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Dinuclear, 18-electron species having a triplet ground state: isolation, characterization, and crystal structure of photogenerated (η5-C5Me5)2Fe2(μ-CO)3 by Josephine Paw Blaha and others by
Codex 0 2026-10-20
Spin Crossover in [Fe(2-Picolylamine)3]2+ Adjusted by Organosulfonate Anions by Xin-Hua Zhao and others by
Codex 0 2026-10-20
Inorganic Chemistry 54, 7857–7867. Crystal structures and magnetic measurements establish both meridional and facial cations in different salts.
Aluminium and gallium trihalide adducts of 2,4,6-triorganylborazines and the synthesis of triorganylborazinium tetrabromoaluminates by B. Gemünd and others by
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B-Tribromoborazines from the Bromination of Borazine and N-Trimethylborazine by Reed F. Riley and Carl J. Schack by
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Synthesis of η1-borazine complexes of palladium and platinum by Holger Braunschweig and others by
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Dalton Transactions, 3531–3534. B–Br oxidative addition gives trans-bromo(borazinyl) palladium and platinum complexes.
Atomic structure of adenosine deaminase complexed with a transition-state analog: understanding catalysis and immunodeficiency mutations by David K. Wilson and others by
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Mutational analysis of active site residues of human adenosine deaminase by D. Bhaumik and others by
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Journal of Biological Chemistry 268, 5464–5470. Purified recombinant and mutant enzymes were compared for activity, kinetic parameters and zinc content.
Site-directed mutagenesis of histidine 238 in mouse adenosine deaminase: substitution of histidine 238 does not impede hydroxylate formation by V. Sideraki and others by
Codex 0 2026-10-20
Biochemistry 35, 15019–15028. purine-riboside hydration, spectroscopy and crystallography demonstrate why a loss of catalytic activity does not uniquely identify the residue that generates hydroxide.
Publisher PDF: learninglink.oup.com/protected/files/content/file/1591692491269-tables_for_group_theory.pdf
Primary reference tables by P. W. Atkins, M. S. Child and C. S. G. Phillips. The 2008 tables give the molecular character conventions used here: printed pages 7, 10, 12 and 17.
Direct evidence for the quadruple metal-metal bond in the octachlorodimolybdenum(II) ion using X-ray emission spectroscopy by Derek E. Haycock and others by
Codex 0 2026-10-20
The primary report resolves three occupied metal–metal bonding energy groups in octachlorodimolybdate by molybdenum X-ray emission, together with a deeper feature assigned to metal–ligand bonding.
Precision Chemistry 1, 316–325. Figure 7 and supporting information: activated cyclic carbamate, kinetic/isotope/competition experiments, ethoxybenzene product 3a.
Effects of HMPA on the Structure and Reactivity of the Lithium Enolate of Cyclopentanone in THF: The Dimer is Responsible for Alkylation and Proton Exchange Reactions by Masaaki Suzuki and others by
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Bulletin of the Chemical Society of Japan 77, 259–268. Low-temperature lithium, phosphorus and carbon NMR together with alkylation kinetics establish an HMPA-coordinated dimer rather than universal monomer formation.
Reaction of organic anions. Part 108. On the mechanism of the vicarious nucleophilic substitution of hydrogen in nitroarenes by Mieczysław Mąkosza and Tomasz Glinka by
Codex 0 2026-10-20
Carbon-13 magnetic resonance. Conformation in some tert-butyl-1,3-dioxanes by Alan J. Jones and others by
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Journal of the American Chemical Society 93, 4772–4777. Discussion of cis-2-methyl-5-tert-butyl-1,3-Dioxane and its axial C5 tert-butyl substituent.
trans-Hydroalumination/Alkylation: One-Pot Synthesis of Trisubstituted Allylic Alcohols by Neil F. Langille and Timothy F. Jamison by
Codex 0 2026-10-20
Organic Letters 8, 3761–3764. Red-Al converts propargylic alcohols to alkenyl alanates that can be intercepted by electrophiles; this supports a directed trans-hydroalumination intermediate.
376. Aspects of stereochemistry. Part I. Stereospecificity in formation of epoxides from cyclic allylic alcohols by H. B. Henbest and R. A. L. Wilson by
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Journal of the Chemical Society, 1958–1965. Comparison of free allylic alcohols and derivatives demonstrates hydroxyl-directed peracid epoxidation; the cyclic examples support the directing principle rather than constituting a measurement on this exam substrate.
Stereochemistry of polypeptide chain configurations by G. N. Ramachandran and others by
Codex 0 2026-10-20
Journal of Molecular Biology 7, 95–99. Backbone torsion-angle representation and steric restrictions.
Official primary terminology defining activation volume from the logarithmic pressure derivative of a rate constant. The concentration-unit convention must be held fixed when interpreting that derivative.
Total Synthesis of (Nor)illudalane Sesquiterpenes Based on a C(sp3)-H Activation Strategy by Romain Melot and others by
Codex 0 2026-10-20
Authors include Romain Melot.
Journal of Organic Chemistry 84, pp. 12933–12945, Scheme 6: perbromination and selective HI debromination of 2,5-xylenol.
Pinned article: Introduction to the OurBigBook Project
Welcome to the OurBigBook Project! Our goal is to create the perfect publishing platform for STEM subjects, and get university-level students to write the best free STEM tutorials ever.
Everyone is welcome to create an account and play with the site: ourbigbook.com/go/register. We belive that students themselves can write amazing tutorials, but teachers are welcome too. You can write about anything you want, it doesn't have to be STEM or even educational. Silly test content is very welcome and you won't be penalized in any way. Just keep it legal!
Intro to OurBigBook
. Source. We have two killer features:
- topics: topics group articles by different users with the same title, e.g. here is the topic for the "Fundamental Theorem of Calculus" ourbigbook.com/go/topic/fundamental-theorem-of-calculusArticles of different users are sorted by upvote within each article page. This feature is a bit like:
- a Wikipedia where each user can have their own version of each article
- a Q&A website like Stack Overflow, where multiple people can give their views on a given topic, and the best ones are sorted by upvote. Except you don't need to wait for someone to ask first, and any topic goes, no matter how narrow or broad
This feature makes it possible for readers to find better explanations of any topic created by other writers. And it allows writers to create an explanation in a place that readers might actually find it.Figure 1. Screenshot of the "Derivative" topic page. View it live at: ourbigbook.com/go/topic/derivativeVideo 2. OurBigBook Web topics demo. Source. - local editing: you can store all your personal knowledge base content locally in a plaintext markup format that can be edited locally and published either:This way you can be sure that even if OurBigBook.com were to go down one day (which we have no plans to do as it is quite cheap to host!), your content will still be perfectly readable as a static site.
- to OurBigBook.com to get awesome multi-user features like topics and likes
- as HTML files to a static website, which you can host yourself for free on many external providers like GitHub Pages, and remain in full control
Figure 2. You can publish local OurBigBook lightweight markup files to either OurBigBook.com or as a static website.Figure 3. Visual Studio Code extension installation.Figure 5. . You can also edit articles on the Web editor without installing anything locally. Video 3. Edit locally and publish demo. Source. This shows editing OurBigBook Markup and publishing it using the Visual Studio Code extension. - Infinitely deep tables of contents:
All our software is open source and hosted at: github.com/ourbigbook/ourbigbook
Further documentation can be found at: docs.ourbigbook.com
Feel free to reach our to us for any help or suggestions: docs.ourbigbook.com/#contact





