Past exam of the physics course of the year 1 of the natural sciences course of the University of Cambridge / 2018 / Section D / 13

Equation and interpretation. The supplied equation is the Time-independent Schrödinger equation for a nonrelativistic particle with mass $m$ in a prescribed potential energy $V(x)$. Equivalently,It is an eigenvalue problem for the Hamiltonian operator. A stationary energy state has full wavefunction $\Psi (x,t)=\psi (x)e^{-iEt/\hslash }$. By the Born rule, $|\psi (x){|}^{2}dx$ is the probability of finding the particle in a small interval $dx$, with wavefunction normalization ${\int }_{-\infty }^{\infty }|\psi {|}^{2}dx=1$.

Infinite barriers. Infinite exterior potential energy excludes any finite-energy probability outside the interval. The infinite square well consequently has $\psi =0$ outside and the hard-wall boundary conditionsThe interior wavefunction must meet the zero exterior amplitude continuously. Its derivative need not be continuous across an infinite wall; imposing both zero value and zero derivative would eliminate every nonzero interior solution.

Ground state. Inside the well $V=0$, so ${\psi }^{\prime \prime }+k^2\psi =0$, with $k=\sqrt{2mE}/\hslash$. Its general solution is $A\sin kx+B\cos kx$. The left wall gives $B=0$, and the right wall gives $ka=n\pi$ for $n=1,2,\dots$. Thus the discrete energy eigenvalues are $E_n=n^2{\pi }^2{\hslash }^2/(2m{a}^2)$. The smallest, $n=1$, is the ground state. Sinceits normalized wavefunction, choosing an irrelevant overall phase to make it positive inside, is

Finite barriers. For a finite step and constant particle mass, both $\psi$ and ${\psi }^{\prime }$ are continuous at $x=0,a$. Wavefunction matching at a finite potential step follows by integrating the Schrödinger equation across a vanishingly small neighborhood of the step: a bounded potential cannot generate a finite jump in ${\psi }^{\prime }$. The bound-state exterior solutions decay rather than vanish identically:Normalizability excludes the growing exterior exponentials. The equivalent interior boundary conditions are ${\psi }^{\prime }(0)=\kappa \psi (0)$ and ${\psi }^{\prime }(a)=-\kappa \psi (a)$; neither boundary value is zero for the nontrivial ground state.

The ground state of a finite square well remains symmetric about $a/2$ and has no nodes. It bends smoothly into exponential tails at both walls, extending over a larger region than the infinite-well state. Its maximum after normalization is lower for the deep well considered here. When $V_w\gg E$, the penetration length $1/\kappa$ is short, so the two shapes are close except near the walls and in the exterior tails.

The finite curve is an illustrative exact matched solution with $V_w=10E_{1,\infty }$; no numerical wall height is specified by the question.

Energy comparison. The finite barriers relax the confinement, allowing a less rapidly varying interior wavefunction and therefore smaller kinetic energy. More explicitly, the even interior solution is proportional to $\cos [k(x-a/2)]$, and matching to the tails gives $k\tan (ka/2)=\kappa$. The lowest root lies at $0<ka<\pi$, while the infinite well has $ka=\pi$. HenceAs $V_w\to \infty$, the tails disappear and the finite-well energy approaches the infinite-well value from below. This comparison uses the same zero of potential energy inside both wells.