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The double-slit experiment compares propagation through two openings. Coherent illumination gives double-slit interference; independent incoherent source patches contribute light intensities whose displaced patterns can reduce the observed interferometric visibility.

A mercury-vapor lamp is an extended, spontaneously emitting source, so practical interference requires spatial filtering and spectral selection. A narrow illuminated source slit gives sufficient spatial coherence; selecting one strong spectral line improves temporal coherence and avoids overlapping differently spaced interference fringes.

In the classical double-slit experiment, both apertures are illuminated by the same narrow source. The arrangement is symmetric, permits direct measurement and adjustment of slit separation, and has equal optical materials in the two paths. Its main drawbacks are low transmitted intensity through narrow apertures, the need for a well-made closely spaced slit pair and alignment, and the finite single-slit diffraction envelope. A broad source washes out interference fringes.

Lloyd's mirror uses the direct wave from a narrow source and the reflected wave, which appears to come from its virtual image behind a plane mirror. It requires only one physical source slit; the mirror can be adjusted to make a small effective source separation without manufacturing a double aperture. Only the direct-reflected overlap region shows interference fringes. Finite mirror size, alignment, surface quality, unequal intensities and the polarization-dependent reflection coefficient can reduce visibility. For the usual grazing reflection from glass, the reflected electric wave acquires approximately a $\pi$ phase shift, so the zero path-difference position is dark rather than the bright central fringe of the symmetric classical double-slit experiment. Both arrangements still require adequate spatial coherence and temporal coherence.

The postulates of quantum mechanics give a framework for predicting observations from a prepared state. The experiments below motivate different features of that framework; no one experiment proves the whole set of postulates or specifies every Hamiltonian operator.

A pure quantum state is a normalized vector in a complex Hilbert space, with vectors differing by an overall quantum phase representing the same physical preparation. In position representation, $\int |\psi (\mathbf{r}){|}^2{d}^{3}r=1$. The linear state space permits quantum superposition, while the Born rule assigns probability ${\int }_{\Omega }|\psi {|}^2{d}^{3}r$ to a position outcome in a region $\Omega$. The wavefunction is a probability amplitude; it is not a classical distribution of definite particle positions and momenta.

An observable is represented by a self-adjoint operator. If $Q$ has spectral projectors $P_q$, its possible measurement outcomes are its spectral values and $\mathrm{Pr}(q)=⟨\psi |P_q|\psi ⟩$. The mean is $⟨Q⟩=⟨\psi |Q|\psi ⟩$. For an ideal repeatable projective measurement, obtaining $q$ leaves the normalized conditional state $P_q\psi /\sqrt{\mathrm{Pr}(q)}$. This projects onto an entire eigenspace if the outcome is degenerate. General detectors need more general measurement in quantum mechanics models; the projective update is an idealization. Noncommuting observables need not have simultaneous sharp values, as the canonical commutation relation and Heisenberg uncertainty relation illustrate.

Between measurements, an isolated system has unitary time evolution generated by its Hamiltonian operator:This preserves normalization and superpositions. Composite systems use a tensor product of state spaces, allowing entangled states as well as product states; identical particles additionally require the bosonic or fermionic exchange symmetry appropriate to their species. Statistical mixtures are described by a density matrix, with $\mathrm{Pr}(q)=\mathrm{tr}(\rho P_q)$. These rules separate preparation, coherent evolution and measurement.

The photoelectric effect exposes discrete energy transfer by light. Illuminate a clean metal cathode in an evacuated tube and measure the collected electron current while varying the light frequency, intensity and a retarding voltage. The stopping potential $V_s$ probes the largest emitted electron kinetic energy, whereas the photocurrent measures the rate at which charge is collected. In the ordinary single-photon regime there is a threshold frequency; above it the maximum energy grows with frequency, rather than with intensity. Changing intensity at fixed frequency mainly changes the number of emitted electrons. These observations are summarized by the Einstein photoelectric equationHere $\Phi$ is the surface work function, and the stopping voltage is understood after any photoelectric contact-potential correction. A photon delivers $h\nu$ in an absorption event; emission is allowed only when that energy can pay the escape cost. This accounts for the frequency threshold and the lack of the classical waiting time associated with slowly accumulating energy in a single electron. The experiment supports energy quantization of light; it does not imply that every incident photon emits an electron or that every emitted electron has the maximum energy. Surface losses and collection geometry affect the full current-voltage curve.

The Davisson–Germer experiment demonstrates a complementary wave property of matter. An electron gun uses a heated emitter, accelerating voltage and apertures to send a narrow beam onto a nickel single crystal in vacuum. A movable collector measures scattered electric current versus direction; rotating the crystal also tests its azimuthal symmetry. The crystal gives sharp angular beams whose positions depend on voltage and crystal orientation. A prominent feature occurs near $54\mathrm{V}$ accelerating voltage and roughly $50^{\circ }$ detector colatitude. The nonrelativistic de Broglie wavelength predicted at that voltage isDiffraction wavelengths inferred using the known crystal structure agree with this voltage dependence. These angular peaks arise from coherent addition of scattering amplitudes from the crystal, not from classical specular reflection of independent point projectiles. Bragg's law is $2d\sin {\theta }_B=r\lambda$ for lattice-plane spacing $d$ and angle to those planes; a detector colatitude is a different angle and must not be substituted without its geometry. The historical readout was current, not a photograph of individual electron trajectories.^[ref]

The double-slit experiment makes the role of amplitudes especially direct. A coherent source illuminates two narrow slits; an observation screen a distance $D$ away records the pattern. For slit spacing $d$ and small screen displacement $y$, the path difference is approximately $dy/D$. The two amplitudes add before probabilities are formed:For equal coherent illumination the interference term varies as $\cos (2\pi dy/(\lambda D))$, giving fringe spacing $\lambda D/d$ beneath the single-slit diffraction envelope. Blocking one slit removes that cross term. Young's optical experiment established wave interference; later particle-resolved realizations with photons or electrons show localized detection events whose accumulated distribution has the interference pattern. Low arrival rates demonstrate that this pattern does not require different incident particles to collide with one another.

If the paths become correlated with distinguishable detector states $|D_1⟩$ and $|D_2⟩$, the cross term acquires their overlap $⟨D_2|D_1⟩$. Perfectly distinguishable path records make that overlap zero, suppressing interference even if the spatial beams still overlap. This connects quantum entanglement, measurement and loss of observable coherence. Without a path measurement, the two alternatives are amplitudes for one preparation, rather than classical mutually exclusive events whose probabilities may simply be added.

Together these experiments motivate a description in which energy transfer and detector outcomes can be discrete, yet propagation retains complex quantum phases and interference. The Born rule connects those amplitudes to repeatable frequencies of outcomes. The Schrödinger equation supplies the dynamics once a Hamiltonian operator is specified, while observable operators, state preparation and the measurement model specify what the apparatus can read.

For the double-slit experiment with oblique incidence, the optical path difference has an unknown incident contribution plus $a\sin \theta$ in the outgoing direction. It cancels between adjacent angular features. From a minimum to the next maximum, the path difference changes by $\lambda /2$:This incidence-independent adjacent-fringe wavelength uses the statement that intensity rises directly from the stated zero to the following peak. No absolute interference order or incidence angle is needed; nonadjacent extrema would require the number of intervening fringes.

In the double-slit experiment, each photon is detected as a localized event carrying energy $h\nu$, while repeated events build the interference pattern of coherent probability amplitudes from the two slits. Acquiring information that distinguishes the paths suppresses the interference; splitting the classical intensity into two incoherent alternatives would not reproduce the fringes.

Put one plate before each slit at normal incidence, with the same known refractive index $n$ and illumination of vacuum wavelength $\lambda$. Relative to the plate-free reference, their thickness difference $\Delta d=d_1-d_2$ produces an optical path difference $(n-1)\Delta d$ and a phase shiftObserve the displacement of the full interference fringe pattern, or scan a controllable reference phase and estimate $\Delta \varphi$. This compares the plates directly; a detectable phase displacement establishes unequal thickness under the common-material assumption. For fringe spacing $\lambda D/b$, the displacement is $-D(n-1)\Delta d/b$, where $b$ is slit separation and $D$ the screen distance, with sign set by the slit labeling.

A differential phase measurement can resolve a small difference sensitively and avoid determining two large absolute thicknesses. It does not guarantee a universally faster or more photon-efficient test: noise, coherence, alignment, and required accuracy matter. Moreover a null phase shift at one wavelength only impliesso equality requires a prior bound, a broadband or multiple-wavelength measurement, or continuously counting interference fringes as the plates are introduced. If the refractive indices differ, this apparatus measures optical thickness difference rather than geometrical thickness difference.

For an isolated quantum system, pure states are normalized rays in a complex Hilbert space, observables are self-adjoint operators, and their probabilities obey the Born rule. A spectral projector $P_a$ has outcome probability $⟨\psi |P_a|\psi ⟩$; an ideal repeatable projective measurement has conditional state $P_a\psi /\sqrt{⟨\psi |P_a|\psi ⟩}$. The Schrödinger equation specifies continuous unitary evolution between such ideal measurements, given a Hamiltonian operator. General measurements need not have the projective state-update rule.

Composite systems use the tensor product of their state spaces. Identical particles additionally obey the bosonic or fermionic exchange symmetry appropriate to their species. The photoelectric effect, Davisson–Germer experiment and double-slit experiment motivate energy quanta, matter-wave phases and probability interference, respectively; these experiments constrain the framework but do not separately prove every abstract postulate or specify every system's Hamiltonian.