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The reduction in size across the lanthanide series associated with incomplete screening by electrons; it contributes to size similarities and contractions in subsequent elements.
A periodic trend is a systematic variation in an atomic or chemical property across the periodic table. Examples include atomic size, ionization energy, and electronegativity.
Electron-shell filling, screening, and nuclear charge help explain broad patterns, but definitions and exceptions matter. An atomic radius inferred from a covalent bond is not the same measurement as an ionic radius in a crystal, so trends should compare like quantities.
A lanthanide is an element in the series from lanthanum, atomic number 57, through lutetium, atomic number 71. The progression is associated with filling the 4f shell and the systematic size change called the lanthanide contraction.
Many lanthanides favour trivalent ions with similar coordination chemistry. Their similarity makes separation demanding, while differences in ionic size and accessible oxidation states permit selectivity.
[ref]
Periodic Table by Royal Society of Chemistry. Lanthanum through lutetium, atomic numbers57–71; element properties
An actinide is an element in the series from actinium, atomic number 89, through lawrencium, atomic number 103. The series is associated with occupation of 5f-derived electronic states, although individual ground-state configurations vary.
Variable oxidation states and ionic sizes affect coordination and separation chemistry. Radioactive isotopes add a distinct nuclear aspect to applications involving nuclear fuel and waste materials.
[ref]
Periodic Table by Royal Society of Chemistry. Actinium through lawrencium, atomic numbers89–103; element properties
Experience considered from the experiencing subject's standpoint. Observable performance does not uniquely specify its qualitative character.
A bacterial cell-envelope assembly involved in oriented lateral peptidoglycan synthesis in many rod-shaped species.
Coordinating synthesis around the cell sidewall helps maintain an elongated geometry. This differs from the divisome, which constructs the new boundary at a division site. Defects in elongation and division can therefore produce different changes in cell shape. [ref]
Molecular Biology of the Cell, 4th edition by Bruce Alberts and others. Chapter 1, Prokaryotic cell organization and growth
For with , the eigenvalues are and the projectors are . A normalized eigenstate has . At the spectrum is degenerate and that direction is undefined.
For diffusion constant , Gaussian increments have variance . Their convolution gives a path weight proportional to with measure factor for slices. The continuum kinetic action is notation for this limiting measure; typical Brownian paths have no ordinary derivative.
In a bosonic coherent-state path integral, coherent-state resolutions between imaginary-time evolution factors turn a normal-ordered grand Hamiltonian into its complex symbol. Coherent-state overlaps supply the first-order temporal term. A thermal trace makes the fields periodic in imaginary time. The chemical potential couples to number, and interactions retain their normal-ordering convention.
For a one-electron P-to-S transition with nuclear spin zero, ten electric-dipole sublevel channels have finite strength at weak nonzero field. Six retain finite strength in the complete orbital-spin decoupling limit. Channel count is distinct from spectral frequency count: retaining first-order residual spin-orbit interaction energy gives five distinct frequencies, with two central channels degenerate.
Pinned article: Introduction to the OurBigBook Project
Welcome to the OurBigBook Project! Our goal is to create the perfect publishing platform for STEM subjects, and get university-level students to write the best free STEM tutorials ever.
Everyone is welcome to create an account and play with the site: ourbigbook.com/go/register. We belive that students themselves can write amazing tutorials, but teachers are welcome too. You can write about anything you want, it doesn't have to be STEM or even educational. Silly test content is very welcome and you won't be penalized in any way. Just keep it legal!
Intro to OurBigBook
. Source. We have two killer features:
- topics: topics group articles by different users with the same title, e.g. here is the topic for the "Fundamental Theorem of Calculus" ourbigbook.com/go/topic/fundamental-theorem-of-calculusArticles of different users are sorted by upvote within each article page. This feature is a bit like:
- a Wikipedia where each user can have their own version of each article
- a Q&A website like Stack Overflow, where multiple people can give their views on a given topic, and the best ones are sorted by upvote. Except you don't need to wait for someone to ask first, and any topic goes, no matter how narrow or broad
This feature makes it possible for readers to find better explanations of any topic created by other writers. And it allows writers to create an explanation in a place that readers might actually find it.Figure 1. Screenshot of the "Derivative" topic page. View it live at: ourbigbook.com/go/topic/derivativeVideo 2. OurBigBook Web topics demo. Source. - local editing: you can store all your personal knowledge base content locally in a plaintext markup format that can be edited locally and published either:This way you can be sure that even if OurBigBook.com were to go down one day (which we have no plans to do as it is quite cheap to host!), your content will still be perfectly readable as a static site.
- to OurBigBook.com to get awesome multi-user features like topics and likes
- as HTML files to a static website, which you can host yourself for free on many external providers like GitHub Pages, and remain in full control
Figure 2. You can publish local OurBigBook lightweight markup files to either OurBigBook.com or as a static website.Figure 3. Visual Studio Code extension installation.Figure 5. . You can also edit articles on the Web editor without installing anything locally. Video 3. Edit locally and publish demo. Source. This shows editing OurBigBook Markup and publishing it using the Visual Studio Code extension. - Infinitely deep tables of contents:
All our software is open source and hosted at: github.com/ourbigbook/ourbigbook
Further documentation can be found at: docs.ourbigbook.com
Feel free to reach our to us for any help or suggestions: docs.ourbigbook.com/#contact





