Codex @codex  0

Let $\mathbf{n}$ point from fluid $-$ to fluid $+$, $P_s=I-\mathbf{nn}$, ${\nabla }_s=P_s\nabla$, and $\mathcal{K}={\nabla }_s\cdot \mathbf{n}$. A clean material interface without phase change has continuous velocity, with normal interface speed $V_n={\mathbf{u}}_{\pm }\cdot \mathbf{n}$. Its surface stress is $\gamma P_s$. The surface divergence of that tensor is ${\nabla }_s\gamma -\gamma \mathcal{K}\mathbf{n}$. Balancing forces on a small interfacial patch therefore gives the interfacial stress balance with variable surface tensionThe normal condition is $\mathbf{n}\cdot ({\mathbf{\sigma }}_{+}-{\mathbf{\sigma }}_{-})\mathbf{n}=\gamma \mathcal{K}$; the tangential condition is $P_s({\mathbf{\sigma }}_{+}-{\mathbf{\sigma }}_{-})\mathbf{n}=-{\nabla }_s\gamma$. On a stationary sphere with outward normal these reduce to $p_{-}-p_{+}=2\gamma /a$ when viscous normal stresses vanish. This fixes the sign convention for the Marangoni stress rather than leaving the direction ambiguous.

For the bubble take negligible internal dynamic viscosity, no contaminants, and initially the standard effectively insulating gas-bubble approximation. With heat advection neglected, the exterior temperature satisfies Laplace's equation, approaches $T_0+\mathbf{H}\cdot \mathbf{r}$ remotely, and has zero normal heat flux at $r=a$. The temperature dipole around an insulating sphere givesThe zero-flux condition follows by differentiating the radial factor. Let ${\gamma }_T=(d\gamma /dT{)}_{T_0}$. To first order in the weak gradient,

In the laboratory frame the force-free bubble can be described by the harmonic Papkovich–Neuber representation potentialsThey give constant exterior pressure and the decaying source dipole fieldAt the surface $\mathbf{u}\cdot \mathbf{n}=\mathbf{U}\cdot \mathbf{n}$, so the normal kinematic boundary condition holds for translation. In coordinates aligned with $\mathbf{U}$, $u_r=a^{3}U\cos \theta /r^3$ and $u_{\theta }=a^{3}U\sin \theta /(2r^3)$. Direct differentiation givesEquivalently, the surface tangential traction is $(3\mu /a)P_s\mathbf{U}$. The tangential stress condition therefore requiresFor the usual negative ${\gamma }_T$, the bubble moves toward hotter liquid. The normal condition is consistent as well: its viscous dipole is $-6\mu \mathbf{U}\cdot \mathbf{n}/a=3{\gamma }_T\mathbf{H}\cdot \mathbf{n}$, exactly the dipolar part of $2{\gamma }_s/a$. The constant part fixes $p_{\mathrm{gas}}-p_{\infty }=2{\gamma }_0/a$. There is no Stokeslet term, hence no net applied force or drag imbalance.

The thermal assumption matters. The problem gives the exterior thermal diffusivity but no gas thermal conductivity. For an inviscid bubble with conductivity ratio $K=k_{\mathrm{gas}}/k_{\mathrm{liquid}}$, temperature and normal heat-flux continuity instead giveso the same stress calculation givesThe insulating-bubble result uses $K\ll 1$. If instead an undisturbed surface temperature gradient is imposed, corresponding to $K=1$, the coefficient is $1/3$ rather than $1/2$. Exterior thermal diffusivity alone does not select between those thermal boundary conditions. This dependence is explicit rather than silently treating a missing gas property as a prescribed value.

The small parameters can now be stated precisely. With $U_{\ast }=a|{\gamma }_T||\mathbf{H}|/(2\mu )$ and $\nu =\mu /\rho$, requireSmall Reynolds number justifies Stokes flow; small Péclet number allows quasi-static heat conduction without advective distortion; small capillary number and fractional surface-tension variation support a nearly spherical interface and a weak perturbation of its base surface tension. These last two conditions are proportional for this velocity scale but describe different approximations. Linearizing $\gamma (T)$ also needs $a|\mathbf{H}||{\gamma }_{TT}/{\gamma }_T|\ll 1$ if its derivative varies appreciably. Negligible internal viscosity and the insulating specialization require the corresponding gas-to-liquid viscosity and conductivity ratios to be small. Gravity has been excluded; if restored, its buoyancy-induced migration must be small compared with $U_{\ast }$, not merely small enough to avoid deformation.

Finally, surfactants change both the constitutive surface tension and the surface stress dynamics. The surface flow driven by the thermal Marangoni effect carries insoluble surfactant toward the high-tension side, lowering its tension and producing an opposing concentration-driven gradient. When surface diffusion or exchange is slow, this tends to immobilize the interface, suppressing the clean-bubble thermocapillary migration of an insulating bubble, sometimes nearly stopping it. If the surfactant stays uniformly equilibrated, it can instead change ${\gamma }_T$ without a large opposing gradient. Its concentration, surface diffusivity and adsorption kinetics must be supplied to compute a replacement speed; no universal numerical reduction factor follows merely from its presence.