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For an interface between two lossless, isotropic, nonmagnetic media with unequal refractive index values $n_1,n_2$, Brewster's angle is the incidence angle at which the reflected amplitude in transverse magnetic polarization vanishes. The Fresnel equations and Snell's law give $\tan {\theta }_B=n_2/n_1$; the reflected and transmitted rays are perpendicular there. The usual formula assumes equal magnetic permeabilities.

Field equations. In a homogeneous source-free nonmagnetic medium, $\mathbf{D}=ϵ{\epsilon }_0\mathbf{E}$ and $\mathbf{B}={\mu }_0\mathbf{H}$. Maxwell's equations becomeThe first equation follows from $\nabla \cdot \mathbf{D}=0$ for spatially constant nonzero $ϵ$. When the effective relative permittivity is negative below, its charge response is already included in $\mathbf{D}$; it must not also be counted as an extra free source.

Amplitude relations and bulk dispersion. Work with complex phasors proportional to $e^{ikx-Kz-i\omega t}$. For $\mathbf{H}=(0,H_y,0)$, the Ampere-Maxwell law givesso the amplitudes must obeyThey are not arbitrary independent constants: the dispersion relation alone would not make arbitrary amplitudes satisfy the equations. These relations give $ik{E}_x-K{E}_z=0$, so the electric divergence vanishes; the magnetic divergence vanishes because there is no $y$ dependence. The only nonzero component of Faraday's law of induction isSubstitution then givesThis proves that all four field equations hold for the specified transverse magnetic polarization when both the amplitude relations and the dispersion relation are imposed.

Interface matching. Let region 1 be vacuum above the interface, with ${ϵ}_1=1$, $K={\beta }_1>0$; region 2 has ${ϵ}_2=ϵ$, $K={\beta }_2<0$. These signs make the evanescent fields decay as $z\to \pm \infty$. In the absence of free surface current, tangential $H_y$ is continuous, giving a common interface amplitude. Tangential $E_x$ is also continuous, henceNormal $D_z$ is continuous as well: both sides have $D_z=-k{H}_y/\omega$. This does not require $E_z$ itself to be continuous; the material can have polarization surface charge. The normal magnetic field is zero on both sides.

Existence and surface dispersion. The opposite signs of ${\beta }_1$ and ${\beta }_2$ require $ϵ<0$. The two bulk equations areUse ${\beta }_2^2={ϵ}^2{\beta }_1^2$ to eliminate the decay constants. For the nontrivial interface branch,A positive ${\beta }_1^2$ together with real propagating $k$ gives $ϵ<-1$. A negative permittivity between $-1$ and zero is insufficient. This lossless planar surface-plasmon dispersion describes a surface plasmon polariton; $ϵ=1$ would instead be identical media and supplies no decaying bound mode.

Frequency range and long wavelengths. With $ϵ=1-{\omega }_p^2/{\omega }^2$, the existence condition becomesThe upper value is a limiting frequency approached as $k\to \infty$, not an attained maximum at finite $k$. Substitution into the dispersion relation givesFor $\omega \ll {\omega }_p$, choosing propagation in the positive $x$ direction,It approaches the vacuum light line from larger $k$. The vacuum decay constant is then ${\beta }_1\simeq {\omega }^2/(c{\omega }_p)$, so confinement becomes weak at low frequency. This calculation assumes the stated real, lossless effective permittivity; dissipation would require complex propagation and decay constants.

For the usual hollow rectangular electromagnetic waveguide, let the propagation axis be $z$ and the interior be $0<x<a$, $0<y<b$. A transverse magnetic polarization has $B_z=0$ and $E_z\ne 0$. At a perfect conductor wall the tangential electric field vanishes. Since $E_z$ is tangential to all four side walls, it satisfies a homogeneous Dirichlet boundary condition around the rectangle.

Separating the transverse Helmholtz equation therefore gives the transverse magnetic mode of a rectangular waveguideA zero value of either index makes $E_z$ identically zero, rather than producing a nonzero field uniform along that direction. The transverse electric and magnetic fields of this TM family are obtained from transverse derivatives of $E_z$, so they also vanish. Thus both TM indices must be nonzero: neither ${\mathrm{TM}}_{n0}$ nor ${\mathrm{TM}}_{0m}$ exists in this rectangular hollow-guide model. In contrast, transverse electric modes obey a Neumann boundary condition on $B_z$ and may have one zero index. The claim is about this waveguide geometry, not all possible guides.

Assume a hollow, perfectly conducting rectangular electromagnetic waveguide filled with air approximated by vacuum. Let its wider side be $a=0.040\mathrm{m}$ and its narrower side $b=0.020\mathrm{m}$. The longitudinal propagation constant of a mode isso the waveguide cutoff frequency isFor a mode with transverse electric polarization, one of $m,n$ may vanish, but they cannot both vanish. For a mode with transverse magnetic polarization, both must be positive. A single hollow conducting guide has no transverse electromagnetic mode with zero cutoff.

The lowest cutoff therefore belongs to the ${\mathrm{TE}}_{10}$ mode, varying across the wider side:Strictly, a traveling mode transporting energy down the guide requires $f>f_c$. At exactly $f_c$, $k_z=0$ and the axial group velocity vanishes. Below cutoff the field is evanescent. A different dielectric filling would replace $c$ by the wave speed in that material.

An incident electromagnetic wave generally produces reflected and transmitted waves because the two media have different electromagnetic response. Consider a flat interface between homogeneous, linear, lossless media with permittivities ${ϵ}_j$ and magnetic permeabilities ${\mu }_j$. Their wave speeds and wave impedances areFor each plane electromagnetic wave, $\mathbf{H}=\hat{\mathbf{k}}\times \mathbf{E}/Z_j$. With no free surface charge or current, the interface conditions for electromagnetic fields require continuous tangential $\mathbf{E},\mathbf{H}$ and normal $\mathbf{D},\mathbf{B}$. Equality of the phase at every point on the boundary gives equal angular frequencies and tangential wavevectors. Hence the reflection angle equals the incidence angle and Snell's law iswhere $n_j=c/v_j$ and each angle is measured from the normal.

At normal incidence use the same tangential axis for all electric amplitudes. The two independent boundary equations areSolving gives the amplitude Fresnel equationsFor nonmagnetic media, these become $r=(n_1-n_2)/(n_1+n_2)$ and $t=2n_1/(n_1+n_2)$. Reflection into a medium of larger refractive index therefore reverses the electric amplitude's sign at normal incidence.

The normal Poynting vector determines the reflected and transmitted fractions of incident power. At normal incidence,It is the power fractions, rather than the squared electric amplitudes alone, that add to unity.

At oblique incidence separate transverse electric polarization ($s$, electric field perpendicular to the incidence plane) from transverse magnetic polarization ($p$, electric field in that plane). For nonmagnetic media, writing $c_i=\cos {\theta }_i$ and $c_t=\cos {\theta }_t$, the Fresnel equations areHere choose a common $s$ direction and, for each ray, the $p$ direction as $\hat{\mathbf{s}}\times \hat{\mathbf{k}}$. This makes the reflected $p$ basis reverse its tangential direction at normal incidence, explaining why the displayed $r_p$ then has the opposite sign to $r_s$. Physical reflectance is independent of this sign convention. For either polarization with propagating transmission,For $p$ polarization, zero reflection occurs at the Brewster angle $\tan {\theta }_B=n_2/n_1$. If $n_1>n_2$, incidence above the critical angle for total internal reflection $\sin {\theta }_c=n_2/n_1$ produces an evanescent field in total internal reflection and $\mathcal{R}=1$ for an isolated lossless interface. A lossy second medium requires complex response coefficients and an absorption term in the energy balance.

For a ray meeting an interface at nonzero incidence angle, the plane spanned by the incoming wavevector and the surface normal. transverse electric polarization has electric field perpendicular to this plane, while transverse magnetic polarization has electric field in it. At exact normal incidence, the surface normal and ray alone do not select a unique plane.

The high-pressure limit of the slow magnetosonic wave approaches an incompressible polarization in the plane of the background magnetic field and wavevector, perpendicular to the latter. It has the displayed leading dispersion relation, the same as the out-of-plane Alfvén wave. Magnetic tension is the restoring force, and pressure balances the compressive component of the magnetic force. In exactly incompressible homogeneous ideal magnetohydrodynamics it is one of the two transverse magnetic polarizations.

A transverse magnetic polarization electromagnetic wave bound to an interface through coupling to the material's collective charge response. Its fields propagate along the interface and decay away from it on both sides. In an ideal nonmagnetic lossless planar vacuum-material interface, a real negative relative permittivity below $-1$ supports the bound branch described by the lossless planar surface-plasmon dispersion. Material losses generally make the propagation constant complex.

In a hollow rectangular electromagnetic waveguide with perfect conductor walls and axis $z$, a transverse magnetic polarization has $B_z=0$ and a nonzero longitudinal electric field $E_z$. The wall boundary conditions impose $E_z=0$ around the transverse rectangle. Separation of variables therefore gives $E_z=E_0\sin (n\pi x/a)\sin (m\pi y/b)e^{i(k_{z}z-\omega t)}$, with $n,m\ge 1$. Setting either index to zero makes the entire field vanish. Thus there is no ${\mathrm{TM}}_{n0}$ or ${\mathrm{TM}}_{0m}$ branch. The transverse eigenvalue is $k_{\perp }^2=(n\pi /a{)}^2+(m\pi /b{)}^2$, with dispersion relation ${\omega }^2/c^2=k_z^2+k_{\perp }^2$. This exclusion is specific to this geometry and these boundary conditions.

Relative to a propagation plane, transverse magnetic polarization has its magnetic field perpendicular to that plane. At a perfectly conducting corrugation its scalar magnetic component obeys a Neumann condition. It reduces to a scalar two-dimensional problem, but not to the Dirichlet problem for the transverse electric component.