe magnetic force is not itself parallel to the rails. Defining and , release from rest givesThe first stop occurs at ; the rod then returns and oscillates between and . At the force is zero but the speed is maximal. Mechanical potential energy is reversibly exchanged with kinetic energy and ; a perfectly conducting circuit provides no damping.
For the resistive long-time drift of an inductive sliding rod, with loop resistance , useJoule heating damps the transient oscillation. On sufficiently long rails the asymptotic motion is steady sliding, not permanent rest:The zero-resistance model has persistent oscillations; its late-time limit cannot be interchanged with taking . These results assume , smooth contacts, negligible rod self-inductance and constant geometry.
For cold, collisionless, unmagnetized electrons with stationary heavy ions, . Therefore andThis is the cold collisionless plasma dielectric response. For a propagating transverse wave, , so in vacuum and in plasma, where . Equivalently and for .
Converting the density gives , so and . At ,At an interface without independently imposed surface charge or sheet current, tangential and normal are continuous, with the electron response included in the effective permittivity. Normal need not be continuous; the induced electron charge is represented by that response. In a convention treating it explicitly as a surface charge, the normal vacuum-displacement jump equals that charge instead.
For the downward transmitted wave, transversality gives . The measured field therefore has , so and . Tangential phase matching givesFor inferring incident power from a transmitted plasma field, choose and . Their magnetic fields have opposite directions. The two tangential conditions areHence and . Since these are peak phasor amplitudes,This is incident power per area perpendicular to its propagation. Per area of the interface the incoming normal flux is . The reflected sign is a phase reversal, not negative reflected energy.
At , the relative permittivity is negative and there is no propagating transverse bulk wave. The field decays evanescently into the plasma and the ideal collisionless half-space reflects all incoming normal power. Collisions would allow absorption; a complex refractive index here does not by itself imply dissipative heating.
A fictitious force is a term required when writing Newton's second law in an accelerating frame; it comes from the coordinate choice rather than a new interaction. For axes rotating at constant about a fixed inertial origin,Apply this identity twice to position to get . Moving the last two terms to the right of gives the stated Coriolis and centrifugal forces. An accelerating origin or changing rotation rate would add further terms.
A slowly rotating fluid planet follows an equipotential of gravitational plus centrifugal potential. The centrifugal potential is , most negative at the equator. An outward equatorial shift raises gravitational potential and restores the balance, producing an oblate figure. Self-gravity also changes with the shape; no flattening coefficient follows from rotation alone without a density model.
Using local north and radial-up unit vectors, the centrifugal acceleration on a stationary mass isIt points away from the rotation axis: upward and equatorward, at angle to radial up in the northern hemisphere. Its vertical fraction of gravitational force isusing a day for this approximate number. The resultant effective weight tilts equatorward relative to radial down. A plumb-defined local vertical already follows effective gravity; the component calculation uses the spherical radial vertical. A supported stationary mass of course has zero net acceleration.
For the Coriolis deflection of vertical launch and drop, retain only first order in , use effective constant , and neglect horizontal velocities in the Coriolis term as instructed. With east positive, vertical velocity gives and no northward acceleration. For launch, and the flight time is . Integrating with zero initial horizontal velocity givesThe landing is westward. The westward velocity accumulated on ascent is only recovered on descent, so the two displacement contributions do not cancel.
For release from rest at , , , and . ThusThe drop lands eastward with one quarter the launch-return displacement magnitude. North–south corrections from horizontal Coriolis coupling are beyond the retained approximation.
Original centrifugal geometry and opposite east–west deflections for launch-return and drop trajectories
. Details. The shell theorem gives enclosed halo mass . Define . Then . Interior to the uniform halo its potential energy may be writtenOuter shells alter the additive constant, not this interior force. An actually infinite uniform mass distribution has no finite potential referenced to infinity; only local potential differences are needed here.
The central force has zero torque, so is conserved and the motion is planar. With , the effective radial potential and equation areFor circular radius , givesSet at fixed . The derivative of the right-hand side at equilibrium is , soBoth frequencies are positive, but radial and azimuthal motion no longer close with the Kepler ratio. At first order in eccentricity , one may write and . For a weak halo this is a nearly Keplerian ellipse whose apsis rotates at angular rate .
Put and . Expansion yieldsThe precession is retrograde. In cycles per unit time the precession frequency is ; per radial period the apsidal shift is . This weak-halo interpretation avoids confusing a focus-centred Kepler ellipse with the centred ellipse of a purely harmonic potential.
A normal mode is a pattern in which all coordinates share one frequency and fixed relative amplitudes. For a conservative linear system, it solves a generalized eigenvalue equation with stiffness matrix and mass matrix . For this free three-mass spring chain,Solving , for , givesTheir overall normalization is arbitrary; distinct modes are orthogonal in the mass inner product. The zero mode is rigid translation because neither end is fixed. In the antisymmetric mode the middle mass stays still, so changing its mass cannot alter the frequency. The symmetric internal mode keeps the centre of mass fixed through its middle displacement . Its frequency rises without bound as and approaches as , becoming degenerate with the antisymmetric frequency in that limit.
For equal masses put and . Positions are equilibrium positions plus displacementsThe translational mode needs the linear-in-time term; a cosine at zero frequency alone would miss arbitrary centre-of-mass velocity.
Taking the springs initially at equilibrium, the impulse gives . Their squared Euclidean norms are , so their initial kinetic energies are . Relative to total ,Subsequent motion conserves each mode's total energy, exchanging its kinetic and spring contributions. The zero-mode share remains centre-of-mass kinetic energy.
Locally, zero curl permits ; for a global single-valued potential the circulation around every noncontractible loop must also vanish. incompressibility gives . The exterior of a cylinder is multiply connected, so local irrotationality alone does not exclude a circulating solution.
For inviscid constant-density flow under conservative gravity, Euler's equation is . The identity gives, for irrotational flow,For steady flow, absorb the potential's time-only gauge term and obtain throughout the connected fluid region. Without irrotationality the steady constant need only be common along each streamline.
Use for the uniform upstream speed and take the flow along . The boundary conditions are and at infinity. A perfect inviscid model imposes no penetration, not no slip. For the intended no-circulation solution, require a globally single-valued potential, so the coefficient of is zero. The logarithmic term would be a net source and violates no penetration, so its coefficient is also zero. Growing terms with violate the uniform far field. For each remaining , the surface normal condition then forces its decaying coefficient to vanish. The terms satisfy and :An irrelevant additive potential constant is understood. At the same elevation, Bernoulli balance with the upstream stream givesThe force per unit height ispressure symmetry gives zero drag and zero lift in this zero-circulation idealization. D'Alembert's paradox is the failure of this inviscid model to represent real separated viscous wakes and their drag, not a claim that a real pole feels no force.
The zero-circulation assumption matters: leaves the stated velocity boundary conditions intact but adds to the surface tangential speed. It produces for positive counterclockwise circulation. Thus the boundary conditions alone do not justify excluding the angular term; an initially noncirculating inviscid start, or an explicitly single-valued potential, supplies the missing condition.[ref]
Flow Past a Cylindrical Obstacle by Richard Fitzpatrick. equations 5.73–5.81 and discussion after 5.83: circulation, force and the zero-circulation initial condition
For the force on a current loop in a bilinear magnetic field, the arrow gives current in the positive direction on the edge , and in the negative direction on the edge . Use . The edges on the coordinate axes contribute zero because the applied field vanishes there. The other two giveThus the force on the square itself, excluding the supply leads, isIt lies in the plane along the diagonal towards increasing and , at to either positive axis.
In the ideal semidiurnal tide model, successive high tides occur after the Earth–Moon relative angle advances by . Since the motions have the same sense, subtract their angular speeds:The lunar orbital period is sidereal, so the consistent terrestrial rotation period is . With , this gives about 12 h 25 min. The sidereal terrestrial period is distinct from the 24-hour solar day.[ref]
Earth Fact Sheet by National Aeronautics and Space Administration. Orbital parameters, sidereal rotation period 23.9345 h and length of day 24 h
If the Earth's rotation is approximated as one revolution in 24 hours, the same calculation instead gives 12 h 27 min. That small difference is the day convention, not a change of sign in the relative angular speed. Actual coastal tide times also depend on ocean dynamics and the solar tide.
For the uniform magnetic field in an off-axis cylindrical cavity, let point from the conductor's axis to the hole's axis and let the current flow in . Its uniform current density in the metal isSuperpose a complete cylinder carrying and a cylinder occupying the hole carrying . Inside a uniformly filled cylinder, Ampère's law gives . For any point in the cavity,There is no remaining position dependence, so the field is uniform. Its magnitude is , perpendicular to the axis-offset vector in the cross-sectional plane. Reversing the current reverses the field.
Use the rotating reference frame equilibrium model, in which the centrifugal potential energy of a particle of mass is . The Boltzmann distribution then givesDefine the concentration ratio as . At the axis,Thus the axis favours the lighter species. The expression assumes a dilute classical mixture at one temperature, equilibrium in the rotating reference frame, and sampling sufficiently close to .
Define , where counts particles in the level. Then , soThe binomial entropy of independent two-level particles follows from counting which of the independently labelled particles occupy each nondegenerate level. This is the usual distinguishable, or localized, two-level model; occupation constraints of a degenerate quantum gas would require different counting.
For large occupations, Stirling's approximation with givesAllowed runs from to in steps of two. Entropy is largest near equal populations and is zero when all particles occupy one level; use at the endpoints.
In vacuum, displacement current contributes the additional term :Taking the divergence and using Gauss law gives , the local conservation of charge. Without displacement current the curl equation would incorrectly require a divergence-free current even during charge accumulation.
For a charging capacitor, a surface cutting the wire carries conduction current while a surface passing through the gap carries changing electric flux. The displacement current term makes the circulation independent of the spanning surface. It is not transport of free charge across the vacuum gap. In matter the macroscopic equation is , with electric polarization included in . Together with Faraday's law of induction, the vacuum equations give electromagnetic waves of speed .
An applied electric field displaces bound charges or reorients permanent dipoles, producing electric polarization , the dipole moment per unit volume. It gives bound charges and . Definefor a linear isotropic dielectric. Then separates free charge from the bound-charge response. Electronic, ionic and orientational electric polarization respond on different timescales; real permittivity is frequency dependent, and its dissipative part describes dielectric loss.
A uniform dielectric filling a parallel-plate capacitor raises its capacitance to . At fixed charge this reduces field energy ; at fixed voltage the stored energy increases because the voltage source supplies charge and energy. Insulation and energy storage are useful applications, limited by loss and dielectric breakdown. Static interface conditions are continuous tangential and a jump in normal equal to free surface charge.
A current in one circuit links magnetic flux through another. It produces magnetic flux linkage through another. With fixed geometry and a linear reciprocal medium, choose consistent winding orientations and writeThe shared coefficient is mutual inductance; reversal of one winding reverses its sign. Faraday's law of induction gives the mutual induced emf for fixed . The minus sign expresses Lenz's law.
The magnetic energy isNonnegative energy for every current pair requires , motivating the coupling coefficient . Transformers use strong common flux to exchange energy between circuits; leakage flux reduces coupling. A shared core increases linkage, but saturation, hysteresis and eddy-current losses limit the linear description. A moving geometry also contributes to the mutual emf.
Find the potential from and . One must specify boundary data: a potential on each Dirichlet boundary, a normal displacement on each Neumann boundary, or an appropriate mixture. Conductors are equipotentials; at dielectric interfaces is continuous and the normal displacement jumps by the specified free surface charge. With no singular dipole sheet, tangential electric field is continuous.
To establish uniqueness of Poisson equation, subtract two solutions with the same charge and boundary data, writing their difference as . Integration by parts givessince . The right side vanishes for identical Dirichlet data, identical Neumann data, or their usual mixed combination. Interface terms cancel under the homogeneous difference conditions. With positive permittivity, : the field is unique, and the potential is unique if any suitable reference potential is fixed. For a pure Neumann problem an additive constant remains, and the prescribed outward displacement flux must equal the enclosed free charge. This theorem justifies image-charge solutions once their boundary data have been checked.
Magnetization is magnetic dipole moment per unit volume. In SI units,in a linear isotropic response. The internal field matters: for a uniformly magnetized ellipsoid it is . Sample shape therefore affects an apparent magnetic susceptibility.
Diamagnetism opposes the applied field, giving small negative magnetic susceptibility from the induced orbital response. It is often only weakly temperature dependent. Paramagnetism aligns pre-existing moments and gives positive magnetic susceptibility; independent localized moments obey approximately in weak fields before saturating. Pauli paramagnetism of conduction electrons is a different, weakly temperature-dependent mechanism.
Ferromagnetism involves collective exchange-driven alignment and spontaneous magnetization below the Curie temperature. A specimen can nevertheless have nearly zero total moment because magnetic domains point in different directions. Field-driven domain-wall motion and rotation change the net magnetization. Antiferromagnets have compensating ordered sublattices below a Néel temperature; ferrimagnets have oppositely ordered but unequal sublattice moments and retain a net moment. Ferrites are useful examples of electrically resistive ferrimagnetic core materials.
Ferromagnetic response is nonlinear and history dependent. A hysteresis loop displays remanent magnetization, magnetic coercivity and saturation. A single constant magnetic permeability cannot describe the entire loop: differential magnetic permeability describes its local slope. The quasistatic energy loss per unit volume and cycle is the loop area . Soft magnetic materials have low magnetic coercivity and usually high useful magnetic permeability; hard magnetic materials retain magnetization and suit permanent magnets.
An electromagnet normally uses a soft, high-permeability core to guide flux generated by a coil. For a uniform-section core with length and air gap , neglecting leakage and fringing,An air gap can dominate the magnetic reluctance even when the core magnetic permeability is large. Core saturation limits the improvement with current, while winding resistance causes heating. For alternating operation, laminations suppress eddy-current loops in metallic cores; high-resistivity ferrites also reduce those losses. Low hysteresis loss is important in repeatedly cycled cores, whereas high magnetic coercivity is valuable in a permanent magnet. Useful design therefore depends on the full magnetic response, electrical losses and operating frequency, rather than the largest quoted magnetic permeability alone.
Generalized coordinates incorporate holonomic constraints without solving separately for every constraint force. For conservative mechanics use . The principle of stationary action makes the action stationary for variations vanishing at the endpoints. Integration by parts givesThe canonical momentum is . A cyclic coordinate gives conserved ; absent explicit time dependence, is conserved. These are symmetry–conservation relationships, not assumptions that all momenta are constant. Nonconservative generalized forces enter the right side.
For example, a pendulum has , giving . The method extends directly to coupled coordinates and velocity-dependent interactions when the correct Lagrangian is used; with a position-only potential is not the most general form.
Viscosity transfers momentum between adjacent fluid layers. A Newtonian fluid has shear stress proportional to strain rate: for simple shear, . Thus parallel plates of area , separation and relative speed require force magnitude in a steady linear profile.
For an incompressible isotropic Newtonian fluid,for constant viscosity. With strain-rate tensor , the viscous dissipation rate per unit volume is . Kinematic viscosity is the momentum diffusivity: a disturbance spreads over distance of order .
The Reynolds number compares inertial and viscous forces. Small Reynolds number supports a creeping-flow approximation, while large values permit thin viscous boundary layers and possible turbulence. It does not mean molecular viscosity has disappeared. Gas viscosity results from molecular momentum transport; a liquid's microscopic transport depends strongly on intermolecular interactions. Non-Newtonian materials require a more general constitutive law.
For an attractive inverse-square potential, let the reduced mass be , potential , and nonzero orbital angular momentum . Conservation of angular momentum makes the orbit planar. The orbit equation isPositive relative energy gives and an unbound hyperbolic Kepler orbit, arriving from and returning to infinity. Its asymptotes satisfy . At infinity and for impact parameter , so the deflection angle isThis describes gravitational encounters in the Newtonian two-body approximation. The body speeds up near periapsis while total energy remains positive. It is distinct from an elliptic bound orbit and from the zero-energy parabolic limit; repulsive Coulomb scattering also gives hyperbolae but uses a different orientation of the force and orbit.
For a homogeneous isotropic solid with small displacement , linear elasticity gives . Momentum balance becomesA plane wave with displacement parallel to its wavevector is longitudinal, whereas perpendicular displacement is transverse. Writing for the bulk modulus and for the shear modulus, their bulk speeds areThere are two independent transverse polarizations. The bulk modulus supplies resistance to compression; shear rigidity supplies transverse restoring stress. An ordinary fluid has no static shear rigidity and cannot sustain these propagating bulk shear waves. A thin rod with freely contracting sides instead has longitudinal speed , because its lateral boundary conditions differ from a bulk plane wave. Reflection, refraction and mode conversion occur at interfaces; a free surface also supports Rayleigh waves.
For torque-free rotation, angular momentum is fixed in inertial space, but angular velocity need not point along it. In principal body axes,and cyclic permutations. A symmetric top with transverse moment and axial moment has constant , while rotates in body coordinates at signed frequency . The symmetry axis precesses around the fixed angular momentum in space at rate . These body-frame and space-frame rates describe different motions and need not coincide.
Poinsot construction expresses the same torque-free motion geometrically. The energy ellipsoid is fixed in the body. Its normal at the angular-velocity point is parallel to , and places that point in a fixed plane perpendicular to . The ellipsoid rolls on this invariable plane without slipping: the instantaneous velocity of its contact point is proportional to . The contact curve is the polhode on the body ellipsoid and the herpolhode on the plane.[ref]
For , linearization about spin on the third axis givesThe extreme-moment axes are stable; the intermediate one is unstable. The major-axis relaxation theorem adds weak internal dissipation while retaining negligible external torque. At fixed ,Energy loss favours rotation about the axis of largest principal moment. Here “major axis” means maximum inertia, not necessarily the body's longest geometric direction. A perfectly rigid torque-free body does not dissipatively settle; its energy is conserved. Distinguishing stability from relaxation also explains why minimum-inertia rotation can be stable in the ideal rigid model.
Forced precession occurs when an external torque changes , with . For steady precession, . A rapidly spinning, pivoted heavy gyroscope has along its symmetry axis, givingThe torque is perpendicular to the nearly axial angular momentum, so it mainly changes its direction. For a steady inclined symmetric top, the more complete condition isIt exhibits slow and fast precession branches when real solutions exist. A generic release excites nutation as well: inclination oscillates instead of staying fixed. Axis constraints and bearing forces must be included when specifying which angular momentum and pivot are being used.
For speed distribution normalized to one and isotropic directions, the incident number flux isThe positive normal velocity weights the population reaching the wall. Consequently its mean translational energy isThe bulk value would omit the arrival weighting.
For the two vessels, let , with subscripts h and c for hot and cold. Equal opposing effusion rates give . Number conservation in equal, fixed volumes adds . HenceBoth final pressures must be determined; holding the cold temperature fixed does not hold its particle number fixed.
For aperture area , the common one-way flux is . The translational heat transfer from hot to cold is thereforeThis is the total heat transfer for a monatomic gas with no active internal modes, neglecting radiation and conduction through vessel walls. For a molecular gas, add for its internal energy per molecule. The maintained unequal temperatures describe a stationary nonequilibrium state even though the net particle current is zero.
A thermodynamic potential packages the equilibrium state in variables suited to the imposed constraints. For a simple fluid, has differential . Legendre transforms give , and , with natural variables of a thermodynamic potential , and respectively. At fixed particle number, Helmholtz free energy is minimized at fixed ; Gibbs free energy at fixed .
A flow vessel is an open control volume, even if its walls are enclosed. For each inlet, pressure forces carry flow work in addition to internal energy. The steady first-law balance isWith no heat exchange, shaft work, or significant kinetic and gravitational energy differences, the enthalpy fluxes are equal. Mass flow must also balance. This equality concerns mass-flow-weighted specific enthalpies, not an unweighted sum over pipes.
Using for the printed specific enthalpy, the formal outlet mass balance givesFor fixed outlet enthalpies the greatest yield occurs at the smallest inlet enthalpy. Among the tabulated pressures this is 30 atm. Approximating the atmospheric-pressure gas enthalpy by the tabulated zero-pressure limiting value givesThis uses a low-pressure approximation: atm is not literally the zero-pressure table entry. Linear interpolation to 1 atm would instead give and . The sparse table does not determine an exact continuous optimum between entries.
TODO: a physically consistent liquid fraction requires corrected outlet conditions and their corresponding gas and liquid enthalpies. The printed claim that the outlet contains liquid at 14 K and atmospheric pressure is inconsistent with helium's critical temperature near 5.2 K and normal boiling point near 4.224 K. The formal calculation above therefore is not a physically realizable 14 K liquefaction yield; the supplied states must not be silently replaced.[ref]
A heat pump delivers : electrical work moves heat from a source as well as contributing energy itself. Its heating coefficient of performance can therefore exceed one, whereas direct resistance heating supplies at most its electrical input as useful room heat. For an ideal reversible pump,with absolute temperatures and . This is an ideal limit; actual costs also depend on compressor performance and tariffs.
For the annual ground-temperature wave, model the soil as a homogeneous semi-infinite conductor, with depth positive downward and a prescribed surface temperature. Here is thermal conductivity and is heat capacity per unit volume, so the thermal diffusivity is . Conservation of energy gives . After transients decay, put . Substitution gives ; the solution bounded at depth uses . Matching the surface then givesThis approximation identifies the ground surface with air temperature and neglects the pump's perturbation of the ground, as required by the model. The attenuation and phase delay arise from heat diffusion, not propagation at one fixed wave speed.
The graph below covers a full annual cycle. At , the amplitude is K and the minimum lags January by a quarter-year. At , the amplitude is only K and the minimum lags by half a year: the ground is slightly warmer than its annual mean in January.
Annual air and ground temperatures, with attenuation and depth-dependent phase delay
. Details. The seasonal source depth for a reversible heat pump has a subtle limit: a deep source approaches and avoids severe winter cooling, but infinite depth is not the thermal optimum of this single-frequency model. In January, with , maximize . The first and largest maximum is at , where , giving and . It is also the optimum of the ideal annually integrated heating work: the heating load is even about January, so its weighted sine term integrates to zero and the depth dependence is again proportional to . Installation cost, finite tube spacing, heat extraction, weather and real pump performance alter this result. The supplied model therefore supports a finite seasonal thermal optimum, while not fixing a practical burial depth in metres.
The coldest day has outside temperature , so the indoor–outdoor temperature difference is 25 K. If is the building's heat-loss coefficient, the required heating rate is . For direct electrical heating,This sets the reference electrical cost for the same delivered heat and tariff.
For the ideal reversible comparison, K and the coldest air source is K. ThusA real air-source pump uses more work than this reversible lower bound, and its low-temperature performance is not specified.
A source much deeper than the annual penetration depth has K. ThereforeThe ideal coldest-day electrical-input ratios are direct : air-source : deep-ground = 1 : 0.0853 : 0.0171. The deep source needs one fifth of the ideal air-source work. These ratios compare equal useful heating, and do not include excavation, circulation losses or an assumed real compressor efficiency.
Phase equilibrium minimizes Gibbs free energy at specified temperature, pressure and composition. Coexisting phases have equal temperature, pressure and chemical potential. For a pure substance, a first-order transition has continuous equilibrium Gibbs free energy but a jump in its first derivatives, such as entropy or volume; the latent heat is . Continuous transitions lack that latent heat and can instead have singular or discontinuous higher responses.
The van der Waals molar equationcombines an excluded-volume correction with attractive interactions. Its inflection conditions giveBelow , the oscillatory isotherm contains a mechanically unstable segment with . Equilibrium instead replaces the loop by a constant-pressure coexistence line. Equality of chemical potentials gives the Maxwell construction,On isothermal compression the gas reaches saturation, then converts progressively into liquid at fixed pressure. The mean molar volume obeys , where is the gas fraction. Metastable superheated or supercooled states can persist when nucleation is delayed; they are not the global equilibrium selected by this construction.
Illustrative reduced van der Waals coexistence and a generic pure-substance phase diagram
. Details. A pressure–temperature phase diagram contains coexistence curves separating solid, liquid and gas. Three phases meet at a triple point; the liquid–gas coexistence curve ends at a thermodynamic critical point, above which liquid and gas can be connected without crossing a first-order phase boundary. A generic solid–liquid line continues beyond the liquid–gas critical temperature. For one component the Gibbs phase rule is , so a three-phase equilibrium fixes both temperature and pressure.
Along a two-phase coexistence curve, for each phase givesThis is the Clapeyron equation, valid with consistent molar or specific quantities. For vaporization, neglecting the liquid volume and treating the vapour as ideal gives , hence . With approximately constant molar latent heat,This Clausius–Clapeyron approximation explains the rapid rise of vapour pressure with temperature. It fails close to the thermodynamic critical point, where phase volumes converge, and is not a universal expression for melting. The sign of a melting-line slope depends on its volume change; water's denser liquid gives a familiar negative slope.
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