The Bohr model assumes Coulomb attraction and classical circular motion between transitions; selected stationary orbits do not radiate; their angular momentum is mvr=nℏ; and a transition exchanges a photon of energy hν=Ei−Ef. The first two dynamical equations giveHere n=1,2,…, m is the electron mass under the fixed-proton approximation, e its charge magnitude, and ϵ0 the vacuum permittivity. The stationary-orbit postulate deliberately suspends the classical radiation prediction; this is a historical model, not a consistent deduction from classical electrodynamics.
rmv2=4πϵ0r2e2,mvr=nℏ⟹rn=me24πϵ0ℏ2n2.
Substitute the quantized radius in mvr=nℏ to get vn=e2/(4πϵ0ℏn). Coulomb potential energy is −e2/(4πϵ0rn) and the stipulated virial relation makes the total one half of this value. HenceThe negative sign means a bound state relative to a separated stationary proton and electron.
vn=nαc,En=−2(4πϵ0)2ℏ2n2me4=−n2Ry.
The emitted photon has energy E3−E2=Ry(1/4−1/9)=5Ry/36. ThereforeThis is the Balmer-alpha transition in this approximation. Absorption in the reverse direction has the same photon energy; fine structure and radiative corrections are beyond the model.
λ=5Ry36hc≃656 nm.
Separate center-of-mass motion and replace m by the reduced mass μ=mM/(m+M) in the relative-coordinate formulas. Then rn is the proton-electron separation, energy levels and the Rydberg constant scale by μ/m, and transition wavelengths increase by m/μ. The electron's own orbital radius about the center of mass is Mrn/(M+m); the proton radius is mrn/(M+m). The relative speed retains αc/n, while the electron's individual speed acquires M/(M+m). Replacing the mass in the radius alone but leaving energies unchanged would be inconsistent.
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