Gaussian Model A impulse response 2026-10-06
For quadratic free energy with positive and kinetic coefficient , a deterministic initial Dirac delta distribution evolves under nonconserved order-parameter dynamics to the meanTaking the expectation removes the centered Gaussian white noise; the resulting diffusion-reaction equation is solved by the heat kernel. The integrated mean is , so spreading does not conserve the initial excess. The connected Fourier mode covariance grows from zero to as by the Itô isometry. A realization retains equilibrium fluctuations after its mean has decayed. Pointwise continuum white-noise quantities require a coarse-graining cutoff.
With constant positive kinetic coefficient and mobility , two independent relaxation channels giveThe deterministic mobility operator is . Each channel separately satisfies microscopic reversibility when its noise obeys the corresponding Model A fluctuation-dissipation relation or fluctuation-dissipation relation for a conserved flux.
Past exam of the mathematics course of the University of Cambridge 2017 iii Paper 344 1 b Solution Created 2026-10-03 Updated 2026-10-06
Here is a kinetic coefficient, and the additive Gaussian white noise must be centered. A rigorous starting point is a finite spatial discretization or finite set of modes of the coarse-grained field. For each field coordinate, the Fokker-Planck probability current has the continuum notationThe equilibrium Boltzmann distribution has . Detailed balance for this time-even field requires zero configuration-space current. ThereforeThis is the Model A fluctuation-dissipation relation. Conversely, that noise strength makes the equilibrium current vanish and gives reversible relaxational dynamics when the equilibrium measure is normalizable.
Alternatively, the Onsager--Machlup path probability for Model A dynamics compares the squared required noise histories and . Their difference gives , using the functional chain rule. The midpoint convention and time-reversal invariance of a path Jacobian justify cancellation of the common Jacobian. Comparing with the conditional path ratio gives the same result. The spatial white-noise continuum is a coarse-grained idealization: retain a microscopic cutoff when pointwise fluctuations or ultraviolet divergences matter.
Polar molecular field 2026-10-05
The polar molecular field is the functional derivative of the free energy with respect to the polar order parameter. In the positive-derivative convention, dissipative dynamics is with positive kinetic coefficient. For a quartic local term and an isotropic gradient penalty,Some authors instead define the molecular field with a minus sign, which changes the associated stress and evolution conventions.