Away from x=x′, an outgoing solution has form G=Ceik∣x−x′∣. Integrate the differential equation across x′ to get G+′−G−′=−2m/ℏ2. Since the derivative jump is 2ikC, C=im/(kℏ2). ThusContinuity excludes a derivative-of-delta contribution. The outgoing condition, equivalently the appropriate limiting resolvent, removes the arbitrary incoming homogeneous solution.
G+(x,x′)=kℏ2imeik∣x−x′∣.
Write the full equation as Lψs=−Uψs. Apply the outgoing inverse of L and add the incident homogeneous solution with unit left-incident amplitude. This givesFor sufficiently short-range potentials this is the outgoing Lippmann-Schwinger equation. The minus sign follows from the definition L=H0−E, rather than E−H0.
ψs(x)=eikx−kℏ2im∫eik∣x−x′∣U(x′)ψs(x′)dx′.
As x→−∞, the scattered kernel is e−ikxeikx′; as x→+∞, it is eikxe−ikx′. Therefore ψs∼eikx+re−ikx on the left and teikx on the right, withEqual asymptotic wavenumbers give R=∣r∣2, T=∣t∣2. Squaring the first amplitude proves the requested expression. These are current ratios, which would require a velocity factor if the two asymptotic potentials differed.
r=−kℏ2im∫eikx′U(x′)ψs(x′)dx′,t=1−kℏ2im∫e−ikx′U(x′)ψs(x′)dx′.
Put β=mα/ℏ2. The delta interaction reduces the integral equation to ψs=eikx+iβeik∣x∣ψs(0)/k. At zero, ψs(0)=(1−iβ/k)−1. HenceTheir sum is one, as required for a real potential. The explicit wave is the indicated incident-plus-reflected form for x<0 and teikx for x>0; it is continuous and has derivative jump −2βψ(0).
t=k−iβk,r=k−iβiβ,T=k2+β2k2,R=k2+β2β2.
The first Born approximation substitutes the incident wave for the exact wave inside the scattering integral. ThusFor the attractive delta this is β2/k2, the leading small-β/k expansion of the exact result. Physically one neglects the distortion of the incident state by repeated interaction with the potential. At low k the Born result can exceed one, while the exact reflection remains bounded and approaches one; it is not valid in that limit.
RB=k2ℏ4m2∫e2ikxU(x)dx2.
For E=−ℏ2κ2/(2m), the decaying Green's function is me−κ∣x−x′∣/(κℏ2), with the same derivative jump as before. A normalizable negative-energy state has no incident homogeneous part. Applying the inverse to Lψ=−Uψ givesThe condition κ>0 is necessary for decay on both sides.
ψ(x)=−κℏ2m∫e−κ∣x−x′∣U(x′)ψ(x′)dx′.
At the delta potential, the bound equation becomes ψ(x)=βψ(0)e−κ∣x∣/κ. A nonzero solution therefore requires κ=β, givingThere is one bound level. The transmission amplitude t(k) has its physical-sheet pole at k=iβ, which produces exactly this decaying state. The real-axis probability's rational continuation T(k)=k2/(k2+β2) has both +iβ and −iβ poles; the lower pole is not an additional bound state. It is essential to distinguish the analytic amplitude from an even continuation of its modulus squared.
Eb=−2ℏ2mα2,ψb(x)=βe−β∣x∣.
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