The thermomechanical effect couples a temperature difference to a pressure difference across a superleak. For the closed-chamber model in the apparatus figure, consider neighboring equilibrium states with small velocities, negligible height difference and pure helium-4. Let be chemical potential per unit mass, in . The Gibbs free energy differential per unit mass givesThe superleak allows the superfluid to redistribute until the two sides have equal . Setting therefore givesThe sign matters: heating one side at initially equal pressure lowers its ; inflow raises its pressure until chemical balance is restored. The hotter side has the higher pressure. The integral follows the constant- path; it need not be evaluated at fixed pressure when material properties vary appreciably.
For an original local example, stipulate constant , and . The predicted pressure difference is . These are teaching assumptions, not helium measurements. This static thermodynamics relation predicts neither the required heater power nor the filling time: those require heat leakage, channel conductance and chamber heat capacity. An outlet would introduce kinetic energy and a flowing balance, so the static is not a predicted fountain height.
A superleak is a narrow or porous connection that strongly suppresses the viscous normal component of a superfluid while allowing appreciable superfluid flow. Treating is a regime assumption, not a perfect material filter for particular atoms. The thermomechanical effect uses that distinction to maintain a temperature difference during chemical equilibration. The idealization fails when normal leakage or dissipative quantum vortex motion becomes appreciable.
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