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The angular momentum associated with motion in a degenerate bending normal mode of a linear molecule. A one-quantum bend has $l=\pm 1$, and the total rotational quantum number obeys $J\ge |l|$.

Use the leading nonrelativistic magnetic coupling for an electronic level with total angular momentum operator $\mathbf{J}$, and choose the $z$ axis along a uniform external magnetic field $\mathbf{B}=B\hat{\mathbf{z}}$, $B\ge 0$. Write its magnetic quantum number as $m_J$, so $J_z|J,m_J⟩=\hslash m_J|J,m_J⟩$. There are $2J+1$ possibilities from $-J$ to $J$. With Landé g-factor $g_J$, the first-order shift isHere $e>0$ is the magnitude of the electron electric charge, $m_e$ its mass, $h$ the Planck constant, and ${\mu }_B$ the Bohr magneton. Both $g_J$ and $m_J$ are dimensionless; with $B$ measured in tesla and ${\mu }_B$ in joules per tesla, $\Delta E$ is in joules. The photon frequency shift $\Delta {\nu }_{ul}$ is in hertz, not angular frequency; indices $u,l$ denote upper and lower levels. NIST states this weak-field convention and its orbital/spin assumptions explicitly.^[ref]

The sign follows directly from magnetic dipole potential energy. Within this electronic $J$ multiplet, the projected magnetic dipole moment is $\mathbf{\mu }=-g_J{\mu }_B\mathbf{J}/\hslash$. Therefore $H_Z=-\mathbf{\mu }\cdot \mathbf{B}$ has the displayed positive coefficient. Subtracting the shifts of the two levels and using photon energy $h{\nu }_{ul}=E_u-E_l$ gives the transition formula. For the orbital case, ${\mu }_B/h=e/(4\pi m_e)$ gives the same leading frequency spacing as the classical charged oscillator. This explains the historical sensitivity to charge divided by mass; the quantum state derivation here is modern.

“Weak” compares interaction energies: mixing with neighbouring fine structure levels must be small, so $J$ remains a useful quantum number. The formula keeps the term linear in $B$ and neglects quadratic shifts. It also omits hyperfine structure; if that is resolved and controls the coupling, the appropriate total electronic-plus-nuclear angular momentum and splitting factor must replace $J,g_J$. Weak compared with fine structure does not automatically mean weak compared with hyperfine structure.

The Wigner-Eckart theorem separates the dependence of a spherical tensor operator on angular momentum projections from its dynamical content. In one standard convention,The reduced matrix element on the right is independent of $m,m^{\prime },q$. The Clebsch-Gordan coefficients impose $m^{\prime }=m+q$ and $|j-k|\le j^{\prime }\le j+k$; additional selection rules, including parity, can make the reduced matrix element vanish.

To see why the factorization holds, combine the rank-$k$ transformation law of the operator with the spin-$j$ transformation law of the initial state. This gives an intertwining operator from the tensor product representation $j\otimes k$ to the final representation $j^{\prime }$. The Clebsch-Gordan decomposition contains each allowed $j^{\prime }$ once. Therefore the corresponding intertwining operator is unique up to an overall scalar, which is the reduced matrix element after the chosen normalization. Ratios within the same pair of multiplets depend only on Clebsch-Gordan coefficients, whenever the common reduced matrix element is nonzero.

A binary in which a black hole captures part of its companion's stellar wind. The captured gas can dissipate energy and, with sufficient specific angular momentum, form an accretion disk. This differs from gas overflowing a Roche lobe through the inner Lagrange point. The fraction captured, its angular momentum and changes in the wind affect the accretion flow and emitted X-rays.

Zeeman splitting is the separation of energy levels or mode frequencies by a background magnetic field. In atomic physics, the magnetic field couples to a magnetic dipole moment, lifting quantum degeneracy. Transitions between the shifted quantum states can turn one spectral line into several. A split level and a split spectral line are different objects: the emitted photon measures the difference between two level energies, and the electric-dipole selection rule determines which differences appear.

The Stern-Gerlach experiment also probes magnetic dipole moments, through beam deflection in a magnetic field gradient. Here the readout is a spectral line.

The pattern makes an invisible magnetic field visible through spectroscopy. It also reveals angular momentum and magnetic dipole moments inside chemical atoms. Zeeman slowers exploit a changing resonance frequency to keep moving chemical atoms absorbing laser photons; a magneto-optical trap combines position-dependent shifts with electromagnetic polarization and laser cooling. Related mode shifts occur in Zeeman splitting of an antiferromagnetic spin wave.