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A meson has quark model flavour content $q_i{\bar{q}}^j$, so four quark flavours give sixteen flavour states inThis counts a flavour set for a specified spin and orbital assignment; it does not count every excited meson. Three quark flavours instead give the familiar nine states $3\otimes \bar{3}=8\oplus 1$.

Taking the fourth quark to be the charm quark, the first nine combinations $q_{\alpha }{\bar{q}}^{\beta }$, with $\alpha ,\beta \in \{u,d,s\}$, are the light sector. The extra seven are $q_{\alpha }\bar{c}$ in $3$, $c{\bar{q}}^{\alpha }$ in $\bar{3}$, and $c\bar{c}$ in $1$ under light-flavour $SU(3)$. For the lowest pseudoscalar mesons, the open-charm states are the three D meson/Ds meson states and their antiparticles, and the hidden-charm state is the eta c meson. The two neutral trivial representation states can mix when the flavour symmetry is broken.

The intended limitation is the accuracy of flavour symmetry: the charm quark is much heavier than the three light quarks, so a quark mass term is far from $SU(4)$ invariant. Exact flavour $SU(4)$ would relate light and charmed states with the same spin, contrary to their large observed mass splittings. However, saying that a four-flavour quark model is never considered would be too strong: flavour $SU(4)$ is used as classification bookkeeping, with much stronger symmetry breaking than light-flavour $SU(3)$.^[ref] This is a flavour special unitary group, distinct from the three-colour gauge group of Quantum chromodynamics.

Represent a quark-antiquark state by a matrix $F$ with $q_i{\bar{q}}_j\leftrightarrow E_{ij}$. Under flavor symmetry, $F\mapsto UF{U}^{†}$, so an infinitesimal generator acts by $[T,F]$. The minus sign in this commutator is the antiquark transformation law; acting on the quark alone would miss states.

Start from ${\pi }^{+}=E_{ud}$. Three useful first steps areFurther actions give $[I_{-},E_{us}]=E_{ds}=K^0$, $[I_{-},E_{sd}]=-E_{su}=-K^{-}$ and $[I_{-},{\pi }^0]=\sqrt{2}{E}_{du}=\sqrt{2}{\pi }^{-}$. Overall phases are conventional. FinallyThus the second neutral octet state is obtained by removing the known ${\pi }^0$ component. Equivalently it is the normalized diagonal state orthogonal to both ${\pi }^0$ and the singlet. The full meson octet isTheir flavour matrices are traceless; the independent singlet is ${\eta }_1=(u\bar{u}+d\bar{d}+s\bar{s})/\sqrt{3}$. The source uses ${\eta }^{\prime }$ for this ideal singlet. That notation is a basis convention here: the physical eta and eta prime mesons is not an exactly pure singlet because physical neutral pseudoscalar mesons mix.^[ref]

The neutral vector mesons with isospin zero have the same conserved quantum numbers, so an off-diagonal mass matrix can mix the singlet $V_1=(u\bar{u}+d\bar{d}+s\bar{s})/\sqrt{3}$ and octet $V_8=(u\bar{u}+d\bar{d}-2s\bar{s})/\sqrt{6}$. Choose phases such thatAt the ideal mixing angle $\tan \theta =1/\sqrt{2}$, or $\theta \simeq 35.3^{\circ }$, these becomeThe overall sign of $\varphi$ is unobservable. The omega meson near $782\mathrm{MeV}$ decays predominantly to three pions, whereas the phi meson near $1020\mathrm{MeV}$ strongly favours kaon-antikaon channels when they are open. Suppression of its nonstrange channels agrees with the OZI rule and a predominantly strange state. The omega meson is below the two-kaon threshold, so its absence of that channel alone would not establish the mixing angle; masses and the broader decay pattern provide the evidence together.^[ref]