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At momentum transfers small compared with $M_W$, the two weak charged current vertices each carry $g/(2\sqrt{2})$ when written with $(1-{\gamma }_5)$, and the W boson propagator reduces to a local factor proportional to $1/M_W^2$. Matching their product to the Fermi interaction gives, at tree level,The Fermi constant is thus determined by the electroweak coupling and symmetry-breaking scale; the four-fermion description is a low-energy effective interaction.

Only the cross term $J_L^{†}{J}_H$ can annihilate the pion and create the stated charged-lepton/antineutrino pair. Its leptonic matrix element is ${\bar{u}}_e(k){\gamma }^{\mu }(1-{\gamma }_5)v_{\nu }(q)$. Lorentz covariance permits a vacuum-to-spin-zero current matrix element only proportional to $p^{\mu }$. At rest this has only a temporal component. The vacuum is parity-even and the pion is parity-odd, while $V_H^0$ is parity-even, so $⟨0|V_H^0|\pi ⟩$ equals its own negative and vanishes. Lorentz covariance then makes the full vector matrix element vanish. The temporal axial current is parity-odd and is allowed: this is the vacuum-to-pseudoscalar current selection rule.

The minus sign in $J_H=V_H-A_H$ cancels the interaction's minus sign, up to an irrelevant common S-matrix phase. ThereforeThe pion decay constant convention here includes the given $\sqrt{2}$ in its current matrix element. Momentum conservation and the external Dirac equations give $p=k+q$, ${\bar{u}}_e/k=m_e{\bar{u}}_e$, $/q{v}_{\nu }=0$. Since $/q(1-{\gamma }_5)=(1+{\gamma }_5)/q$, the neutrino term vanishes andThis is helicity suppression: the amplitude vanishes in the zero charged-lepton-mass limit despite the larger available phase space.

For the spin sum, the Dirac adjoint of $1-{\gamma }_5$ is $1+{\gamma }_5$, and the completeness relations giveThe chiral projectors automatically eliminate the unused neutrino helicity when the full massless completeness relation is inserted. There is no initial spin average for a spin-zero pion.

In the pion rest frame, let $r=|\mathbf{k}|=|\mathbf{q}|$, $E=\sqrt{r^2+m_e^2}$. After integrating the spatial delta function and angles, the two-body Lorentz-invariant phase space becomesThe root is $r_{\ast }=(m_{\pi }^2-m_e^2)/(2m_{\pi })$ and $E_{\ast }=(m_{\pi }^2+m_e^2)/(2m_{\pi })$. The absolute derivative of the delta-function argument is $r_{\ast }/E_{\ast }+1=m_{\pi }/E_{\ast }$. Thus ${\Phi }_2=r_{\ast }/(4\pi m_{\pi })$. Multiplying by the spin sum and the initial factor $1/(2m_{\pi })$ yields the leptonic pseudoscalar decay widthIf the decay constant were instead defined by a matrix element $i{f}_{\pi }{p}^{\mu }$ without $\sqrt{2}$, then $f_{\pi }=\sqrt{2}{F}_{\pi }$ and the width coefficient would be $f_{\pi }^2/(8\pi )$; mixing these conventions would introduce a factor-of-two error.

The same derivation for a muon cancels the common hadronic and weak factors in the pion electron-to-muon decay ratio:The numerical value uses approximate masses $0.511,105.66,139.57$ MeV. Agreement with the corresponding Standard Model prediction tests lepton universality and the chiral, helicity-suppressing structure of the weak charged current, rather than the poorly calculable hadronic decay constant. A difference in the electron and muon weak couplings would multiply the ratio by their squared coupling ratio. Precision agreement must be assessed after radiative corrections, with matching photon-inclusive experimental definitions; the displayed tree-level ratio is not itself the radiatively corrected precision prediction.